Zusammenfassung
Eine der wichtigsten Eigenschaften der Tonminerale ist ihr ausgeprägtes Kationenaustauschvermögen. Die Höhe des Kationenaustauschvermögens wird durch die Menge der Zwischenschichtkationen bestimmt, deren Anzahl (pro Formeleinheit) durch die Schichtladung festgelegt und pH-Wert unabhängig ist. Unter den üblichen Bedingungen können nur bei Smectiten und Vermiculiten alle Zwischenschichtkationen gegen andere Kationen ausgetauscht werden. In den Glimmern und Illiten sind die Kaliumionen so fest gebunden, daß unter normalen Bedingungen nur die an den Rändern und Außenflächen liegenden Kationen ausgetauscht werden; das Kationenaustauschvermögen ist wesentlich kleiner als die Menge der austauschfähigen Kationen (Tabelle 3.1).
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Literatur
Abudelgawad G, Viani BE, Dixon JB (1985) Palygorskit separation from dodecylammonium-treated clays. Clays Clay Min 33: 438
Ahn JH, Peacor DR (1986) Transmission and analytical electron microscopy of the smectite-to-illite transition. Clays Clay Min 34: 165; 180
Alther G (1986) The effect of the exchangeable cations on the physicochemical properties of Wyoming bentonites. Appl Clay Sci 1: 273
Andreoli CY, Robert M, Pons CH (1989) First steps of smectite-illite transformation with humecation and desiccation cycles. Appl Clay Sci 4: 423
Annabi-Bergaya F, Cruz IM, Gatineau L, Fripiat J J (1981) Adsorption of alcohols by smectites. Clay Min 16: 115
Armstrong DE, Chesters G (1964) Properties of protein-bentonite complexes as influenced by equilibration conditions. J Soil Sci 98: 39
Babich H, Stotzky G (1980) Reductions in inactivation rates of bacteriophages by clay minerals in lake water. Water Res 14: 185
Barak P (1989) Double layer theory prediction of Al-Ca exchange on clay and soil. J Colloid Interface Sci 133: 479
Barrer RM (1986) Expanded clay minerals. J Inclusion Phenomena 4: 109
Barrer RM (1989) Clay minerals as selective and shape-selective sorbents. Pure Appl Chem 61: 1903
Barshad I (1969) Preparation of H saturated montmorillonite. Soil Sci 108: 38
Bell TE (1986) Microstructure in mixed-layer illite/smectite and its relationship to the reaction of smectite to illite. Clays Clay Min 34: 146
Beneke K, Lagaly G (1982) The brittle mica-like KNiAsO4 and its organic derivatives. Clay Min 17: 175
Bergseth H, Singh BR, Stuanes A (1974) Deviation from equivalent ion exchange in humus material using 89Sr2+ for determination of cation exchange capacity. Coll Polym Sei 252: 555
Bergseth H (1980) Selektivität von Illit, Vermiculit und Smectit gegenüber Cu2+, Pb2+, Zn2+, Cd2+ und Mn2+. Acta Agriculturae Scan 30: 460
Bergseth H (1982) Einfluß von Temperaturerhöhung auf die Selektivität eines suspendierten Vermiculits gegenüber Cu2+, Zn2+ und Cd2+. Acta Agriculturae Scan 32: 373
Berkheiser V, Mortland MM (1975) Variability in exchange ion position in smectite: Dependence on interlayer solvent. Clays Clay Min 23: 404
Besson G, Mifsud C, Tschoubar C, Mering J (1974) Order and disorder relations in the distribution of the substitutions in smectites, illites and vermiculites. Clays Clay Min 22: 379
Botero IY, Bruant M, Cases IM, Canet D, Fiessinger F (1988) Adsorption of nonionic polyacrylate on sodium montmorillonite. J Colloid Interface Sci 124: 515
Braganza LF, Crawford RJ, Smalley MV, Thomas RK (1990) Swelling of butylammonium vermiculite in water. Clays Clay Min 38: 90
Brandenburg U, Lagaly G (1988) Rheological properties of sodium montmorillonite dispersions. Appl Clay Sci 3: 263
Brindley GW, Ray S (1964) Complexes of Ca-montmorillomte with primary monohydric alcohols. Am Min 49: 106
Brindley GW (1966) Ethylene glycol and glycerol complexes of smectites and vermiculites. Clay Min 6: 237
Brindley GW, Thompson TD (1970) Methylene blue adsorption by montmorillonites. Determination of surface areas and exchange capacities with different initial cation saturations. Israel J Chem 8: 409
Brindley GW, Ertem G (1971) Preparation and solvation properties of some variable charge montmorillonites. Clays Clay Min 19: 399
Brouwer E, Baeyens B, Maes A, Cremers A (1983) Cesium and rubidium ion exchange equilibria in illite clay. J Phys Chem 87: 1213
Cady SS, Pinnavaia TJ (1978) Porphyrin intercalation in mica-type silicates. Inorg Chem 17: 1501
Cairns-Smith AG, Hartmann H (1986) Clay minerals and the origin of life. Cambridge University Press
De la Calle C, Suquet H, Dubernat J, Pezerat H (1978) Mode d’empilement des feuillets dans les vermiculites hydratées à deux couches. Clay Min 13: 275
Calvert CS (1984) Simplified complete CsCl-hydrazine-dimethylsulfoxide intercalation of kaolinite. Clays Clay Min 32: 125
Carr RM, Chin H (1971) Complexes of halloysite with organic compounds. Clay Min 9: 153
Cebula DJ, Thomas RK, White JW (1981) Diffusion of water in Li+-montmorillonite studied by quasi-elastic neutron scattering. Clays Clay Min 29: 241
Cenens J, Schoonheyd RA (1988) Visible spectroscopy of methylene blue on hectorite, laponite B, and barasym in aqueous suspension. Clays Clay Min 36: 214
Chenu C, Pons CH, Robert M (1987) Interaction of kaolinite and montmorillonite with neutral polysaccharides. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Internat Clay Conf, Denver 1985. The Clay Mineral Soc, Bloomington, Indiana pp 375–381
Chenu C, Jaunet AM (1990) Modification de l’organisation texturale d’une montmorillonite calcique liées à l’adsorption d’un polysaccharide. C R Acad Sci Paris, t 310, Serie II, 975
Clementz DM (1976) Interaction of petroleum heavy ends with montmorillonite. Clays Clay Min 24: 312
Cornejo J, Steinle J, Boehm HP (1978) Die Oberflächenacidität von Titandioxid und von mit Phosphationen belegtem Titandioxid. Z Naturforsch 33b: 1238
Costanzo PM, Giese RF (1990) Ordered and disordered organic intercalates of 8.4-Å, synthetically hydrated kaolinite. Clays Clay Min 38: 160
Czarnecka E, Gillot JE (1980) Formation and characterization of clay complexes with bitumen from Athabasca oil sand. Clays Clay Min 28: 197
Dean KR, McAtee JL (1986) Asphaltene adsorption on clay. Appl Clay Sci 1: 313
Dékány I, Szántó F, Weiss A, Lagaly G (1985) Interlamellar liquid sorption on hydrophobic silicates. Ber Bunsenges Phys Chem 89: 62
Dékány I, Szántó F, Weiss A, Lagaly G (1986) Interactions of hydrophobic layer silicates with alcohol-benzene mixtures. Ber Bunsenges Phys Chem 90: 422
Delville A, Grangjean J, Laszlo P (1991) Order aquisition by clay platelets in a magnetic field. NMR study of the structure and microdynamics of the adsorbed water layer. J Phys Chem 95: 1383
Dodson PJ, Somasundaran P (1984) Desorption of polyacrylamide and hydrolized polyacrylamide from kaolinite surface. J Colloid Interface Sci 97: 481
El-Amamy MM, Mill Th (1984) Hydrolysis kinetics of organic chemicals on montmorillonite and kaolinite surfaces as related to moisture content. Clays Clay Min 32: 67
Ertem G (1972) Irreversible collapse of montmorillonite. Clays Clay Min 29: 199
Fahn R, Weiss A, Hofmann U (1953) Über die Thixotropie bei Tonen. Ber Dtsch Keram Ges 30: 21
Farmer VC, Mortland MM (1966) An infrared study of the coordination of pyridine and water to exchangeable cations in montmorillonite and saponite. J Chem Soc A: 344
Favre H, Lagaly G (1991) Organobentonite with quaternary alkylammonium ions. Clay Min 26: 19
Fenoll Hach-Ali P, Weiss A (1969) Estudio de la reacción de caolinita y n-metilformamida. Anales de la Real Sociedad Española de Física y Química, tomo LXV: 769
Fernandez-Gonzales M, Weiss A, Lagaly G (1976) Über das Verhalten nordwest-spanischer Kaoline bei der Bildung von Einlagerungsverbindungen. Keram Z 28: 55
Ferris AP, Jepson WB (1974) The exchange capacities of kaolinite and the preparation of homoionic clays. J Colloid Interface Sci 51: 245
Fitzsimmons RF, Posner AM, Quirk JP (1970) Electron microscopic and kinetic study of the flocculation of calcium montmorillonite. Israel J Chem 8: 301
Frey E, Lagaly G (1979) Selective coagulation in mixed colloidal suspensions. J Colloid Interface Sci 70: 46
Fripiat JJ (1973) Time concepts in surface chemistry. In: Serratosa JM (ed) Proc Intern Clay Conf Madrid, 1972. Div de Ciencias, CSIC Madrid, pp 537–547
Fripiat J J (1977) Mobility of physically adsorbed hydroxylic molecules on surfaces made from oxygen atoms. J Colloid Interface Sci 58: 511
Fripiat JJ, Cases J, Francois M, Letellier M (1982) Thermodynamic and microdynamic behavior of water in clay suspensions and gels. J Colloid Interface Sci 89: 378
Fukushima Y (1984) X-ray diffraction study of aqueous montmorillonite emulsions (richtig: dispersions). Clays Clay Min 32: 320
Gast RG, Klobe WD (1971) Sodium - lithium exchange equilibria on vermiculite at 25° and 50 °C. Clays Clay Min 19: 311
Gast RG (1972) Alkali metal cation exchange on Chambers montmorillonite. Soil Sci Soc Am Proc 36: 14
Ghabru SK, Mermut AR, Arnaud RI (1989) Layer-charge and cation-exchange characteristics of vermiculite (weathered biotite) isolated from an Gray Luvisol in Northeastern Saskatchewan. Clays Clay Min 37: 164
Glaeser R, Mering J (1976) Influence du taux de substitution isomorphique en couche tetraedrique sur les propriétés et l’organisation structurale des smectites dioctaedriques. In: Bailey SW (ed) Proc Internat Clay Conf Mexico 1975. Appl Pub, Wilmette, Illinois, USA, pp 173–183
Graf G, Lagaly G (1980) Interaction of clay minerals with adenosine-5-phosphates. Clays Clay Min 28: 12
Greenland DJ (1963) Adsorption of polyvinylalcohols by montmorillonite. J Colloid Sci 18: 647
Heller L, Yariv S (1970) Anilinium montmorillonites and the formation of ammonium/amine associations. Israel J Chem 8: 391
Herrmann H, Lagaly G (1985) ATP-clay interactions. In: Konta J (ed) Proc European Clay Conf Prague 1983. Karls Universität, Prag, pp 269–277
Hirsch D, Nir S, Banin A (1989) Prediction of cadmium complexation in solution and adsorption to montmorillonite. Soil Sci Soc Am J 53: 716
Hofmann U, Hausdorf A (1945) Über das Sedimentvolumen und die Quellung von Bentonit. Kolloid Z Z Polymere 110: 1
Hofmann U, Fahn R, Weiss A (1957) Thixotropie bei Kaolinit und innerkristalline Quellung bei Montmorillonit. Kolloid Z Z Polymere 151: 97
Hofmann U (1961) Geheimnisse des Tons. Der Dtsch Keram Ges 38: 201
Hofmann U (1962) Die Tonminerale und die Plasitizität des Tons. Keram Z 14: 14
Hofmann U (1964) Oberflächenladung und Rheologie der Tonminerale. Ber Dtsch Keram Ges 41: 680
Hollander AF, Somasundaran P, Gryte CC (1981) Adsorption of Polyacrylamide and sulfonated Polyacrylamide on Na-kaolinite. In: Tewari PH (ed) Adsorption from aqueous solutions. Plenum Press, New York, London, pp 143–162
Hougardy J, Stone WEE, Fripiat JJ (1976) NMR-study of adsorbed water. I. Molecular orientation and protonic motions in the two-layer hydrate of a Na-vermiculite. J Chem Phys 64: 3840
Hsieh YP (1989) Effects of relative humidity on the basal expansion of Mg-smectite equilibrated with ethylene glycol at low vapor pressure. Clays Clay Min 37: 459
Inoue A, Minato H (1979) Ca-K exchange reaction and interstratification in montmorillonite. Clays Clay Min 27: 393
Jackson ML, Abdel-Kader FH (1978) Kaolinite intercalation procedure for all sizes and types with XRD spacing distinctive from other phyllosilicates. Clays Clay Min 26: 81–87
Jaynes WF, Bigham JM (1987) Charge reduction, octahedral charge, and lithium retention in heated, Li+-saturated smectites. Clays Clay Min 35: 440
Karickhoff SW, Bailey GW (1976) Protonation of organic bases in clay-water systems. Clays Clay Min 24: 170
Keller WD, Haenni RP (1978) Effects of micro-sized mixtures of kaolin minerals on properties of kaolinites. Clays Clay Min 26: 384
Kjellander R, Marcelja S, Quirk JP (1988) Attractive double layer interactions between calcium clay particles. J Colloid Interface Sci 126: 194
Kleíjn WB, Oster JD (1982) A model of clay swelling and tactoid formation. Clays Clay Min 30: 383
Klimentides RE, Mackinnon IDR (1986) High-resolution imaging of ordered mixed-layer clays. Clays Clay Min 34: 155
Kodama H, Ross GJ, Toshimichi J, Robert JW (1974) Effect of layer charge location on potassium exchange and hydration of micas. Am Min 59: 491
Kraehenbuehl F, Stoeckli HF, Brunner F, Kahr G, Müller-Vonmoos M (1987) Study of the water bentonite system by vapour adsorption, immersion calorimetry and X-ray techniques. Clay Min 22: 1
Kulicke WM (1986) Zum Fließverhalten von Stoffen und Stoffgemischen. Hüthig und Wepf, Basel
Lagaly G (1976) Kinkblock- und Gaucheblockstrukturen bimolekularer Filme. Angew Chem 88: 628
Lagaly G, Fernandez-Gonzales M, Weiss A (1976) Problems in layer charge determination of montmorillonites. Clay Min 11: 173
Lagaly G (1979) The “layer-charge” of regular interstratified 2/1 clay minerals. Clays Clay Min 27: 1
Lagaly G (1981) Characterization of clays by organic compounds. Clay Min 16: 1
Lagaly G, Müller-Vonmoos M, Kahr G, Fahn R (1981) Vorgänge bei der Sodaaktivierung von Bentoniten am Beispiel eines Bentonits von Neuseeland. Keram Z 33: 278
Lagaly G (1982) The layer charge heterogeneity in vermiculites. Clays Clay Min 30: 215
Lagaly G (1984) Clay-organic reactions. Phil Trans R Soc London A 311: 315
Lagaly G (1986) Smectitic clays as ionic macromolecules. In: Wilson AD, Prosser HJ (eds) Developments of ionic polymers, vol 2. Elsevier, London, pp 77–140
Lagaly G (1986) Colloids. Ullmann’s Encyclopedia of Industrial Chemistry, Vol A7, pp 341–367
Lagaly G (1987) Water and solvents on surfaces bristling with alkyl chains. In: Kleeberg H (ed) Interactions of water in ionic and nonionic hydrates. Springer, Berlin Heidelberg, pp 229–240
Lagaly G (1989) Principles of flow of kaolin and bentonite dispersions. Appl Clay Sci 4: 105
Lagaly G, Malberg R (1990) Disaggreagation of alkylammonium montmorillonites in organic solvents. Colloids and Surfaces 49: 11
Lagaly G (1991) Erkennung und Identifizierung von Tonmineralen mit organischen Stoffen. In: Tributh H, Lagaly G (Hrsg) Identifizierung und Charakterisierung von Tonmineralen. DTTG, Gießen 1991, S 86–130
Lagaly G (1992) From clay mineral crystals to colloidal clay mineral dispersions. In: Dobias B (ed) Coagulation and flocculation: theory and application. Marcel Dekker, pp 427–494
Lahav N (1990) Preparation of stable suspensions of delaminated kaolinite by combined dimethylsulfoxide-ammonium fluoride treatment. Clays Clay Min 38: 219
Lailach GE, Brindley GW (1969) Specific co-adsorption of purines and pyrimidines by montmorillonite. Clays Clay Min 17: 95
Laird DA, Scott AD, Fenton TL (1989) Evolution of the alkylammonium method for determining layer charge. Clays Clay Min 37: 41
Larsson N, Siffert B (1983) Formation of lysozyme-containing crystals of montmorillonite. J Colloid Interface Sci 93: 424
Laudelout H, van Bladel R, Bolt GH, Page AL (1968) Thermodynamics of heterovalent cation exchange reaction in a montmorillonite clay. Trans Farad Soc 64: 1477
Laura RD, Cloos P (1975) Adsorption of ethylene diamine on montmorillonite saturated with different cations, IV, V. Clays Clay Min 23: 343, 417
Levy R, Francis CW (1975) Interlayer adsorption of polyvinylpyrrolidone on montmorillonite. J Colloid Interface Sci 50: 442
Levy R, Francis CW (1975) A quantitative method for the determination of montmorillonite in soils. Clays Clay Min 23: 85
Lim CH, Jackson ML (1986) Expandable phyllosilicate reactions with lithium on heating. Clays Clay Min 34: 346
Lipsicas M, Straley C, Costanzo PM, Giese RF (1985) Static and dynamic structure of water in hydrated kaolinites. J Colloid Interface Sci 107: 221
Lipsicas M, Raythatha R, Giese RF, Costanzo PM (1986) Molecular motions, surface interactions, and stacking disorder in kaolinite intercalates. Clays Clay Min 34: 635
Lombardi G, Russel JD, Keller WD (1987) Compositional and structural variations in size fractions of a sedimentary and a hydrothermal kaolin. Clays Clay Min 35: 321
Low PF (1987) The clay-water interface. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Intern Clay Conf, Denver 1985. The Clay Minerals Soc, Bloomington, Indiana, pp 247–256
Lubetkin SD, Middleton SR, Ottewill RH (1984) Some properties of clay water dispersions. Phil Trans R Soc Lond A 311: 353
Luca S de, Slaughter M (1985) Existence of multiple kaolinite phases and their relationship to disorder in kaoline minerals. Am Min 70: 149
Luck WAP (1978) Zur Struktur des Wassers und wäßriger Systeme. Progr Colloid Polymer Sci 65: 6
Madsen F (1977) Surface area measurements of clay minerals by glycerol sorption on a thermobalance. Thermochimica Acta 21: 89
Maes A, Cremers A (1977) Charge density effects in ion exchange, part 1 - Heterovalent exchange equilibria. J Chem Soc Farad Trans I, 73: 1807
Maes A, Verheyden D, Cremers A (1985) Formation of highly selective cesium-exchange sites in montmorillonites. Clays Clay Min 33: 251
Malberg R, Dékány I, Lagaly G (1988) Short-chain alkylammonium montmorillonites and alcohols: gas adsorption and immersional wetting. Clay Min 24: 631
Malla PB, Douglas LA (1987) Identification of expanding layer silicates: layer charge vs expansion properties. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Internat Clay Conf Denver, 1985. The Clay Min Soc Bloomington, Indiana, pp 277–283
Mamy J, Gaultier JP (1975) Étude de l’évolution de l’ordre cristalline dans la montmorillonite en relation avec la diminution d’échangeabilité de potassium. Proc Internat Clay Conf Mexiko, 1975. Appl Pub, Wilmette, Illinois, USA, 1976, pp 149–155
Mareks CH, Wachsmuth H, Reichenbach H Graf von (1989) Preparation of vermiculite for HRTEM. Clay Min 24: 23
Martin H, Laudelout H (1963) Thermodynamique de l’échange des cations alcalins dans les argiles. J Chimie Physique: 1086
Martin-Rubi JA, Rausell-Colom JA, Serratosa JM (1974) Infrared adsorption and X-ray diffraction study of butylammonium complexes of phyllosilicates. Clays Clay Min 22: 87
McAtee JL (1963) Organic cation exchange on montmorillonite as observed by ultraviolet analysis. Clays Clay Min 10: 153
McBride MB, Pinnavaia TJ, Mortland MM (1975) Electron spin resonance studies of cation orientation in restricted water layers on phyllosilicates (smectite) surfaces. J Phys Chem 79: 2430
McBride MB, Pinnavaia TJ, Mortland MM (1975) Perturbation of structural Fe3+ in smectites by exchange ions. Clays Clay Min 23: 103
McBride M (1979) An interpretation of cation selectivity variations in M+-M+ exchange on clays. Clays Clay Min 27: 417
Mering J, Oberlin A (1976) Electron optical study of smectites. Clays Clay Min 15: 3
Mingelgrin K, Tsvetkov F (1985) Surface condensation of organo-phosphate esters on smectites. Clays Clay Min 33: 62
Moinereau J (1977) Adsorption de composes humiques par une montmorillonite H+, Al3+. Clay Min 12: 75
Mortland MM, Raman KV (1968) Surface acidity of smectites in relation to hydration, exchangeable cation, and structure. Clays Clay Min 16: 393
Moshi AO, Wild A, Greenland DJ (1974) Effect of organic matter on the charge and phosphate adsorption of Kikuyu Red Clay from Kenya. Geoderma 11: 275
Muljadi D, Posner AM, Quirk JP (1966) The mechanism of phosphate adsorption by kaolinite, gibbsite and pseudoboehmite. J Soil Sci 17: 212
Mulla DJ, Low PF (1983) The molar absorptivity of interparticle water in clay-water systems. J Coll Interf Sci 95: 51
Müller-Vonmoos M, Kahr G, Madsen FT (1991) Bestimmung der Zwischenschichtladung von Smectit-Illit-Wechsellagerungen in Kaolin-Bentoniten. In: Tributh H, Lagaly G (Hrsg) Identifizierung und Nachweis der Tonminerale, DTTG, Gießen, S 131–155
Nadeau PH (1985) The physical dimensions of fundamental clay particles. Clay Min 20: 499
Nadeau PH (1987) Clay particle engineering: a potential new technology with diverse applications. Appl Clay Sci 2: 83
Napper DH (1983) Polymeric stabilization of colloidal dispersions. Acad Press, London New York
Narine DR, Guy RD (1981) Interaction of some large organic cations with bentonite in diluted aqueous systems. Clays Clay Min 29: 205
Nir S (1986) Specific and nonspecific cation adsorption to clays: solution concentrations and surface potentials. Soil Sci Soc Am J 50: 52
Nir S, Hirsch D, Navrot J, Banin A (1986) Specific adsorption of lithium, sodium, potassium, and strontium to montmorillonite; observations and predictions. Soil Sci Soc Am J 50: 58
Norrish K, Rausell-Colom JA (1963) Low-angle X-ray diffraction studies of the swelling of montmorillonite and vermiculite. Clays Clay Min 12: 123
O’Brian NR (1971) Fabric of kaolinite and illite floccules. Clays Clay Min 19: 353
Olis AC, Malla PB, Douglas LA (1990) The rapid estimation of the layer charges of 2:1 expanding clays from a single alkylammonium ion expansion. Clay Min 25: 39
Olness A, Clapp CE (1973) Occurence of collapsed and expanded crystals in montmorillonite-dextran complexes. Clays Clay Min 21: 289
Olphen H van (1968) Modification of the clay surface by pyridine-type compounds. J Colloid Interf Sci 28: 370
Olphen H van (1977) An introduction to clay colloid chemistry. Wiley, New York
Overbeek JThG (1977) Recent developments in the understanding of colloid stability. J Colloid Interf Sci 58: 408
Parfitt RL, Greenland DJ (1970) Adsorption of polysaccharides by montmorillonite. Soil Sci Soc Am Proc 34: 862
Parfitt RL, Greenland DJ (1970) Adsorption of poly(ethylene glycols) on clay minerals. Clay Min 8: 305; 317
Perez-Rodriguez JL, Wüson MJ (1969) Effects of pretreatment on a 14 Å swelling mineral from Gartley, Aberdeenshire. Clay Min 8: 39
Pham Thi Hang, Brindley GW (1970) Methylene blue adsorption by clay minerals. Determination of surface areas and cation exchange capacities. Clays Clay Min 18: 203
Pinnavaia TJ, Hall PL, Cady SS, Mortland MM (1974) Aromatic radical cation formation on the intracrystal surfaces of transition metal layer lattice silicates. J Phys Chem 78: 994
Plancon A, Giese RF, Snyder R (1988) The Hinckley index for kaolinites. Clay Min 23: 249
Range KJ, Range A, Weiss A (1968) Zur Existenz von Kaolinithydraten. Z Naturforsch 23b: 1144
Range KJ, Range A, Weiss A (1969) Fire-clay type kaolinite or fire-clay mineral? Experimental classification of kaolinite-halloysite minerals. In: Heller L (ed) Proc Internat Clay Conf Tokyo, 1969. Israel Univ Press, Jerusalem, pp 3–13
Rao KPC, Krishna Murti GSR (1987) Influence of noncrystalline material on phosphate adsorption by kaolin and bentonite clays. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Internat Clay Conf, Denver, 1985. The Clay Minerals Soc, Bloomington, Indiana, pp 179–185
Rausell-Colom JA, Salvador PS (1971) Gelification de vermiculite dans des solution d’acide γ-amino butyrique. Clay Min 9: 193
Rausell-Colom JA, Saez-Aunon, Pons CH (1989) Vermiculite gelation: structural and textural evolution. Clay Min 24: 459
Reiehenbach H Graf von (1966) Anomalien des Kationenaustausches bei Vermiculiten. Z Pflanz Bodenk 113: 203
Reichenbach H Graf von, Rich CI (1969) Potassium release from muscovite as influenced by particle size. Clays Clay Min. 17: 23
Reichenbach H Graf von (1973) Exchange equilibria of interlayer cations in different particle size fractions of biotite and phlogopite. In: Serratosa JM (ed) Proc Intern Clay Conf Madrid 1972, Div de Ciencias, CSIC, Madrid, pp 457–466
Reynolds RC (1965) An X-ray study of an ethylene glycol montmorillonite complex. Am Min 50: 990
Roper MM, Marshall KC (1978) Effects of a clay mineral on microbial predation and parasitism of Escherichia coli. Microbial Ecology 4: 279
Ross GJ, Rich CI (1973) Effect of particle thickness on potassium exchange from phlogopite. Clays Clay Min 21: 77
Ruehlicke G, Kohler EE (1981) A simplified procedere for determining layer charge by the n-alkylammonium method. Clay Min 16: 305
Rühlicke G, Niederbudde EA (1985) Determination of layer charge density of expandable 2:1 clay minerals in soils and loess sediments using the alkylammonium method. Clay Min 20: 291
Rupert JP (1973) Electron spin resonance spectra of interlamellar copper(II)-arene complexes on montmorillonite. J Phys Chem 77: 784
Samii AM, Lagaly G (1987) Adsorption of nuclein bases on smectites. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Internat Clay Conf Denver, 1985. The Clay Minerals Soc, Bloomington, Indiana, pp 363–369
Schnitzer M, Kodama H (1972) Reactions between fulvic acid and Cu2+-montmorillonite. Clays Clay Min 20: 359
Schön G, Staudt U, Wendel R (1976) Über den Einfluß von einwertigen Zwischenschichtkationen auf die elektrische Leitfähigkeit von Vermiculiten in verschiedenen Hydrationszuständen. Colloid Polym Sci 254: 1000
Schramm LL, Kwak JCT (1982) Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspensions. Clays Clay Min 30: 40
Schwertmann U (1962) Die selektive Kationenadsorption der Tonfraktion einiger Böden aus Sedimenten. Z Pflanzenern Bodenk 97: 9
Schwertmann U (1969) Aggregation of aged hydrogen clays. In: Heller L (ed) Proc Internat Clay Conf Tokyo, 1969. Israel University Press, Jerusalem, pp 683–690
Scott AD, Ismail FT, Locaties RR (1973) Changes in interlayer potassium exchangeability induced by heating micas. In: Serratosa JM (ed) Proc Intern Clay Conf Madrid 1972. Div de Ciencias, CSIC, Madrid, pp 467–479
Serratosa JM (1966) Infrared analysis of the orientation of pyridine molecules in clay complexes. Clays Clay Min, Proc 14th Nat Conf, pp 385–391
Shainberg I, Kemper WD (1966) Hydration status of adsorbed ions. Soil Sci Soc Am Proc 30, 707;
Shainberg I, Alperoviteh, Keren R (1987) Charge density and Na-K-Ca exchange on smectites. Clays Clay Min 35: 68
Shawhney BL (1972) Selective sorption and fixation of cations by clay minerals: a review. Clays Clay Min 20: 93
Siffert B, Espinasse P (1980) Adsorption of diacids and sodium polyacrylate onto montmorillonite. Clays Clay Min 28: 381
Slade PG, Telleria MI, Radoslovich EW (1976) The structures of ornithine-vermiculite and 6-aminohexanoic acid-vermiculite. Clays Clay Min 24: 134
Smalley MV, Thomas RK, Braganza LF, Matsuo T (1989) Effect of hydrostatic pressure on the swelling of n-butylammonium vermieulite. Clays Clay Min 37: 474
Sposito G, Prost R (1982) Structure of adsorbed water on smectites. Chem Rev 82: 553
Stanjek H, Friedrich R (1986) The determination of layer charge by curve-fitting of Lorentz- and polarization corrrected X-ray diagrams. Clay Min 21: 183
Stul MS, Mortier WJ (1974) The heterogeneity of the charge density in montmorillonites. Clays Clay Min 22: 391
Stul MS, van Leemput L, Leplat L, Uytterhoeven JB (1983) The adsorption of organic vapors on alkylammonium smectites, the influence of mineral charge density and monofunctional ammonium cation type. J Colloid Interf Sci 94: 154
Stutz E, Kahr G, Défago G (1989) Clays involved in suppression of tobacco black root rot by a strain of Pseudomonas fluorescens. Soil Biol Biochem 21: 361
Stutzmann Th, Siffert B (1970) Contribution to the adsorption mechanism of acetamide and Polyacrylamide onto clays. Clays Clay Min 25: 392
Suquet H, de la Calle C, Pézérat H (1975) Swelling and structural organization of saponite. Clays Clay Min 23: 1
Suquet H, Jiyama JT, Kodama H, Pézérat H (1977) Synthesis and swelling properties of saponites with increasing layer charge. Clays Clay Min 25: 231
Suquet H, Pézérat H (1987) Parameters influencing layer stacking types in saponite and vermiculite: a review. Clays Clay Min 35: 353
Szántó F, Gilde M (1973) Rheological properties and thixotropic behaviour of kaolinite suspensions. Acta Universitas Szegediensis, Acta Physica et Chimica, Vol. XIX, 3: 291
Talibudeen O (1954) Complex formation between montmorillonoid clays and amino-acids and protein. Trans Farad Soc 51: 582
Tazaki K, Kimura S, Yoshima T, Akai J, Fyfe WS (1989) Clay organic complexes as a cementing agent in the Arahama sand dune, Japan. Clays Clay Min 37: 219
Tazaki K, Fyfe WS, Fukushima K, Fukani A (1990) Wet-to dry transition of smectite as revealed by humidity-controlled electron microscopy. Clays Clay Min 38: 327
Teileria MI, Slade PG, Radoslovich EW (1977) X-ray study of the interlayer region of a barium-vermiculite. Clays Clay Min 25: 119
Theng BKG (1974) The chemistry of clay-organic reactions. Hilger, London
Theng BKG (1979) Formation and properties of clay-polymer complexes. Elsevier, Amsterdam
Thompson TD, Brindley GW (1969) Adsorption of pyrimidines, purines, and nucleotides by Na-, Mg- and Cu-illite. Am Min 54: 858
Tisdall JM, Oades JM (1982) Organic matter and water-stable aggregates in soils. J Soil Sci 33: 141
Tombácz E, Balász J, Lakatos J, Szántó F (1989) Influence of the exchangeable cations on stability and rheological properties of montmorillonite suspensions. Coll Polym Sci 267: 1016
Tombácz E, Gilde M, Abraham I, Szántó F (1990) Effect of sodium chloride on interactions of fulvic acid and fulvate with montmorillonite. Appi Clay Sci 5: 101
Touillaux R, Salvador P, Vandermeersche C, Fripiat JJ (1968) Study of water layers adsorbed on Na- and Ca-montmorillonite by the pulsed nuclear magnetic resonance technique. Israel J Chem 6: 337
Tributh H, Lagaly G (1986) Aufbereitung und Identifizierung von Boden- und Lagerstättentonen. GIT Fachz Lab 30: 524; 771
Ueda T, Harada S (1968) Adsorption of cationic polysulfone on bentonite. J Appi Polym Sci 12: 2395
Vali H, Bachmann L (1988) Ultrastructure and flow behaviour of colloidal clay dispersions. J Colloid Interf Sci 126: 278
Vansant EF, Uytterhoeven JB (1972) Thermodynamics of the exchange of n-alkylammonium ions on Na-montmorillonite. Clays Clay Min 20: 47
Vogt K, Köster HM (1978) Zur Mineralogie, Kristallchemie und Geochemie einiger Montmorillonite aus Bentoniten. Clay Min 13: 25
Wada K (1961) Lattice expansion of kaoline minerals by treatment with potassium acetate. Am Min 46: 78
Weiss A, Hofmann U (1951) Batavit. Z Naturforsch 6b: 405
Weiss A, Mehler A, Koch G, Hofmann U (1956) Über das Anionenaustauschvermögen der Tonminerale. Z anorg allgem Chem 284: 247
Weiss A (1958) Der Kationenaustausch bei den Mineralen der Glimmer-, Vermiculit- und Montmorillonitgruppe. Z anorg allgem Chem 297: 257
Weiss A (1958) Über äquimolaren Kationenaustausch bei niedrig geladenen Ionenaustauschern. Kolloid Z 158: 22
Weiss A, Frank R (1961) Über den Bau der Gerüste in thixotropen Gelen. Z Naturforsch 16b: 141
Weiss A (1962) Neuere Untersuchungen über die Struktur thixotroper Gele. Rheologica Acta 2: 292
Weiss A (1963) Ein Geheimnis des chinesischen Porzellans. Angew Chem 75: 736
Weiss A (1963) Organische Derivate von glimmerartigen Schichtsilicaten. Angew Chem 75: 113
Weiss A (1963b) Mica-type layer silicates with alkylammonium ions. Clays Clay Min 10: 191
Weiss A, Russow J (1963) Über die Lagen der austauschfähigen Kationen bei Kaolinit. In: Rosenqvist IT, Graff-Petersen P (eds) Proc Internat Clay Conf Stockholm, 1963 vol 1. Pergamon Press, London, pp 203 - 213
Weiss A, Häbich A, Weiss A (1964) Einige Eigenschaften der 1. bis 4. Wasserschicht in quellungsfähigen Schichtsilicaten. Ber Dtsch Keram Ges 41: 687
Weiss A, Thielepape W, Orth H (1967) Neue Kaolinit-Einlagerungsverbindungen. Proc Internat Clay Conf Jerusalem, 1966, vol 1. Israel Univ Press, Jerusalem, pp 277–293
Weiss A, Becker HO, Orth H, Mai G, Lechner H, Range KJ (1970) Particle size effects and reaction mechanism of the intercalation into kaolinite. In: Heller L (ed) Proc Internat Clay Conf Tokyo, 1969, vol II. Israel Univ Press, Jerusalem, pp 180–186
Weiss A, Orth H, Ruthard R (1970) Comparison of intercalation compounds of kaolinite and titanium disulfide with acid amides. In: Heller L (ed) Proc Internat Clay Conf Tokyo, 1969, vol II. Israel Univ Press, Jerusalem, pp 194–195
Weiss A, Orth H (1973) Zur Kenntnis der Intercalationsverbindungen von Kaolinit, Nakrit, Dickit und Halloysit. Z Naturforsch 28b: 252
Weiss A (1989) About sealing of waste disposals by clays with special consideration of organic compounds in percolating water. Appl Clay Sci 4: 193
Wendelbo R, Rosenqvist IT (1987) Effects of anion adsorption on mechanical properties of clay-water systems. In: Schultz LG, van Olphen H, Mumpton FA (eds) Proc Internat Clay Conf Denver, 1985. The Clay Minerals Soc, Bloomington, Indiana, pp 422–426
Yariv S, Heller L (1970) Sorption of cyclohexylamine by montmorillonites. Israel J Chem 8: 935
Yariv S, Nasser A, Bar-on P (1990) Metachromasy in clay minerals. J Chem Soc Farad Trans 86: 1593
Young RN, Ohtsubo M (1987) Interparticle action and rheology of kaolinite-amorphous iron hydroxide (ferrihydrite) complexes. Appl Clay Sci 2: 63
Zhang ZZ, Low PF (1989) Relation between the heat of immersion and the initial water content of Li-, Na-, and K-montmorillonite. J Colloid Interf Sci 133: 461
Zhao X, Urano K, Ogasawara S (1989) Adsorption of polyethylene glycol from aqueous solution on montmorillonite clays. Colloid Polymer Sci 267: 899
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Lagaly, G. (1993). Reaktionen der Tonminerale. In: Jasmund, K., Lagaly, G. (eds) Tonminerale und Tone. Steinkopff. https://doi.org/10.1007/978-3-642-72488-6_3
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