Skip to main content
SpringerLink
Log in

FT-IR and Resonance Raman Study of Photo-Induced Valence Tautomerization of 2,3-Diphenylindenone Oxide

  • Conference paper
Progress in Fourier Transform Spectroscopy

Part of the book series: Mikrochimica Acta Supplement ((MIKROCHIMICA,volume 14))

  • 41 Accesses

Abstract

FT-IR and resonance Raman spectra of the transient species of 2,3-diphenylindenone oxide generated by irradiation with UV light have indicated that the reversible photo-coloration reaction of this compound is well interpreted in terms of valence tautomerization involving transient species having a benzopyryhum olate structure. Frequency shifts and intensity changes in both the IR and Raman spectra of the transient species in different solvents suggest, however, that at least two transients are involved in the photo-coloration.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. E. F. Ullman, J. E. Milks, J. Am. Chem. Soc. 1962, 84, 1315; 1964, 86, 3814.

    Article  CAS  Google Scholar 

  2. E. F. Ullman, W. A. Henderson, Jr., J. Am. Chem. Soc. 1964, 86, 5050; 1966, 88, 4942.

    Article  CAS  Google Scholar 

  3. R. C. Bertelson, in: Photochromism (G. H. Brown, ed.), Wiley-Interscience, New York, 1971, p. 375.

    Google Scholar 

  4. E. Hadjoudis, G. Bersos, J. Photochem. 1981, 5, 47.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, School of Science and Engineering, Waseda University, Tokyo 169, Japan

    Hiroaki Takahashi, Akira Inoue & Noboru Kunimatsu

Authors
  1. Hiroaki Takahashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Akira Inoue
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Noboru Kunimatsu
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Analytical Chemistry, University of Veszprém, Veszprém, Hungary

    János Mink

  2. Institute of Isotopes, Hungarian Academy of Sciences, Budapest, Hungary

    János Mink

  3. Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest, Hungary

    Gábor Keresztury

  4. Institut für Analytische Chemie, Technische Universität Wien, Wien, Austria

    Robert Kellner

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Springer-Verlag Wien

About this paper

Cite this paper

Takahashi, H., Inoue, A., Kunimatsu, N. (1997). FT-IR and Resonance Raman Study of Photo-Induced Valence Tautomerization of 2,3-Diphenylindenone Oxide. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_42

Download citation

  • DOI: https://doi.org/10.1007/978-3-7091-6840-0_42

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-211-82931-8

  • Online ISBN: 978-3-7091-6840-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation