Skip to main content

Part of the book series: SpringerBriefs in Earth System Sciences ((BRIEFSEARTHSYST))

  • 1492 Accesses

Abstract

After a brief introduction into the marine carbon cycle, the calcite compensation theory and the rain-ratio hypothesis, two theories that may explain glacial to interglacial changes in atmospheric CO2 concentrations are presented. The validity of these theories in the Southern Ocean is tested with B/Ca-reconstructed carbonate ion concentrations of deep and intermediate waters. Deglacial [CO3 2−] excursions reveal a close relationship between changes in the oceanic inorganic carbon system and atmospheric CO2, which follow the predictions of the calcite compensation theory on glacial-interglacial timescales. Short-termed [CO3 2−] variations are likely due to the influence of the biological pump and/or changes in circulation patterns.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Archer D, Maier-Reimer E (1994) Effect of deep-sea sedimentary calcite preservation on atmospheric CO2 concentration. Nature 376:260–263

    Article  Google Scholar 

  • Biscaye PE, Grousset FE, Revel M, Van der Gaast S, Zielinski GA, Vaars A, Kukla G (1997) Asian provenance of glacial dust (stage 2) in the Greenland ice sheet project 2 ice core, summit. Greenland J Geophys Res 102:26765–26781

    Article  Google Scholar 

  • Bory AM, Biscaye P, Svensson A, Grousset F (2002) Seasonal variability in the origin of recent atmospheric mineral dust at NorthGRIP. Greenland Earth Plan Sci Lett 196:123–134. doi:10.1016/S0012-821X(01)00609-4

    Article  Google Scholar 

  • Broecker WS, Peng T-H (1987) The role of CaCO3 compensation in the glacial to interglacial atmospheric CO2 change. Glob Biogeochem Cycles 1:15–29

    Article  Google Scholar 

  • Emerson SR, Hedges JI (2008) Chemical oceanography and the marine carbon cycle. Cambridge University Press, New York

    Book  Google Scholar 

  • Fischer H, Schmitt J, Lüthi D, Stocker TF, Tschumi T, Parekh P, Joos F, Köhler P, Völker C, Gersonde R, Barbante C, Floch ML, Raynaud D, Wolff E (2010) The role of Southern ocean processes on orbital and millennial CO2 variations—a synthesis. Quat Sci Rev 29:193–205

    Article  Google Scholar 

  • Foster LC, Finch AA, Allison N, Andersson C, Clarke LJ (2008) Mg in aragonitic bivalve shells: seasonal variations and mode of incorporation in Arctica Islandica. Chem Geol 254:113–119. doi:10.1016/j.chemgeo.2008.06.007

    Article  Google Scholar 

  • Gaffey SJ, Bronnimann CE (1993) Effects of bleaching on organic and mineral phases in biogenic carbonates. J Sediment Res 63:752–754

    Google Scholar 

  • Harrison SP, Kohfeld KE, Roelandt C, Claquin T (2001) The role of dust in climate changes today, at the last glacial maximum and in the future. Earth-Sci Rev 54(1–3):43–80. doi:10.1016/S0012-8252(01)00041-1

    Article  Google Scholar 

  • Hodell DA, Venz KA, Charles CD, Ninnemann US (2003) Pleistocene vertical carbon isotope and carbonate gradients in the South Atlantic sector of the Southern ocean. G-cubed. doi:10.1029/.2002GC000367

    Google Scholar 

  • Keir RS (1988) On the late pleistocene ocean geochemistry and circulation. Paleoceanography 3:413–445

    Article  Google Scholar 

  • Key RM, Kozyr A, Sabine CL, Lee K, Wanninkhof R, Bullister JL, Feely RA, Millero FJ, Mordy C, Peng T-H (2004) A global ocean carbon climatology: results from global data analysis project (GLODAP). Glob Biogeochem Cycles. doi:10.1029/2004GB002247

    Google Scholar 

  • Köhler P, Fischer H, Munhoven G, Zeebe RE (2005) Quantitative interpretation of atmospheric carbon records over the last glacial termination. Glob Biogeochem Cycles. doi:10.1029/2004GB002345

    Google Scholar 

  • Krause-Nehring J, Klügel A, Nehrke G, Brellochs B, Brey T (2011a) Impact of sample pretreatment on the measured element concentrations in the bivalve Arctica islandica. Geochem Geophys Geosyst 12:Q07015. doi:10.1029/2011GC003630

    Article  Google Scholar 

  • Krause-Nehring J, Thorrold SR, Brey T (2011b) Trace element ratios (Ba/Ca and Mn/Ca) in Arctica islandica shells—is there a clear relationship to pelagic primary production? J Geophys Res-Biogeo (submitted)

    Google Scholar 

  • Krause-Nehring J, Thorrold SR, Brey T (2012) Centennial records of lead contamination in northern Atlantic bivalves (Arctica islandica). Mar Pollut Bull 64:233–240. doi: 10.1016/j.marpolbul.2011.11.028

    Google Scholar 

  • Love KM, Woronow A (1991) Chemical changes induced in aragonite using treatments for the destruction of organic material. Chem Geol 93:291–301. doi:10.1016/0009-2541(91)90119-C

    Article  Google Scholar 

  • Mahowald NM, Yoshioka M, Collins WD, Conley AJ, Fillmore DW, Coleman DB (2006) Climate response and radiative forcing from mineral aerosols during the last glacial maximum, pre-industrial, current and doubled-carbon dioxide climates. Geophys Res Lett 33. doi:10.1029/2006GL026126

  • Marchitto TM, Lynch-Stieglitz J, Hemming SR (2005) Deep Pacific CaCO3 compensation and glacial-interglacial atmospheric CO2. Earth Planet Sci Lett 231:317–336

    Article  Google Scholar 

  • Monnin E (2006) EPICA dome C high resolution carbon dioxide concentrations. doi:10.1594/PANGAEA.47248

  • Nriagu JO (1990) The rise and fall of leaded gasoline. Sci Total Environ 92:13–28. doi:10.1016/0048-9697(1090)90318-O

    Article  Google Scholar 

  • Orsi AH, Whitworth T, Nowlin WD (1995) On the meridional extent and fronts of the Antarctic circumpolar current. Deep Sea Res Pt I(42):641–673

    Article  Google Scholar 

  • Pierrot DEL, Wallace DWR (2006) MS excel program developed for CO2 system calculations. ORNL/CDIAC-105a. Carbon dioxide information analysis center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee. doi:10.3334/CDIAC/otg.CO2SYS_XLS_CDIAC105a

    Google Scholar 

  • Raitzsch M, Hathorne EC, Kuhnert H, Groeneveld J, Bickert T (2011) Modern and late pleistocene B/Ca ratios of the benthic foraminifer planulina wuellerstorfi determined with laser ablation ICP-MS. Geology 39:1039–1042

    Article  Google Scholar 

  • Roe G (2009) On the interpretation of Chinese loess as a paleoclimate indicator. Quat Res 71:150–161

    Article  Google Scholar 

  • Ruth U, Wagenbach D, Steffensen JP, Bigler M (2003) Continuous record of microparticle concentration and size distribution in the central Greenland NGRIP ice core during the last glacial period. J Geophys Res 108:4098–4110. doi:10.1029/2002JD002376

    Article  Google Scholar 

  • Schöne BR, Houk SD, Castro ADF, Fiebig J, Oschmann W, Kröncke I, Dreyer W, Gosselck F (2005) Daily growth rates in shells of Arctica islandica: assessing sub-seasonal environmental controls on a long-lived Bivalve Mollusk. Palaios 20:78–92. doi:10.2110/palo.2003.p2103-2101

    Google Scholar 

  • Sigman DM, Hain MP, Haug GH (2010) The polar ocean and glacial cycles in atmospheric CO2 concentration. Nature 466:47–55

    Article  Google Scholar 

  • Stecher HA, Krantz DE, Lord CJ, Luther GW, Bock KW (1996) Profiles of strontium and barium in Mercenaria mercenaria and Spisula solidissima shells. Geochim Cosmochim Ac 60:3445–3456. doi:3410.1016/0016-7037(3496)00179-00172

    Article  Google Scholar 

  • Steffensen JP (1997) The size distribution of microparticles from selected segments of the Greenland ice core project ice core representing different climatic periods. J Geophys Res 102(C12):26755–26764

    Google Scholar 

  • Steffensen JP, Andersen KK, Bigler M, Clausen HB, Dahl-Jensen D, Fischer H, Goto-Azuma K, Hansson M, Johnsen SJ, Jouzel J, Masson-Delmotte V, Popp T, Rasmussen SO, Röthlisberger R, Ruth U, Stauffer B, Siggaard-Andersen ML, Svensson A, White JWC (2008) High-resolution Greenland ice core data show abrupt climate change happens in few years. Science 321(5889):680–684. doi:10.1126/science.1157707

    Article  Google Scholar 

  • Wiltshire KH, Dürselen C-D (2004) Revision and quality analyses of the Helgoland Reede long-term phytoplankton data archive. Helgoland Mar Res 58:252–268. doi:210.1007/s10152-10004-10192-10154

    Article  Google Scholar 

  • Yu J, Elderfield H (2007) Benthic foraminiferal B/Ca ratios reflect deep water carbonate saturation state. Earth Planet Sci Lett 258:73–86

    Article  Google Scholar 

  • Zielinski GA, Mershon GR (1997) Paleoenvironmental implications of the insoluble microparticle record in the GISP2 (Greenland) ice core during the rapidly changing climate of the pleistocene-holocene transition. Geol Soc Am Bull 109:547–559

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by funding from MARUM. The North-GRIP project was directed and organized by the Department of Geophysics at the Niels Bohr Institute for Astronomy, Physics and Geophysics, University of Copenhagen. It was supported by funding agencies in Denmark(SNF), Belgium (NFSR), France (IFRTP and INSU/CNRS), Germany (AWI), Iceland (RannIs), Japan (MECS), Sweden (SPRS), Switzerland (SNF) and the United States of America (NSF). We wish to thank all the funding bodies and field participants.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Gerrit Lohmann , Franziska Kersten or Katrin Wolff .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 The Author(s)

About this chapter

Cite this chapter

Lohmann, G., Grosfeld, K., Wolf-Gladrow, D., Wegner, A., Notholt, J., Unnithan, V. (2013). Climate Archives. In: Lohmann, G., Grosfeld, K., Wolf-Gladrow, D., Unnithan, V., Notholt, J., Wegner, A. (eds) Earth System Science: Bridging the Gaps between Disciplines. SpringerBriefs in Earth System Sciences. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-32235-8_5

Download citation

Publish with us

Policies and ethics