Abstract
We studied the vibrational structure of reactive S1 cis-stilbene through wavepacket motions generated impulsively at various delay-times. They showed gradual frequency downshift, demonstrating highly anharmonic nature of the excited-state potential and structural evolution with photoisomerization
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References
K. Ishii, S. Takeuchi, and T. Tahara, “A 40-fs time-resolved absorption study on cis-stilbene in solution: observation of wavepacket motion on the reactive excited state”, Chem. Phys. Lett. 398, 400, 2004.
S. Fujiyoshi, S. Takeuchi, and T. Tahara, “Time-resolved impulsive stimulated Raman scattering from excited-state polyatomic molecules in solution”, J. Phys. Chem. A 107, 494, 2003.
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Takeuchi, S., Ruhman, S., Tsuneda, T., Chiba, M., Taketsugu, T., Tahara, T. (2009). Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_99
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DOI: https://doi.org/10.1007/978-3-540-95946-5_99
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