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Gas Quality from Biomass Gasification; An Extensive Parametric Equilibrium Study

Parametric equilibrium study of gasification

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Developments in Thermochemical Biomass Conversion

Abstract

Chemical equilibrium relations between the major gas components in gasification are valuable for reactor design and process optimisation, as well as for a generally increased understanding of the processes. However, most previous equilibrium calculations have been limited to more or less narrow ranges of operating conditions and specific fuel characteristics. In the present work, an extensive systematic parametric study was performed utilising a D-optimal experimental design to structure the equilibrium calculations. The sensitivity analysis of designed calculation data, covered equilibrium relations between the responses CO, H2, CH4, CO2, H2O, NH3, HCN, higher heating value and all reasonable combinations of gasification conditions and fuel properties. The effects were evaluated by partial least squares (PLS) analysis and the results were illustrated with concentrations and higher heating values as functions of the most influential factors. The data set is available for interested readers.

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References

  1. Watkinson, A.P., Lucas, J.P. and Lim, C.J. (1991) A prediction of performance of commercial coal gasifiers. FUEL, Vol. 70, pp 519–527.

    Article  CAS  Google Scholar 

  2. Cousins, W. J. (1978) A theoretical study of wood gasification processes. New Zeeland Journal of Science, Vol 21, pp 175–183.

    CAS  Google Scholar 

  3. Shesh, K. K., Sunavala, P.D. (1990) Thermodynamics of pressurized air-steam gasification of biomass. Indian Journal of Technology, Vol. 28, pp 133–138

    CAS  Google Scholar 

  4. Kinoshita, C. M., Wang, Y. and Takahashi, P. (1991) Chemical equilibrium computations for gasification of biomass to produce methanol. Energy Sources, Vol. 13, pp 361–368.

    Article  CAS  Google Scholar 

  5. Buekens, A. G. and Schoeters, J. G. (1984). Mathematical modelling in gasification (Keynote paper), in Thermochemical processing of biomass, (ed. Bridgwater, A. V.), Butterworths, London.

    Google Scholar 

  6. Shand, R. N. and Bridgwater, A. V. (1984), Fuel gas from biomass: Status and new modelling approaches, in Thermochemical processing of biomass, (ed. Bridgwater, A. V.), Butterworths, London.

    Google Scholar 

  7. Desrosiers, R. (1981) Thermodynamics of gas-char reactions, in Biomass gasification, principles and technologies, (Ed. T.B. Reed), Noyes Data Coorp., New Jersay,pp 119–153

    Google Scholar 

  8. Eriksson, L., Hermens, J. L. M., Johansson, E., Verhaar, H. J. M. and Wold, S. (1995) Multivariate analysis of aquatic toxicity data with PLS. Aquatic Sciences, Vol. 57, pp 1015–1621

    Article  Google Scholar 

  9. Kettaneh-Wold, N. (1995) Analysis of mixture data with partial least squares. Chemometrics and Intelligent Laboratory Systems, 14, 57–69

    Article  Google Scholar 

  10. DuMouchel, W., and Jones, B. (1994) A simple bayesian modification of D-Optimal designs to reduce dependence on an assumed model. Technometrics, Vol. 36, pp 37–46.

    Google Scholar 

  11. MODDE, (1995) “Modelling and design, users guide”, Vol 3.0, Umetri AB, Umeâ.

    Google Scholar 

  12. Eriksson, G. and Hack, K. (1990) Chem-Sage — A computer program for the calculation of complex chemical equilibria. Metal Transactions, Vol. 21B, pp 1013–1023.

    Article  CAS  Google Scholar 

  13. JANAF (1985) Thermochemical Tables. Journal of Physical and Chemical Reference Data, 3rd ed. Vol 14.

    Google Scholar 

  14. Box, G. E. P., Hunter, W. G., and Hunter, J. S. (1978) Statistics for experimenters; An introduction to design, data analysis and model building. Wiley, New York.

    Google Scholar 

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© 1997 Springer Science+Business Media Dordrecht

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Nordin, A., Kallner, P., Johansson, E. (1997). Gas Quality from Biomass Gasification; An Extensive Parametric Equilibrium Study. In: Bridgwater, A.V., Boocock, D.G.B. (eds) Developments in Thermochemical Biomass Conversion. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1559-6_67

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  • DOI: https://doi.org/10.1007/978-94-009-1559-6_67

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7196-3

  • Online ISBN: 978-94-009-1559-6

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