Skip to main content

Novel Vacuum Evaporated Cavitand Sensors for Detecting Very Low Alcohol Concentrations

  • Conference paper
  • First Online:
Sensors and Microsystems

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 54))

  • 2129 Accesses

Abstract

High vacuum evaporation (VE) is used for the first time to grow thin films of novel tetraphosphonate, Tiiii[H, CH3, Ph], and tetrathiophosphonate, TSiiii[H, CH3, Ph], cavitands for gas sensing applications. The sensing capabilities of the samples were investigated by exposing Tiiii- and TSiiii-coated QCMs to very low concentrations of ethyl alcohol. The sensitivity, the speed (t50 = 5 s for both the samples) and the detection limit (0.4 ppm for Tiiii and 2.5 ppm for TSiiii) of the samples were determined, indicating highly competitive sensing capabilities.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. M. Tonezzer, M. Melegari, G. Maggioni, R. Milan, G. Della Mea, E. Dalcanale, “Vacuum-evaporated cavitand sensors: Dissecting specific from nonspecific interactions in ethanol detection”, Chem. Mat., [20], 6535–6541, 2008.

    Article  Google Scholar 

  2. M. Melegari, M. Suman, L. Pirondini, C. Massera, F. Ugozzoli, E. Kalenius, P. Vainiotalo, J.-C. Mulatier, J.-P Dutasta, E. Dalcanale, “Supramolecular sensing with phosphonate cavitands”, Chem. Eur. J., [14], 5772–5778, 2008.

    Article  Google Scholar 

  3. M. Tonezzer, A. Quaranta, G. Maggioni, S. Carturan, G. Della Mea, “Optical sensing responses of tetraphenyl porphyrins toward alcohol vapours: A comparison between vacuum evaporated and spin-coated thin films”, Sens. Actuat. B [122], 620–626, 2007.

    Article  Google Scholar 

  4. M. Tonezzer, “Production, characterization and testing of solid organic and metallorganic films for gas sensing applications,” Ph.D. Thesis, University of Trento, Trento, Italy, 1–231, 2007.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer Science+Business Media B.V.

About this paper

Cite this paper

Tonezzer, M., Maggioni, G., Melegari, M., Dalcanale, E. (2010). Novel Vacuum Evaporated Cavitand Sensors for Detecting Very Low Alcohol Concentrations. In: Malcovati, P., Baschirotto, A., d'Amico, A., Natale, C. (eds) Sensors and Microsystems. Lecture Notes in Electrical Engineering, vol 54. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3606-3_29

Download citation

  • DOI: https://doi.org/10.1007/978-90-481-3606-3_29

  • Published:

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-3605-6

  • Online ISBN: 978-90-481-3606-3

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics