Abstract
Oxidation of charcoal with nitric acid or with SeO2/H2O2 produced biochar, the material similar to the Indian black earth of the Amazon region. The Electron paramagnetic resonance (EPR) spectroscopy data indicate that the organic-free radical density of the prepared biochar is greater under the treatment of charcoal with SeO2/H2O2 than with nitric acid. The FTIR and EPR spectroscopy data of the prepared biochar metal ion complexes with VO2+ and Cu2+ indicate oxygen as metal ions ligand atoms.
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References
Fong, S.S., L. Seng, and H.B. Mat. 2007. Reuse of nitric acid in the oxidative pretreatment step for preparation of humic acids from low rank coal of Mukah. Journal of the Brazilian Chemical Society 18: 41–46.
Francioso, O., S. Sanchez-Cortes, S. Bonora, M.L. Roldán, and G. Certini. 2011. Structural characterization of charcoal size-fractions from a burnt Pinus pinea forest by FT-IR, Raman and surface-enhanced Raman spectroscopies. Journal of Molecular Structure 994: 155–162.
Mahalakshmy, R., P. Indraneel, and B. Viswanathan. 2009. Surface functionalities of nitric acid treated carbon – A density functional theory based vibrational analysis. Indian Journal of Chemistry 48A: 352–356.
Novotny, E.H., M.H.B. Hayes, B.E. Madari, T.J. Bonagamba, S.E.R. Azevedo, A. Song, N.M. Guixue, C.R.B. Fukamachi, and A.S. Mangrich. 2009. Lessons from the Terra Preta de Índios of the Amazon region for the utilisation of charcoal for soil amendment. Journal of the Brazilian Chemical Society 20: 1003–1010.
Pearson, R.G. 1963. Hard and soft acids and bases. Journal of the American Chemical Society 85(22): 3533–3539.
Stainsack, J., A.S. Mangrich, M.B.F. Maia Claudia, V.G. Machado, J.C.P. dos Santos, and S. Nakagaki. 2003. Spectroscopic investigation of hard and soft metal binding sites in synthetic melanin. Inorganica Chimica Acta 356: 243–248.
Yodovich, Y.E., and M.P. Ketris. 2006. Selenium in coal: A review; international. Journal of Coal Geology 67: 112–126.
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© 2013 Zhejiang University Press and Springer Science+Business Media Dordrecht
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Mangrich, A.S., Angelo, L.C., Mantovani, K.M. (2013). Biochar Produced from Chemical Oxidation of Charcoal. In: Xu, J., Wu, J., He, Y. (eds) Functions of Natural Organic Matter in Changing Environment. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5634-2_184
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DOI: https://doi.org/10.1007/978-94-007-5634-2_184
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