Abstract
Chemical equilibrium relations between the major gas components in gasification are valuable for reactor design and process optimisation, as well as for a generally increased understanding of the processes. However, most previous equilibrium calculations have been limited to more or less narrow ranges of operating conditions and specific fuel characteristics. In the present work, an extensive systematic parametric study was performed utilising a D-optimal experimental design to structure the equilibrium calculations. The sensitivity analysis of designed calculation data, covered equilibrium relations between the responses CO, H2, CH4, CO2, H2O, NH3, HCN, higher heating value and all reasonable combinations of gasification conditions and fuel properties. The effects were evaluated by partial least squares (PLS) analysis and the results were illustrated with concentrations and higher heating values as functions of the most influential factors. The data set is available for interested readers.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Watkinson, A.P., Lucas, J.P. and Lim, C.J. (1991) A prediction of performance of commercial coal gasifiers. FUEL, Vol. 70, pp 519–527.
Cousins, W. J. (1978) A theoretical study of wood gasification processes. New Zeeland Journal of Science, Vol 21, pp 175–183.
Shesh, K. K., Sunavala, P.D. (1990) Thermodynamics of pressurized air-steam gasification of biomass. Indian Journal of Technology, Vol. 28, pp 133–138
Kinoshita, C. M., Wang, Y. and Takahashi, P. (1991) Chemical equilibrium computations for gasification of biomass to produce methanol. Energy Sources, Vol. 13, pp 361–368.
Buekens, A. G. and Schoeters, J. G. (1984). Mathematical modelling in gasification (Keynote paper), in Thermochemical processing of biomass, (ed. Bridgwater, A. V.), Butterworths, London.
Shand, R. N. and Bridgwater, A. V. (1984), Fuel gas from biomass: Status and new modelling approaches, in Thermochemical processing of biomass, (ed. Bridgwater, A. V.), Butterworths, London.
Desrosiers, R. (1981) Thermodynamics of gas-char reactions, in Biomass gasification, principles and technologies, (Ed. T.B. Reed), Noyes Data Coorp., New Jersay,pp 119–153
Eriksson, L., Hermens, J. L. M., Johansson, E., Verhaar, H. J. M. and Wold, S. (1995) Multivariate analysis of aquatic toxicity data with PLS. Aquatic Sciences, Vol. 57, pp 1015–1621
Kettaneh-Wold, N. (1995) Analysis of mixture data with partial least squares. Chemometrics and Intelligent Laboratory Systems, 14, 57–69
DuMouchel, W., and Jones, B. (1994) A simple bayesian modification of D-Optimal designs to reduce dependence on an assumed model. Technometrics, Vol. 36, pp 37–46.
MODDE, (1995) “Modelling and design, users guide”, Vol 3.0, Umetri AB, Umeâ.
Eriksson, G. and Hack, K. (1990) Chem-Sage — A computer program for the calculation of complex chemical equilibria. Metal Transactions, Vol. 21B, pp 1013–1023.
JANAF (1985) Thermochemical Tables. Journal of Physical and Chemical Reference Data, 3rd ed. Vol 14.
Box, G. E. P., Hunter, W. G., and Hunter, J. S. (1978) Statistics for experimenters; An introduction to design, data analysis and model building. Wiley, New York.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Nordin, A., Kallner, P., Johansson, E. (1997). Gas Quality from Biomass Gasification; An Extensive Parametric Equilibrium Study. In: Bridgwater, A.V., Boocock, D.G.B. (eds) Developments in Thermochemical Biomass Conversion. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1559-6_67
Download citation
DOI: https://doi.org/10.1007/978-94-009-1559-6_67
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7196-3
Online ISBN: 978-94-009-1559-6
eBook Packages: Springer Book Archive