Skip to main content

Palladium based Micro-Membrane for Water Gas Shift Reaction and Hydrogen Gas Separation

  • Conference paper
Microreaction Technology

Abstract

A novel palladium-based micromembrane has been fabricated which has the potential to be used for water gas shift reaction and hydrogen gas separation in catalytic microreaction systems for methanol fuel reforming. The membrane is supported by a copper film that has an array of patterned holes. Copper will also act as a catalyst in the shift reaction that will convert unwanted carbon monoxide gas produced earlier in the microreaction system during methanol fuel reforming into hydrogen which in turn will be separated by the membrane. The novelty of this structure is that we have integrated the water gas shift reactor as well as the hydrogen gas separator in the same structure. The microfabrication process allows for integration of heaters and temperature sensors into the device.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. The Knowledge Foundation, Inc. The latest developments in portable power: Advances in R & D for the commercialization of small fuel cells and battery technologies for use in portable applications, Bethesda, MD, April 29-30 1999.

    Google Scholar 

  2. C. Hebling, A. Heinzel, D. Golombowski, T. Meyer, M. Muller and M. Zedda, “Fuel cells for low power applications, ” in the 3rd International Conference on Microreaction Technology, Frankfurt, Germany, April 18-21 1999. DECHEMA.

    Google Scholar 

  3. M. Datta (chair) and N. Smilanich (co Chair), “Technology Roadmaps: Energy Storage Systems, ” National Electronics Manufacturing Technology Roadmaps, December 1996.

    Google Scholar 

  4. A. G. Knapton, “Palladium Alloys for Hydrogen Diffusion Membranes, ” Platinum Met Rev., 21, pp. 44–50, (1977).

    CAS  Google Scholar 

  5. A. J. Franz, K. F. Jensen and M. A. Schmidt, “Palladium based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions, ” IEEE MEMS, pp. 382–387 (1999)

    Google Scholar 

  6. A. Zheng, F. Jones, J. Fang and T. Cui, “Dehydrogenation of cyclohexane to benzene in a membrane microreactor, ” in the proceedings of 4th Annual Conference on Microreaction Technology, March 5-9, 2000, pp. 284–292, Atlanta, GA, 2000.

    Google Scholar 

  7. S. V. Karnik, M. K. Hatalis and M. V. Kothare, “Issues Involved in Fabrication of a Palladium based Micro-Membrane for Hydrogen Gas Separation, ” Presented at American Institute of Chemical Engineers (AIChE) annual meeting, November 12-17, 2000, Los Angeles, CA.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2001 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Karnik, S.V., Hatalis, M.K., Kothare, M.V. (2001). Palladium based Micro-Membrane for Water Gas Shift Reaction and Hydrogen Gas Separation. In: Matlosz, M., Ehrfeld, W., Baselt, J.P. (eds) Microreaction Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56763-6_30

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-56763-6_30

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-62706-4

  • Online ISBN: 978-3-642-56763-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics