Abstract
Manganese oxides with tunnel and layered crystal structures constitute a large family of porous materials from ultramicropore to mesopore [1]. Most of the structural frameworks of the manganese dioxides (MD) consist of MnO6 octahedral units shared by corners and/or edges. The excellent electrochemical properties of several MD phases have attracting much attention for positive electrode materials in lithium batteries [2-5]. MnO2 was originally developed as electrode in Leclanché cells and, recently as positive electrode for a primary Li cell, but extensive research has been undertaken during the last decade to develop rechargeable Li//MnO2 cells [6].
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Julien, C., Massot, M. (2002). Lattice Dynamics of Manganese Oxides and Their Intercalated Compounds. In: Julien, C., Pereira-Ramos, J.P., Momchilov, A. (eds) New Trends in Intercalation Compounds for Energy Storage. NATO Science Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0389-6_16
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