Abstract
The vibrational circular dichroism (VCD) and absorption spectra of (−)-poly(menthyl methacrylate), (−)-poly(menthyl acrylate), and (−)-poly(menthyl vinyl ether) are reported and compared to those of (1R, 2S, 5R)-(−)-menthol in solution in CCl4, from 830 to 1500 cm-1. Many VCD peaks are common to both menthol and the corresponding polymers, but there is evidence of other peaks that are characteristic for each of the polymers.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
T. A. Keiderling, P. Pancoska, in: Advances in Spectroscopy Part B, Biomolecular Spectroscopy, Vol. 21 (R. J. H. Clark, R. Hester, eds.), Wiley, Chichester, 1993, p. 267.
L. A. Nafie, T. A. Keiderling, P. J. Stephens, J. Am. Chem. Soc. 1976, 98, 2715.
D. Tsankov, T. Eggimann, G. Liu, H. Wieser, Proc. SPIE 1993, 2089, 178.
J. McCann, D. Tsankov, N. Hu, G. Liu, H. Wieser, J. Mol. Struct. 1994, 349, 309.
M. M. Koton, T. A. Sokolova, M. H. Savitskaya, T. M. Kiseleva, J. Gen. Chem. (U.S.S.R.) 1958, 28, 409.
R. L. Frank, H. R. Davis, Jr., S. S. Drake, J. J. McPherson, Jr., J. Am. Chem. Soc. 1944, 66, 1509.
W. H. Watanabe, L. E. Conlon, J. Am. Chem. Soc. 1957, 79, 2828.
D. Tsankov, T. Eggimann, H. Wieser, Appl. Spectrosc. 1995, 49, 132.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer-Verlag Wien
About this paper
Cite this paper
McCann, J.L., Schulte, B., Tsankov, D., Wieser, H. (1997). Vibrational Circular Dichroism Spectra of Selected Chiral Polymers. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_215
Download citation
DOI: https://doi.org/10.1007/978-3-7091-6840-0_215
Publisher Name: Springer, Vienna
Print ISBN: 978-3-211-82931-8
Online ISBN: 978-3-7091-6840-0
eBook Packages: Springer Book Archive