Abstract
There has been an increasing interest in the photochemical processes that occur in the surface waters of the oceans and other natural waters. The sunlight aquatic environment, which includes the euphotic zone, aerosols, the surface microlayer and the sediment-water interface in shallow areas, is a likely site for photochemical transformations of dissolved and particulate non-living matter, both organic and inorganic (Zafiriou et al. 1984). The most obvious evidence of photoreaction in aquatic environments is the widespread presence of phytoplankton and other light-dependent underwater plants, and much effort has been directed towards the mathematical description of photosynthesis by freshwater as well as marine phytoplankton.
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References
Anderson MA, Morel FM (1982) The influence of aqueous iron chemistry on the uptake of iron by the coastal diatom Thalassiosira weissflogii. Limnol Oceanogr 27:789–813
Baker KS, Smith RC, Green AES (1982) Middle ultraviolet irradiance at the ocean surface: Measurements and models. Limnol Oceanogr 27:500–509
Behnke W, Scheer V, Zetzsch C (1995) Production of photolytic precursor of atomic Cl from aerosols and Cl- in the presence of O3. In: Grimvall A., Leer EWB de (eds) Naturally produced organohalogens. Kluwer Academic Publishers, Dordrecht, pp 375–384
Berg CMG Van den (1995) Evidence for organic complexation of iron in seawater. Mar Chem 50:139–157
Blough NV, Zepp RG (1995) Reactive oyxgen species in natural waters. In: Foote CS, Valentine JS (eds) Active oxygen in chemistry. Chapman and Hall, New York, pp 280–333
Brand (1991) Minimum iron requirements of marine phytoplankton and the implications for biogeochemical control of new production. Limnol Oceanogr 36:1756–1771
Braterman PS, Cairns-Smith AG, Sloper RW (1984) Photo-oxidation of iron(II) in water between pH 7.5 and 4.0. J Chem Soc Dalton Trans 1441–1445
Calza, P, Maurino V, Minero C, Pelizzetti E, Sega M, Vincenti M (2001) Chloro and bromophenols formation from phenol and halides by simulated solar light irradiation in the presence of iron ions, iron oxides and cadmium sulfide. (to be published)
Calza, P, Maurino V, Minero C, Pelizzetti E, Sega M, Vincenti M (2001) Chloro and bromophenols formation from phenol and halides by simulated solar light irradiation in the presence of iron ions, iron oxides and cadmium sulfide.
Faust BC, Hoignè J(1990) Photolysis of Fe(III)-hydroxy complexes as sources of OH radicals in clouds, fog and rain. Atmos Environ 23:235–240
Faust BC, Zepp RG (1993) Photochemistry of aqueous iron(III)-polycarboxylate complexes: roles in the chemistry of atmospheric and surface waters. Environ Sci Technol 27:2517–2522
Finlayson-Pitts BJ, Pitts JN Jr (1986) Atmospheric chemistry: Fundamentals and experimental techniques. Wiley, New York Foote ST, Clennan EL (1995) Properties and reactions of synglet dioxygen. In: Foote CS, Valentine JS, Greenberg A, Liebman JF (eds) Active oxygen in chemistry, vol II. Blackie Academic and Professional, Glasgow, UK, pp 105–140
Gerisher H (1979) Solar photoelectrolysis with semiconductor electrodes. Appl Physics 31:115–172
Gledhill M, Berg CMG Van den (1995) Measurement of the redox speciation of iron in seawater by catalytic cathodic voltammetry. Mar Chem 50:51–61
Harvey GR (1983), Dissolved carbohydrates in the New York bight and the variability of marine organic matter. Mar Chem 12:333–339
Hautala R (1978) U.S. Environmental Protection Agency. U.S. National Technical Information Service, Springfield, VA. (EPA-600/3–78–060 Report PB-285)
Hoignè J (1990) Formulation and calibration of environmental reaction kinetics; oxidation by aqueous photooxidants as an example in aquatic chemical kinetics. In: Stumm W (ed) Reaction rates of processes in natural waters. Wiley Interscience, New York, pp 43–70
Hoignè J, Faust BC, Haag WR, Scully FE, Zepp RG (1989) Aquatic humic substances as sources and sinks of photochemically produced transient reactants. In: Suffert EM, Mac Carthy P (eds) Aquatic substances: Influence on fate and treatment of pollutants. American Chemical Society, Washington D.C., pp 363–381
Howard PH (1975) EPA report No. EPA-560/5–75–006. Washington, DC
Joussot-Dubien J, Kadiri A (1970) Photosensitized oxidation of ammonia by singlet oxygen in aqueous solution and in seawater. Nature 227:700–701
Keene WC (1995) Inorganic Cl cycling in the marine boundary layer: A review. In: Grimvall A, Leer WB de (eds) Naturally-produced organohalogens. Kluwer Academic Publishers, Dordrecht, pp 363–371
Lee WN, Zepp, RG, Gordon JA, Baughman GL, Cline DM (1977) Kinetics of chemical degradation of malathion in water. Environ Sci Technol 11(1):88–93
Leermakers PA, Thomas HT, Weis LD, James FC (1966) Spectra and photochemistry of molecules adsorbed on silica gel IV. J Am Chem Soc 88:5075–5083
Leighton PA (1961) Photochemistry of air pollution. Academic Press, New York, pp 6–41
Look SA, Fenical W (1984) Erythrolides: Unique marine diterpenoids interrelated by a naturally occurring di-6-methane rearrangement. J Am Chem Soc 106:5026–5027
Martin JH, Fitzwater SE, Gordon RM (1990) Iron deficiency limits phytoplankton growth in Antartic waters. Global Biogeochem Cycles 4:5–12
McKnight DM, Kimball BA, Bencala KE (1988) Iron photoreduction and oxidation in an acidic mountain stream. Science 240:637–640
Miles CJ, Brezonik PL (1981) Oxygen consumption in humic colored waters by a photochemical ferrousferric catalytic cycle. Environ Sci Technol 15:1089–1095
Miller GC, Zepp RG (1979) Effects of suspended sediments on photolysis rates of dissolved pollutants. Wat Res 13:453–485
Millero FJ (1996) Chemical oceanography, 2nd edn. CRC Press, Boca Raton
Minero C, Maurino V, Calza P, Pelizzetti E (1997) Photocatalytic formation of tetrachloromethane from chloroform and chloride ions. New J Chem 21:841–842
Newman L (ed) (1984) Gas-liquid chemistry of natural waters, vols I and II. Brookhaven National Laboratory, Upton, N.Y. (BNL 51757)
Pelizzetti E, Minero C, Maurino V (1990) The role of colloidal particles in the photodegradation of organic compounds of environmental concern in aquatic systems. Adv Colloid Interface Sci 32:271–316
Rodgers MAT, Snowden PT (1982) Lifetime of O2 (1Δg) in liquid water as determined by time-resolved infrared luminescence measurements. J Amer Soc 104:5541–5561
Roof AAM (1982) Aquatic photochemistry. In: Hutzinger O (ed) The handbook of environmental chemistry, vol IIB: Reactions and processes. Springer-Verlag, Berlin, pp 43–65
Rue EL, Bruland KW (1995) Complexation of iron(III) by natural organic ligands in the Central North Pacific as determined by a new competitive ligand equilibration/adsorptive cathodic stripping voltammetric method. Mar Chem 50:117–138
Sehgal C, Sutherland RG, Verrall RE (1980) Optical spectra of sonoluminescence from transient and stable cavitation in water satured with various gases. J Phys Chem 84:388
Shindo H, Huang PM (1982) Role of manganese IV oxide in abiotic formation of humic substances in the environment. Nature 298:363
Singh HB, Kasting JF (1988) Chlorine-hydrocarbon photochemistry in the marine troposphere and lower stratosphere. J Atmos Chem 7:262–285
Stumm W (1992) Chemistry of the solid-water interface. John Wiley and Sons, New York
Swallow JC (1969) Hydrated electrons in seawater. Nature 222:369–370
Voelker BM, Morel FMM, Sulzberger B (1997) Iron redox cycling in surface waters: Effects of humic substances and light. Environ Sci Technol 31(4):1004–1011
Wardman P (1989) Reduction potentials of one-electron couples involving free-radicals in aqueous solution. J Phys Chem Ref Data 18:1637–1755
Williams PM, Druffel ERM (1987) Radiocarbon in dissolved organic matter in the Central North Pacific Ocean. Nature 330:246–248
Zafiriou OC (1983) Naturally water photochemistry. In: Riley JP, Chester R (eds) Chemical oceanography, vol VIII. Academic Press, New York, pp 339–379
Zafiriou OC, Joussot-Dubien J, Zepp RG, Zika R (1984) Photochemistry of natural waters. Environ Sci Technol 18(12):358–371
Zepp RG (1978) Quantum yields for reaction of pollutants in dilute aqueous solution. Environ Sci Technol 12(3):327–329
Zepp RG (1980) Assessing the photochemistry of organic pollutants in aquatic environments. In: Haque R (ed) Dynamics, exposure and hazard assessment of toxic chemicals. Ann Arbor Science, Ann Arbor, Mich., pp 69–110
Zepp RG, Wolfe NL (1987) Abiotic transformation of organic chemicals at the particle-water interface. In: Stumm W (ed) Aquatic surface chemistry. Wiley, New York, pp 423–455
Zika R (1981) Marine organic photochemistry. In: Duursma EK, Dawson R (eds) Marine organic chemistry. Elsevier, Amsterdam, The Netherlands, pp 299–326
Zika R, Salzman E, Chameides WL, Davis DD (1982) Hydrogen peroxide levels in rainwater collected in south Florida and the Bahamas Islands. J Geophys Res 87:5015–5017
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Pelizzetti, E., Calza, P. (2002). Photochemical Processes in the Euphotic Zone of Sea Water: Progress and Problems. In: Gianguzza, A., Pelizzetti, E., Sammartano, S. (eds) Chemistry of Marine Water and Sediments. Environmental Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04935-8_3
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DOI: https://doi.org/10.1007/978-3-662-04935-8_3
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