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57Fe Mössbauer spectroscopy on the cyclic spin-cluster Fe6(tea)6(CH3OH)6

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ICAME 2005

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Abstract

We present 57Fe Mössbauer spectroscopy experiments on the cyclic spincluster Fe6(tea)6(CH3OH)6 (tea=triethanolaminatot-(-3)). In former studies, the spin cluster has been treated as a homogenous, quasi-one-dimensional spin S=5/2 Heisenberg antiferromagnet. Our experiments reveal spectra, which consists of two different quadrupolar doublets. In consequence, there are two different Fe sites among the hexanuclear iron spin-cluster.

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Authors and Affiliations

  1. Institut fur Physik der Kondensierten Materie, TU Braunschweig, 38106, Braunschweig, Germany

    J. Kreitlow, J. Litterst & S. Sullow

  2. Physikalisches Institut, Universitat Karlsruhe (TH), 76128, Karlsruhe, Germany

    B. Pilawa

Authors
  1. J. Kreitlow
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  2. J. Litterst
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  3. S. Sullow
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  4. B. Pilawa
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Corresponding author

Correspondence to J. Kreitlow .

Editor information

Editors and Affiliations

  1. Université Montpellier II — CNRS, Montpellier, France

    P.-E. Lippens  & J.-C. Jumas  & 

  2. Uiversité Henri Poincaré-Nancy I, Villers-lès-Nancy, France

    J.-M. R. Génin

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Kreitlow, J., Litterst, J., Sullow, S., Pilawa, B. (2006). 57Fe Mössbauer spectroscopy on the cyclic spin-cluster Fe6(tea)6(CH3OH)6 . In: Lippens, PE., Jumas, JC., Génin, JM.R. (eds) ICAME 2005. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-49853-7_81

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  • DOI: https://doi.org/10.1007/978-3-540-49853-7_81

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-49852-0

  • Online ISBN: 978-3-540-49853-7

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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