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Pseudo-One-Dimensional MX3 and MX4 Transition Metal Chalcogenides

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Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures

Part of the book series: Physics and Chemistry of Materials with Low-Dimensional Structures ((PCMB,volume 5))

Abstract

Transition metal dichalcogenides have provided us with some of the best examples for the illustration of both the physics of low-dimensional compounds and intercalation chemistry. Their structure is made of MX2 layers built up from [MX6] octahedra as in TiS2, or [MX6] trigonal prisms as in NbS2 or NbSe2. The latter compounds allowed for the first time an experimental observation of a charge density wave (CDW) [1].

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    Alain Meerschaut & Jean Rouxel

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    Jean Rouxel

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Meerschaut, A., Rouxel, J. (1986). Pseudo-One-Dimensional MX3 and MX4 Transition Metal Chalcogenides. In: Rouxel, J. (eds) Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4528-9_6

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