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Hetero-Carbon: Heteroatomic Molecules and Nano-structures of Carbon

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Advanced Sensors for Safety and Security

Abstract

The hetero-carbon as hetero-fullerenes, hetero-graphene and hetero-nanotubes are considered as unique nanosensors which properties essentially differ from properties of undoped molecules and nanostructures of carbon. Products of a new method of pyrolysis (NMP) of pyridine by mass – spectrometric method are investigated. Fullerene С60 and its hydrides (С60Н6), small carbon molecules C3–C11, quasi-fullerene С48 and new heteroatomic fullerene-like molecules such as functionalized polyazafullerenes (C35N5)H9, (С45N5)(OH)3H14 and (С49N11)(OH)5Н18 with the large contents of nitrogen are basic substances formed at NMP of pyridine. The formation of undoped molecules С60, С60Н6 and С48 could be carried out only from fragments С2Н2, С3Н3, С4Н4 and С5Н5 of destruction of С5NН5 molecules. The growth of heteroatomic molecules is carried out with participation of pyridine molecules or the product of their dehydrogenation (C5N).

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Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., 01601, Kyiv, Ukraine

    Ganna Kharlamova

  2. Frantsevich Institute for Problems of Materials Science of NAS, 3 Krzhyzhanovsky st., dep. 73, 03142, Kyiv, Ukraine

    Oleksii Kharlamov, Marina Bondarenko, Nadezhda Gubareni & Veneamin Fomenko

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  1. Ganna Kharlamova
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  2. Oleksii Kharlamov
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  3. Marina Bondarenko
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  4. Nadezhda Gubareni
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  5. Veneamin Fomenko
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Correspondence to Ganna Kharlamova .

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  1. NUARI, Norwich University Applied Research Institutes, Herndon, Virginia, USA

    Ashok Vaseashta

  2. State Engineering University of Armenia, Yerevan, Armenia

    Surik Khudaverdyan

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Kharlamova, G., Kharlamov, O., Bondarenko, M., Gubareni, N., Fomenko, V. (2013). Hetero-Carbon: Heteroatomic Molecules and Nano-structures of Carbon. In: Vaseashta, A., Khudaverdyan, S. (eds) Advanced Sensors for Safety and Security. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7003-4_31

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