Abstract
An overview of experimental work recently performed in the Lisbon laboratories is provided. Several physical properties of liquids as well as those of the coexistence between two liquid phases and between liquid and solid have been determined at absolute negative pressures. Examples for this include thermal pressure coefficients, loci of temperature of maximum density, negatively sloped melting lines, speed of propagation of low-intensity ultrasound waves, and (p, T, x) conditions of occurrence of liquid-liquid phase separation. The major achievements that emerged within the scope of this research program were: (i) the first experimental evidence for the existence of a TMD in supercooled and stretched gallium, and (ii) the first experimental detection of phase separation phenomena in molecular liquid mixtures under tension.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Imre, A., Martinás, K., Rebelo, L.P.N. (1998) Thermodynamics of negative pressures in liquids, J. Non-Equilibrium Thermodyn. 23, 351–375; Rebelo, L.P.N., Van Hook, A., Ye, Y.J. (1993) Liquids at negative pressures (transl.), Química 51, 33-42.
Debenedetti, P.G. (1996) Metastable Liquids, Princeton Univ. Press, Princeton, N.J.
Veiga, H.I.M, Rebelo, L.P.N., Nunes da Ponte, M., Szydlowski, J. (2001) Water and gallium at absolute negative pressures. Loci of maximum density and of melting, Int. J. Thermophys. 22, 1159–1174.
Henderson, S.J., Speedy, R.J. (1987) Temperature of maximum density in water at negative pressure, J. Phys. Chem. 91, 3062–3068; Henderson, S.J., Speedy, R.J. (1987) Melting temperature of ice at positive and negative pressures, J. Phys. Chem. 91, 3069-3072.
Imre, A., Van Hook, W.A. (1998) Liquid-liquid equilibria in polymer solutions at negative pressure, Chem. Soc Rev. 27, 117–123.
Visak, Z.P., Rebelo, L.P.N., Szydlowski, J. (2002) Achieving absolute negative pressures in liquids:precipitation phenomena in solution, J. Chem. Educ. 79, 869–873
Rebelo, L.P.N., Visak, Z.P., Szydlowski, J. (2002) Metastable critical lines in (acetone + polystyrene) solutions and the continuity of solvent quality states, Phys. Chem. Chem. Phys. 4, 1046–1052.
Ohde, Y., Komori, K., Nakamura, T. Tanzawa, Y., Nishino, Y., Hiro, K. (2001) Effects of gas transports in metals on negative pressures in water in Mo/Cu Berthelot tubes, J. Phys. D: Appl. Phys. 34, 1717–1726.
Young, D. A. (1991) Phase Diagrams of the Elements, Univ. California Press, Berkeley, California.
Donohue, J. (1974) The Structures of the Elements, John Wiley & Sons, N.Y.
Bosio, L., Windsor, C.G. (1975) Observation of a metastability limit in liquid gallium, Phys. Rev. Lett. 35, 1652–1655; Bosio, L, Cortes, R., Defrain, A. (1973) Chaleur massique du gallium liquide en surfusion et des phases cristallines β et γ, J. Chimie Phys. 70, 357-359.
Manuscripts in preparation.
Buldyrev, S.V., Franzese, G., Giovambattista, N., Malescio, G., Sadr-Lahijany, M.R., Scala, A., Skibinsky, A., Stanley, H.E. (2002) Models for a liquid-liquid phase transition, Physica A 00, 00–00 (in press).
Poole, P.H., Grande, T., Angell, CA, McMilan, P.F. (1997) Polymorphic phase transitions in liquids and glasses, Science 275, 322–323.; Angell, CA., Bressel, R.D., Hemmati, M., Sare, E.J., Tucker, J.C. (2000) Water and its anomalies in perspective: tetrahedral liquids with and without liquid-liquid phase transitions, Phys. Chem. Chem. Phys. 2, 1559-1566; Rebelo, L.P.N., Debenedetti, P.G., Sastry, S. (1998) Singularityfree interpretation of the thermodynamics of supercooled water. Thermal and volumetric behavior, J. Chem. Phys. 109, 626-633.
Stanley, H.E., Buldyrev, S.V., Canpolat, M., Mishima, O., Sadr-Lahijany, M.R., Scala, A., Starr, F.W. (2000) The puzzling behavior of water at very low temperature, Phys. Chem. Chem. Phys. 2, 1551–1558; Franzese, G, Malescio, G., Skibinski, A, Buldyrev, S.V., Stanley, H.E. (2001) Generic mechanism for generating a liquid-liquid phase transition, Nature 409, 692-695; Mishima, O., Stanley, H.E. (1998) The relationship between liquid, supercooled and glassy water, Nature 396, 329-335.
Streett, W.B., Ringermacher, H.I., Büren, J.L. (1972) Sound velocity, adiabatic compressibility, and specific heat of liquid and dense fluid krypton, J. Chem. Phys. 57, 3829–3838.
Work in progress.
Imre, A., Van Hook, W.A. (1994) Polymer-solvent demixing under tension. Isotope and pressure effects on liquid-liquid transitions, VII. Propionitrile-polystyrene solutions at negative pressure, J. Polym. Sci: B: Polym. Phys. 32, 2283–2287.
Imre, A., Van Hook, W.A (1997) Continuity of solvent quality in polymer solutions. Poor-solvent to θ-solvent continuity in some polystyrene solutions, J. Polym. Sci: B: Polym. Phys. 35, 1251–1259.
Narayanan, T., Kumar, A. (1994) Reentrant phase transitions in multicomponent liquid mixtures, Phys. Rep. 249, 135–218
Schneider, G. (1963) Druckeinfluβ auf die entmischung flüssiger systeme, Zeitschrift Phys. Chem. Neue Folge 37, 333–352; ibid: 39, 187-197.
Rebelo, L.P.N., Visak, Z.P., de Sousa, H.C., Szydlowski, J., de Azevedo, R.G., Ramos, A.M., Najdanovoc Visak, V., Nunes da Ponte, M., Klein, J. (2002) Double critical phenomena in (water + polyacrylamides) solutions, Macromolecules 35, 1887–1895.
Imre, A.R., Melnichenko, G., Van Hook, W.A. (1999) Liquid-liquid equilibria in polystyrene solutions: the general pressure dependence, Phys. Chem. Chem. Phys. 1, 4287–4292.
Rebelo, L.P.N. (1999) A simple gE-model for generating all basic types of binary liquid-liquid equilibria and their pressure dependence. Thermodynamic constraints at critical loci, Phys. Chem. Chem. Phys. 1, 4277–4286.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Rebelo, L.P.N. et al. (2002). Measuring the Properties of Liquids and Liquid Mixtures at Absolute Negative Pressures. In: Imre, A.R., Maris, H.J., Williams, P.R. (eds) Liquids Under Negative Pressure. NATO Science Series, vol 84. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0498-5_9
Download citation
DOI: https://doi.org/10.1007/978-94-010-0498-5_9
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0896-2
Online ISBN: 978-94-010-0498-5
eBook Packages: Springer Book Archive