Abstract
This paper reviews the most recent studies of metal solutions in amines and ethers. The metal solubility can be greatly enhanced by the addition of “crown” and “cryptate” to the solution. Studies are also presented which provide evidence for the existence of the monomer (M) and alkali anion (M−) species. Finally a general equilibrium scheme for all species is presented and the influence of the solvent is discussed.
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References
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Dye, J.L. (1973). Metal Solutions in Amines and Ethers. In: Jortner, J., Kestner, N.R. (eds) Electrons in Fluids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61962-5_6
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DOI: https://doi.org/10.1007/978-3-642-61962-5_6
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