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Ultrafast Phenomena XII pp 636–638Cite as

Ultrafast Infrared Studies of Ligand Rearrangement at Coordinatively Unsaturated Transition Metal Centers

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Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 66))

Abstract

Femtosecond infrared spectroscopy has been applied to the study of ligand rearrangement dynamics of coordinatively unsaturated transition metal complexes. A new site-diffusion model based on the Langevin equation is proposed to describe the observed rearrangement dynamics.

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References

  1. X. Xie, J.D. Simon, ″Picosecond time-resolved absorption studies of the solvation of Cr(CO)5 in alcohols: A unimolecular kinetic model for the formation of Cr(CO)5 (OHR) from photogenerated Cr(CO)5(ROH),″ J. Am. Chem. Soc. 112, 1130–1136, 1990.

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  2. S.E. Bromberg, H. Yang, M.C. Asplund, T. Lian, B.K. McNamara, K.T. Kotz, J.S. Yeston, M. Wilkens, H. Frei, R.G. Bergman, C.B. Harris, ″The mechanism of a C-H bond activation reaction in room-temperature alkane solution,″ Science 278, 260–263, 1997.

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Authors and Affiliations

  1. Department of Chemistry, University of California, Berkeley, CA, 94720, USA

    K.T. Kotz, P.T. Snee, C.K. Payne & C.B. Harris

  2. Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St., Cambridge, MA, 02138, USA

    H. Yang

Authors
  1. K.T. Kotz
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  2. H. Yang
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  3. P.T. Snee
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  4. C.K. Payne
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  5. C.B. Harris
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© 2001 Springer-Verlag Berlin Heidelberg

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Kotz, K., Yang, H., Snee, P., Payne, C., Harris, C. (2001). Ultrafast Infrared Studies of Ligand Rearrangement at Coordinatively Unsaturated Transition Metal Centers. In: Ultrafast Phenomena XII. Springer Series in Chemical Physics, vol 66. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56546-5_188

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  • DOI: https://doi.org/10.1007/978-3-642-56546-5_188

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-62512-1

  • Online ISBN: 978-3-642-56546-5

  • eBook Packages: Springer Book Archive

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