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Metallocenium Salts of Transition Metal Bisdichalcogenate Anions; Structure and Magnetic Properties

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Conducting and Magnetic Organometallic Molecular Materials

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 27))

Abstract

The properties of the salts based on metallocenium cations and transition metal bisdichalcogenide anions are reviewed and particular attention is paid to the correlation between the magnetic properties correlated and the crystal and molecular structures. The large majority of these salts have crystal structures based on linear chain arrangements of alternating cation (D+) and anion (A−) stacks which are classified in four major structural types, depending on the stacking motifs. The magnetic properties of these salts, which at low temperatures can present a wide range of magnetic order type and phase transitions, are correlated with the type of magnetic interaction between the magnetic building blocks, which in the large majority of the cases can be well described by the McConnell model using spin density calculations.

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Abbreviations

A− :

Anion

AF:

Antiferromagnet (ic, ism)

bds:

Benzene-1, 2-diselenolate

bdt:

Benzene-1, 2-dithiolate

Cp:

Cyclopentadienyl

Cp*:

Pentanethylcyclopentadienyl

D+ :

Cation

dcdmp:

2, 3-Dicyano-5, 6-dimercaptopyrazine

dmio:

1, 3-Dithiol-2-one-4, 5-dithiolate

dmit:

1, 3-Dithiol-2-thione-4, 5-dithiolate

dsit:

2-Thioxo-1, 3-dithiole-4, `5-diselenolate

edt:

Ethylenedithiolate

EPR:

Electron paramagnetic resonance

FAP:

Field aligned paramagnet

FIM:

Ferrimagnet (ic, ism)

FM:

Ferromagnet (ic, ism)

MM:

Metamagnet (ic, ism)

mnt:

Maleonitriledithiolate

SCE:

Saturated Calomel electrode

SF:

Spin-flop

TCNE:

Tetracyanoethylene

TCNQ:

7, 7, 8, 8-Tetracyano-p-quinodimethane

tcbdt:

3, 4, 5, 6-Tetracholorobenzene-1, 2-dithiolate

tds:

(Trifluoromethyl)ethylene diselenolate

tdt:

(Trifluoromethyl)ethylene dithiolate

α-tpdt:

2, 3-Thiophenedithiolate

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Acknowledgments

The authors wish to thank their coworkers for continued collaboration in this field, particularly D. Belo, S. Rabaça, R. Meira, I.C. Santos, M.T Duarte, J. Novoa, C. Rovira and R.T. Henriques. The financial support from Fundação para a Ciência e Tecnologia and MAGMANet network of excellence is gratefully acknowledged.

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Authors and Affiliations

  1. Department Química, Instituto Tecnológico e Nuclear/CFMCUL, P-2686-953, Sacavém, Portugal

    V. Gama & M. Almeida

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  1. V. Gama
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  2. M. Almeida
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Correspondence to M. Almeida .

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Editors and Affiliations

  1. UMR CNRS 6226, Université de Rennes 1, Rennes CX, 35042, France

    Marc Fourmigué

  2. UMR 6226 CNRS, Université de Rennes 1, av. du Général Leclerc 263, Rennes CX, 35042, France

    Lahcène Ouahab

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Gama, V., Almeida, M. (2009). Metallocenium Salts of Transition Metal Bisdichalcogenate Anions; Structure and Magnetic Properties. In: Fourmigué, M., Ouahab, L. (eds) Conducting and Magnetic Organometallic Molecular Materials. Topics in Organometallic Chemistry, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-00408-7_5

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