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Sorption and Retardation of Organic Contaminants in Subsurface Systems: Effects on Transport and Fate

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Advances in Groundwater Pollution Control and Remediation

Part of the book series: NATO ASI Series ((ASEN2,volume 9))

Abstract

Sorption processes in subsurface systems are complex, often involving non-linear phase relationships and rate-limited conditions. These processes unquestionably impact reactive solute behavior under typical field scale conditions, and therefore must be considered in attempts to model or otherwise predict contaminant fate and transport in the subsurface. The thoughtful selection of equilibrium and rate models that accurately describe the inherently complex and system-specific dynamics of sorption processes is an imperative for accurate fate and transport modeling.

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References

  • Adeel, Z. and R.G. Luthy (1995). Sorption and transport kinetics of a nonionic surfactant through an aquifer sediment. Environ Sci Technol 29:1032–1042

    Article  Google Scholar 

  • Brusseau, M.L., and P.S.C. Rao (1989). Sorption nonideality during organic contaminant transport in porous media. CRC Crit Rev Environ Control 19:33–99

    Article  Google Scholar 

  • Carter, M.C., J.E. Kilduff and W.J. Weber, Jr. (1995). Site energy distribution analysis of preloaded adsorbents. Environ Sci Technol 29:1773–1780

    Article  Google Scholar 

  • Chiou, C.T., L.J. Peters and V.H. Freed (1979). A physical concept of soil-water equilibria for nonionic organic compounds. Sci 206:831–832

    Article  Google Scholar 

  • Chiou, C.T., P.E. Porter and D.W. Schmedding (1983). Partition equilibria of nonionic compounds between soil organic matter and water. Environ Sci Technol 17:227–231

    Article  Google Scholar 

  • Clunie, J.S. and B.T. Ingram (1983). Adsorption of nonionic surfactants. In Adsorption from Solution at the Solid/Liquid Interface. Parkitt, G.D. and C.H. Rochester (eds.) Academic Press

    Google Scholar 

  • Jaynes, W.F. and S.A. Boyd (1991). Hydrophobicity of siloxane surfaces in smectites as revealed by aromatic hydrocarbon adsorption from water. Clays Clay Miner 39:428–436

    Article  Google Scholar 

  • Karickhoff, S.W., D.S. Brown and T.A. Scott (1979). Sorption of hydrophobic pollutants on natural sediments. Wat Res 13:241–248

    Article  Google Scholar 

  • Karickhoff, S.W. (1980). Sorption kinetics of hydrophobic pollutants in natural sediments. In Contaminants and Sediments Vol 2. Analysis, Chemistry and Biology. Baker, R.A. (ed.) Ann Arbor Publ

    Google Scholar 

  • Karickhoff, S.W. (1981). Semi-empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils. Chemosphere 10:833–846

    Article  Google Scholar 

  • Karickhoff, S.W. (1984). Organic pollutant sorption in aquatic systems. J Hydraul Eng 110:707–735

    Article  Google Scholar 

  • Lee, L.S., P.S.C. Rao, M.L. Brusseau and R.A. Ogwada (1988). Nonequilibrium sorption of organic contaminants during flow through columns of aquifer materials. Environ Toxicol Chem 7:779–793

    Article  Google Scholar 

  • Leo, A., C. Hansch and D. Elkins (1971). Partition coefficients and their uses. Chem Rev 71:525–616

    Article  Google Scholar 

  • McCarty, P.L., M. Reinhard and B.E. Rittman (1981). Trace organics in groundwater. Environ Sci Technol 15:40–51

    Article  Google Scholar 

  • Miller, C.T., and W.J. Weber, Jr. (1986). Sorption of hydrophobic organic pollutants in saturated soil systems. J Contam Hydrol 1:584–592

    Article  Google Scholar 

  • Mingelgrin, U. and Z. Gerstl (1983). Reevaluation of partitioning as a mechanism of nonionic chemicals adsorption in soils. J Environ Qual 12:1–11

    Article  Google Scholar 

  • Munz, C. and P.V. Roberts (1986). Effects of solute concentrations and cosolvents on the aqueous activity coefficient of halogenated hydrocarbons. Environ Sci Technol 20:830

    Article  Google Scholar 

  • Narkis, N. and B. Ben-David (1985). Adsorption of non-ionic surfactants on activated carbon and mineral clay. Wat Res 7:815–824

    Article  Google Scholar 

  • Pennell, K.D., R.D. Rhue, P.S.C. Rao and C.T. Johnston (1992). Vapor-phase sorption of p-xylene and water on soils and clay minerals. Environ Sci Technol 26:756–763

    Article  Google Scholar 

  • Pennell K.D., L.M. Abrióla and W.J. Weber, Jr. (1993). Surfactant-enhanced solubilization of residual dodecane in soil columns 1. Experimental investigation. Environ Sci Technol 27:2332–2340

    Article  Google Scholar 

  • Pennell, K.D., D.E. Wigder, T.D. Dekker and L.M. Abriola (1995). Experimental and modelinginvestigations of rate-limited surfactant sorption. Environ Sci Technol (in preparation)

    Google Scholar 

  • Rao, P.S.C., J.M. Davidson, R.E. Jessup and H.M. Selim (1979). Evaluation of conceptual models for describing nonequilibrium adsorption-desorption of pesticides during steady flow in soils. Soil Sci Soc Am J 43:22–28

    Article  Google Scholar 

  • Rosen, M.J. (1988). Surfactants and interfacial phenomena, 2nd ed. Wiley, New York

    Google Scholar 

  • Schwarzenbach, R.P. and J. Westall (1981). Transport of non-polar organic compounds from surface water to groundwater. Environ Sci Technol 15:1360–1367

    Article  Google Scholar 

  • Spurlock, F.C. and J.W. Bigger (1994a). Thermodynamics of organic chemical partition in soils 1. Development of a general partition model and application to linear isotherms. Environ Sci Technol 28:989–995

    Article  Google Scholar 

  • Spurlock, F.C. and J.W. Bigger (1994b). Thermodynamics of organic chemical partition in soils 2. Partition of substituted phenylureas form aqueous solution. Environ Sci Technol 28:996–1002

    Article  Google Scholar 

  • Weber, W.J. Jr. and C.T. Miller (1988). Modeling the sorption of hydrophobic contaminants by aquifer materials I. Rates and equilibria. Wat Res 22:457–464

    Article  Google Scholar 

  • Weber, W.J. Jr., P.M. McGinley and L.E. Katz (1991). Sorption phenomena in subsurface systems: Concepts, models and effects on contaminant fate and transport. Wat Res 25:499–528

    Article  Google Scholar 

  • Weber, W.J. Jr., P.M. McGinley and L.E. Katz (1992). A distributed reactivity model for sorption by soils and sediments 1. Conceptual basis and equilibrium assessments. Environ Sci Technol 26:1955–1962

    Article  Google Scholar 

  • Weber, W.J. Jr. and F.A. DiGiano (1995).Process Dynamics in Environmental Systems. John Wiley &Sons, Inc., Wiley-Interscience, New York, NY

    Google Scholar 

  • Weber, W.J. Jr. and W. Huang (1995). A distributed reactivity model for sorption by soils and sediments 4. Intraparticle heterogeneity and phase-distribution relationships under non-equilibrium conditions. Environ Sci Technol (in review)

    Google Scholar 

  • Young, T.M. and W.J. Weber, Jr. (1995). A distributed reactivity model for sorption by soils and sediments 3. Effects of diagenetic processes on sorption energies. Environ Sci Technol 29:92–97

    Article  Google Scholar 

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© 1996 Kluwer Academic Publishers

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Weber, W.J., Pennell, K.D., Dekker, T.J., Abriola, L.M. (1996). Sorption and Retardation of Organic Contaminants in Subsurface Systems: Effects on Transport and Fate. In: Aral, M.M. (eds) Advances in Groundwater Pollution Control and Remediation. NATO ASI Series, vol 9. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0205-3_1

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  • DOI: https://doi.org/10.1007/978-94-009-0205-3_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6576-4

  • Online ISBN: 978-94-009-0205-3

  • eBook Packages: Springer Book Archive

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