Abstract
High vacuum evaporation (VE) is used for the first time to grow thin films of novel tetraphosphonate, Tiiii[H, CH3, Ph], and tetrathiophosphonate, TSiiii[H, CH3, Ph], cavitands for gas sensing applications. The sensing capabilities of the samples were investigated by exposing Tiiii- and TSiiii-coated QCMs to very low concentrations of ethyl alcohol. The sensitivity, the speed (t50 = 5 s for both the samples) and the detection limit (0.4 ppm for Tiiii and 2.5 ppm for TSiiii) of the samples were determined, indicating highly competitive sensing capabilities.
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References
M. Tonezzer, M. Melegari, G. Maggioni, R. Milan, G. Della Mea, E. Dalcanale, “Vacuum-evaporated cavitand sensors: Dissecting specific from nonspecific interactions in ethanol detection”, Chem. Mat., [20], 6535–6541, 2008.
M. Melegari, M. Suman, L. Pirondini, C. Massera, F. Ugozzoli, E. Kalenius, P. Vainiotalo, J.-C. Mulatier, J.-P Dutasta, E. Dalcanale, “Supramolecular sensing with phosphonate cavitands”, Chem. Eur. J., [14], 5772–5778, 2008.
M. Tonezzer, A. Quaranta, G. Maggioni, S. Carturan, G. Della Mea, “Optical sensing responses of tetraphenyl porphyrins toward alcohol vapours: A comparison between vacuum evaporated and spin-coated thin films”, Sens. Actuat. B [122], 620–626, 2007.
M. Tonezzer, “Production, characterization and testing of solid organic and metallorganic films for gas sensing applications,” Ph.D. Thesis, University of Trento, Trento, Italy, 1–231, 2007.
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Tonezzer, M., Maggioni, G., Melegari, M., Dalcanale, E. (2010). Novel Vacuum Evaporated Cavitand Sensors for Detecting Very Low Alcohol Concentrations. In: Malcovati, P., Baschirotto, A., d'Amico, A., Natale, C. (eds) Sensors and Microsystems. Lecture Notes in Electrical Engineering, vol 54. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3606-3_29
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DOI: https://doi.org/10.1007/978-90-481-3606-3_29
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