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Substitution- and Temperature-Effects on Hemithioindigo Photoisomerization – The Relevance of Energy Barriers

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Ultrafast Phenomena XVI

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 92))

Abstract

The kinetics of the Z/E-photoisomerization of Hemithioindigo-compounds (HTI) with variations of substitution and temperature are investigated using transient absorption spectroscopy in the visible spectral range. The existence of potential energy barriers in the excited state is demonstrated. These barriers mainly determine the photoisomerization time.Effective tuning of the barriers can be achieved by adequate chemical substitution.

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Author information

Authors and Affiliations

  1. LS für BioMolekulare Optik, LMU München, Oettingenstr. 67, D-80538, Munich, Germany

    T. Cordes, M. Lipp & W. Zinth

  2. TU Berlin, Straße des, 17 Juni 135, D-10623, Berlin, Germany

    T. Schadendorf & K. Rück-Braun

Authors
  1. T. Cordes
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  2. T. Schadendorf
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  3. M. Lipp
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  4. K. Rück-Braun
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  5. W. Zinth
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Corresponding author

Correspondence to T. Cordes .

Editor information

Editors and Affiliations

  1. National Research Council Canada, Sussex Drive 100, Ottawa, K1A 0R6, Canada

    Paul Corkum

  2. Dipto. Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy

    Sandro Silvestri

  3. Technology (MIT), Massachusetts Institute of, Massachusetts Ave. 77, Cambridge, 02139, USA

    Keith A. Nelson

  4. Sektion Physik, Univ. München, Oettingenstr. 67, München, 80538, Germany

    Eberhard Riedle

  5. Lawrence Berkeley National Laboratory, University of California, Cyclotron Road 1, Berkeley, 94720, USA

    Robert W. Schoenlein

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© 2009 Springer-Verlag Berlin Heidelberg

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Cordes, T., Schadendorf, T., Lipp, M., Rück-Braun, K., Zinth, W. (2009). Substitution- and Temperature-Effects on Hemithioindigo Photoisomerization – The Relevance of Energy Barriers. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_103

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  • DOI: https://doi.org/10.1007/978-3-540-95946-5_103

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-95945-8

  • Online ISBN: 978-3-540-95946-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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