Skip to main content

Wet Chemical and Electrochemical Etching Processes

  • Living reference work entry
  • First Online:
Encyclopedia of Nanotechnology

Isotropy and Anisotropy

When a material is attacked by a liquid or vapor etchant, the material will be removed isotropically (uniformly in all directions) or through anisotropic etching (uniformity in vertical direction). The difference between isotropic etching and anisotropic etching is shown in Fig. 1. Material removal rate for wet etching is usually faster than the rates for many dry etching processes and can easily be changed by varying temperature or the concentration of active species.

Fig. 1
figure 1

(a) Completely anisotropic etching of a semiconductor (b) Isotropic etching where the semiconductor is etched all around uniformly if not masked

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  1. Radjenovic, B., Radmilovic-Radjenovic, M., Mitric, M.: Level set approach to anisotropic wet etching of silicon. Sensors (Basel) 10, 4950–4967 (2010)

    Article  Google Scholar 

  2. Elwenspoek, N.: Silicon Micromachining. Cambridge University Press, Cambridge, UK (1998)

    Google Scholar 

  3. Mayer, G.K., Offereins, H.L., Sandmaier, H., Kühl, K.: Fabrication of non-underetched convex corners in anisotropic etching of (100)-silicon in aqueous KOH with respect to novel micromechanic elements. J. Electrochem. Soc. 137, 3947–3951 (1990)

    Article  Google Scholar 

  4. Wacogne, B., Sadani, Z., Gharbi, T.: Compensation structures for V-grooves connected to square apertures in KOH-etched (1 0 0) silicon: theory, simulation and experimentation. Sensors Actuators A Phys. 112, 328–339 (2004)

    Article  Google Scholar 

  5. Lehmann, V., Föll, H.: Formation mechanism and properties of electrochemically etched trenches in n-type silicon. J. Electrochem. Soc. 137, 653–659 (1990)

    Article  Google Scholar 

  6. Bassu, M., Surdo, S., Strambini, L.M., Barillaro, G.: Electrochemical micromachining as an enabling technology for advanced silicon microstructuring. Adv. Funct. Mater. 22, 1222–1228 (2012)

    Article  Google Scholar 

  7. Lehmann, V.: The physics of macropore formation in low doped n-type silicon. J. Electrochem. Soc. 140, 2836–2843 (1993)

    Article  Google Scholar 

  8. Janshoff, A., Dancil, K.-P.S., Steinem, C., Greiner, D.P., Lin, V.S.Y., Gurtner, C., et al.: Macroporous p-type silicon Fabry − Perot layers. Fabrication, characterization, and applications in biosensing. J. Am. Chem. Soc. 120, 12108–12116 (1998). 1998/11/01

    Article  Google Scholar 

  9. Lee, C.-L., Kanda, Y., Hirai, T., Ikeda, S., Matsumura, M.: Electrochemical grooving of Si wafers using catalytic wire electrodes in HF solution. J. Electrochem. Soc. 156, H134–H137 (2009)

    Article  Google Scholar 

  10. Sugita, T., Hiramatsu, K., Ikeda, S., Matsumura, M.: Fabrication of pores in a silicon carbide wafer by electrochemical etching with a glassy-carbon needle electrode. ACS Appl. Mater. Interfaces 5, 2580–2584 (2013)

    Article  Google Scholar 

  11. Peng, K.Q., Xu, Y., Wu, Y., Yan, Y.J., Lee, S.T., Zhu, J.: Aligned single-crystalline Si nanowire arrays for photovoltaic applications. Small 1, 1062–1067 (2005)

    Article  Google Scholar 

  12. Peng, K.Q., Yan, Y.J., Gao, S.P., Zhu, J.: Dendrite-assisted growth of silicon nanowires in electroless metal deposition. Adv. Funct. Mater. 13, 127–132 (2003)

    Article  Google Scholar 

  13. Oh, Y., Choi, C., Hong, D., Kong, S.D., Jin, S.: Magnetically guided nano-micro shaping and slicing of silicon. Nano Lett. 12, 2045–2050 (2012)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mathew Ombaba .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer Science+Business Media Dordrecht

About this entry

Cite this entry

Ombaba, M., Inayat, S.B., Islam, M.S. (2015). Wet Chemical and Electrochemical Etching Processes. In: Bhushan, B. (eds) Encyclopedia of Nanotechnology. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6178-0_431-2

Download citation

  • DOI: https://doi.org/10.1007/978-94-007-6178-0_431-2

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Dordrecht

  • Online ISBN: 978-94-007-6178-0

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics