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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds pp 39–54Cite as

Pd(III) Mott–Hubbard Compounds

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Abstract

In spite of long history of MX-chain complexes, all Pt or Pd compounds are in CDW state, without exception. We have recently succeeded in realizing Pd(III) MH state by two methods, that is, one is the chemical pressure via long alkyl chains introduced as counteranions, [Pd(en)2Br](C n -Y)2⋅4H2O, and the other is the partial substitution with Ni(III) ions, [Ni1−x Pd x (chxn)2Br]Br2. In both systems, it has been revealed that Pd(III) MH state was realized by the chemical pressure acting in the systems.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-Ku, Sendai, 980-8578, Japan

    S. Takaishi & M. Yamashita

Authors
  1. S. Takaishi
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  2. M. Yamashita
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Correspondence to S. Takaishi .

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Editors and Affiliations

  1. , Departement of Chemistry, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan

    Masahiro Yamashita

  2. Kashiwano 5-1-5, Kashiwa, 277-8561, Japan

    Hiroshi Okamoto

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Takaishi, S., Yamashita, M. (2013). Pd(III) Mott–Hubbard Compounds. In: Yamashita, M., Okamoto, H. (eds) Material Designs and New Physical Properties in MX- and MMX-Chain Compounds. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1317-2_4

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