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Particle Chemical Reactions

  • Chapter
The Airborne Microparticle

Abstract

There are several aspects of chemical reactions associated with microparticles that are of considerable interest. Among these are homogeneous gas-phase reactions which produce clusters that grow and coagulate to form nanometer or larger size particles, reactions between reactive gases and pre-existing droplets and solid particles, and precipitation reactions that occur in solutions to produce microcrystals. An elementary example of a gas phase process that produces particulate matter is the reaction between vapors of ammonia and hydrochloric acid to form ammonium chloride smokes when they come in contact.

Given the very small (∼10−6 to 10−14) volume ratios of atmospheric condensed matter to atmospheric gases it may seem very unlikely that chemical reactions occurring on the surface or, for some liquid droplets, in the interior of atmospheric aerosols could play an important role in determining concentrations of critically important atmospheric trace species. However, during the last decade it has been conclusively demonstrated that such heterogeneous processes are extremely important to the chemistry of both the troposphere and stratosphere. C.E. Kolb et al. (1994)

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  1. Department of Chemical Engineering, University of Washington, Box 351750, Seattle, WA, 98185-1750, USA

    Prof. E. James Davis

  2. Institut für Automatisierungstechnik Lehrstuhl für Laseranwendungstechnik und Meßsysteme, Maschinenbau, Ruhr-Universität-Bochum, Universitätsstr. 150, 44780, Bochum, Germany

    Prof. Dr. Gustav Schweiger

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Davis, E.J., Schweiger, G. (2002). Particle Chemical Reactions. In: The Airborne Microparticle. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56152-8_10

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