Skip to main content

Transformations of Petroleum Hydrocarbons in Nature (Chemical and Biochemical Alteration of Crude Oils)

  • Chapter
Petroleum Hydrocarbons
  • 338 Accesses

Abstract

The present chapter is devoted to the transformation of petroleum hydrocarbons occurring reservoirs, i.e. those that are characteristic of crude oils proper. As will be demonstrated, these transformations may be substantial in causing important modifications in the original hydrocarbon composition of crudes. Ways and mechanisms of these reactions proceeding under a thermal effect (thermolysis), catalytic influence (catalysis), as well as under oxidative impact of microorganisms (biodegradation) have been discussed for years.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Andreev PF, Bogomolov AI, Dobryanskii AF, Kartsev AA (1958) Petroleum transformations in nature. Gostoptekhizdat, Leningrad, 416 pp (in Russian)

    Google Scholar 

  • Arefyev OA, Zabrodina MN, Norenkova IK, Karpenko MN, Makushina VM, Petrov AA (1978) Biological degradation of crudes. Isv USSR Acad Sci Ser Geol 9: 134–139 (in Russian)

    Google Scholar 

  • Arefyev DO, Zabrodina MN, Makushina VM, Petrov AA (1980a) Relict tetra- and pentacyclic hydrocarbons in ancient crudes of the Siberian platform. Isv USSR Acad Sci Ser Geol 3: 135–140 (in Russian)

    Google Scholar 

  • Arefyev OA, Makushina VM, Petrov AA (1980b) Asphaltenes markers in petroleum geochemical history. Isv USSR Acad Sci Ser Geol 4: 124–130 (in Russian)

    Google Scholar 

  • Arkhangelskaya RA, Norenkova IK, Tarasova TG (1978) Impact of oxidation processes on the chemical composition of resinous petroleum fractions. Geol Nefti Gaza 10: 49–54 (in Russian)

    Google Scholar 

  • Bailey N, Jobson A, Rogers M (1973a) Bacterial degradation of crude oil-comparison of field and experimental data. Chem Geol 11: 203–221

    Article  Google Scholar 

  • Bailey N, Krouse H, Evans C, Rogers M (1973b) Alteration of crude oil by water and bacteria. Evidence from geochemical and isotope studies. Am Assoc Petrol Geol Bull 57: 1276

    Google Scholar 

  • Botneva TA, Shulova NS (1981) Genetic types of the near Caspian depression crudes and their compositional prognosis. In: Organic geochemistry of pre-cambrian oils, gases and organic matter. Nauka, Moscow, pp 41–47 (in Russian)

    Google Scholar 

  • Connen J (1984) Biodégradation of crude oils in reservoirs. Advances in petroleum geochemistry, vol 1. Academic Press. London, pp 300–335

    Google Scholar 

  • Connan J, Le Tran K, van der Weide B (1975) Alteration of petroleum in reservoirs. In: Proc 9th World Petrol Congr, Tokyo, vol 2. Appl Sci Publ, Leningrad, pp 171–178

    Google Scholar 

  • Connan J, Restle A, Albrecht P (1979) Biodegradation of crude oils in the Aquitaine basin. In: Advances in organic geochemistry: physics and chemistry of the earth, vol 12. Pergamon, Newcastle, pp 1–17

    Google Scholar 

  • Evans C, Rogers M, Batley N (1971) Evolution and alteration of petroleum in western Canada. Chem Geol 8: 147–170

    Article  Google Scholar 

  • Gabrielyan AG (1981) On the problem of petroleum evolution in natural environment. In: Organic geochemistry of pre-cambrian crude oils, gases and organic matter. Nauka, Moscow, pp 119–125

    Google Scholar 

  • Goodwin N, Park P, Rawlinson T (1981) Crude oil biodégradation. 10th Int Meet Organ Geochem, programme and abstracts. Bergen, p 69

    Google Scholar 

  • Guseva AN, Leifman IE, Vassoyevitch NB (1976) On biogeochemistry of lipids, lipoids and related polymeric compounds. In: Analysis of organic material of contemporary and fossil sediments. Nauka, Moscow, pp 25–56 (in Russian)

    Google Scholar 

  • Hufnagel H, Teschner M, Wehner H (1979) Correlation studies on crude oils and source-rocks in the German Molasse basin. In: Advances in organic geochemistry: physics and chemistry of the earth, vol 12. Pergamon, Newcastle, pp 51–66

    Google Scholar 

  • Jobson A, Cook F, Westlake D (1979) Interaction of aerobic and anaerobic bacteria in petroleum biodégradation. Chem Geol 24: 355–365

    Article  Google Scholar 

  • Kayukova GP, Pustilnikova SD, Abryutina NN, Golovkina LS, Mekhtieva VL, Petrov AA (1981) Structurally modified hydrocarbons of hopane type. Neftekhimiya 21: 803–811 (in Russian)

    Google Scholar 

  • Kayukova GP, Pustilnikova SD, Arefyev OA, Kurbskii GP, Petrov AA (1982) Peculiarities of polycyclic relicts’ distribution in the crude of Tatariya. Neftekhimiya 22: 579–586 (in Russian)

    Google Scholar 

  • Kuklinskii AI, Pushkina RA (1974) Isoprenoid links in chains of saturated petroleum hydrocarbons. Neftekhimiya 14: 520–525 (in Russian)

    Google Scholar 

  • Leifman IE, Guseva AN (1978) On compositional alteration of organic matter, original for the formation of combustible fossils, in the course of the vegetable world’s evolution. In: Accumulation and transformation of organic matter in contemporary and fossil sediments. Nauka, Moscow, pp 9–17 (in Russian)

    Google Scholar 

  • Maksimov SP (ed) (1981) Criteria in crudes’ and gases’ qualitative composition prognosis, issue 22. Nedra, Moscow, 164 pp (in Russian)

    Google Scholar 

  • Martin R, Winters J, Williams I (1964) Occurrence of hydrocarbons in petroleum and its genesis. In: New research in the area of petroleum and gas genesis. CNIITEneftegas, Moscow, pp 38–78 (in Russian)

    Google Scholar 

  • McKirdy D, Aldridge A, Ypma P (1981) A geochemical comparison of crude oils from pre-or- dovician, carbonate rocks. 10th Int Meet Organ Geochem, programme and abstracts. Bergen, pp 144–145

    Google Scholar 

  • McKirdy D, Aldridge A, Ypma P (1983) Geochemical comparison of some crude oils from pre- ordovician carbonate rocks. Advances in organic geochemistry, 1981. Wiley, New York, pp 99–107

    Google Scholar 

  • Milner C, Rogers M, Evans C (1977) Petroleum transformation in reservoirs. J Geochem Explor 7: 101–153

    Article  Google Scholar 

  • Philippi G (1977) On the depth, time and mechanism of origin of the heavy to medium-gravity naphthenic oils. Geochim Cosmochim Acta 41: 33–52

    Article  Google Scholar 

  • Reed W (1977) Molecular compositions of weathered petroleum and comparison with its possible source. Geochim Cosmochim Acta 41: 237–247

    Article  Google Scholar 

  • Rubinstein J, Strausz O, Spyckerelle C et al. (1977) The origin of the oil sand formations of Alberta: a chemical and a microbiological simulation study. Geochim Cosmochim Acta 41: 1341–1353

    Article  Google Scholar 

  • Rubinstein J, Spyckerelle C, Strausz O (1979) Pyrolysis of asphaltenes: a source of geochemical information. Geochim Cosmochim Acta 43: 1–6

    Article  Google Scholar 

  • Safonova GI (1974) Catagenetic alterations of crudes in deposits. Nedra, Moscow 151 pp (Tr Vsesoyuznogo Nauchno-Issledovatelskogo Geol Neftyanogo Inst, issue 145, in Russian)

    Google Scholar 

  • Seifert W, Moldowan J (1979) The effect of biodégradation on steranes and terpanes in crude oils. Geochim Cosmochim Acta 43: 111–126

    Article  Google Scholar 

  • Sokolov VA, Bestuzhev MA, Tikhomolova TV (1972) Chemical composition of crude oils and natural gases in connection with their origins. Nedra, Moscow, 276 pp (in Russian)

    Google Scholar 

  • Tchakhmakhtchev VA (1983) Geochemistry of the process of migration of hydrocarbon systems. Nedra, Moscow, 228 pp (in Russian)

    Google Scholar 

  • Tissot B, Califet-Debyser J, Deroo G, Oudin J (1971) Origin and evolution of hydrocarbons in early toarcian shales. Paris basin, France. Am Assoc Petrol Geol Bull 55 /12: 2177–2193

    Google Scholar 

  • Tissot B, Welte D (1981) Petroleum formation and occurrence. Mir, Moscow, 501 p (in Russian)

    Google Scholar 

  • Uspenskii VA (1970) Introduction to petroleum geochemistry. Nedra, Leningrad, 309 pp (in Russian)

    Google Scholar 

  • Vassoyevitch NB (1958) Petroleum formation in Terrigenic depositions. Tr Vsesoyuznogo Naut- chno-Issledovatelskogo Geol-Razvedotchnogo Inst, issue 128: 9–205 (in Russian)

    Google Scholar 

  • Wen-Yen Kuang, Meinschein W (1979) Sterols as ecological indicators. Geochim Cosmochim Acta 43: 739–745

    Article  Google Scholar 

  • Zabrodina MN, Arefyev OA, Norenkova IK, Makushina VM, Arkhangelskaya RA, Petrov AA (1981) Biodégradation of crudes in the Starogroznenskoe deposit. Isv USSR Acad Sci Ser Geol 9: 126–132 (in Russian)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1987 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Petrov, A.A. (1987). Transformations of Petroleum Hydrocarbons in Nature (Chemical and Biochemical Alteration of Crude Oils). In: Petroleum Hydrocarbons. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71737-6_7

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-71737-6_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-71739-0

  • Online ISBN: 978-3-642-71737-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics