Abstract
Processes are needed to rapidly and cost-effectively produce highly pure lithium salts for the rechargeable battery sector. Lithium purification is a chemical engineering challenge, due to the low concentration of lithium compared to sodium, potassium, magnesium, calcium, and transition metal ions commonly occurring in lithium brine resources. We describe a Solid Phase Extraction (SPE) process that rejects sodium and potassium, while binding lithium and other higher valent ions. Lithium is then harvested by selective displacement from the SPE column . The rapid equilibration kinetics of SPE composites enables these ion separations to occur in a small SPE column and in one column stage. The chemical parameters of the process are described.
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Molnar R, Weber DS, Burga E, Sawyer V, Spanjers RP, Jaacks JA (2018) N I 43—101 Technical report preliminary economic assessment (Rev. 1) of the Clayton Valley Lithium Project Esmeralda County, Nevada. https://sedar.com/FindCompanyDocuments.do. Accessed 29 Apr 2018
Seeley FG, Baldwin WH (1974) Extraction of lithium from neutral brines using a beta diketone and trioctylphosphine oxide. U.S. Patent 3,793,433
Bentzen EH, Hassan Ghaffari H, Galbraith L, Hammen, RF, Robinson RJ, Hafez SA, Annavarapu S (2013) Preliminary economic assessment on The Bokan Mountain rare earth element project, near ketchikan, Alaska. http://ucore.com/pea/
Hammen R, Hammen J, Hammen C, Lifton J (2013) Separation of rare earth subclasses by using highly specific solid phase extraction columns. In: Proceedings, 52nd annual conference of metallurgists COM 2013, Montréal, QC
Lifton J, Hammen R (2012) The state of the art in separating and purifying the heavy rare earths: solvent exchange, ion exchange, and solid phase extraction, which is the optimal process? In Proceedings, 51st annual conference of metallurgists COM 2012, Niagara Falls, ON
Hammen RF (1993) Chromatographic material. United States Patent 5,240,602, 31 Aug 1993
Hammen; RF (2001) Process for separating a substance from a mixture. United States Patent 6,251,278, 26 June 2001
Hammen RF, Hammen JP (2004) Tethered polymer ligands. United States Patent 6,689,715, 10 Feb 2004
Hammen RF, Hammen JP (2005) Composite matrices with interstitial polymer networks. United States Patent 6,946,070, 20 Sept 2005
Hammen RF, Hammen JP (2007) Composite matrices with interstitial polymer networks. United States Patent 7,201,844, 10 Apr 2007
Hammen RF, Hammen JP (2007) (Missoula, MT), Tethered polymer ligands. United States Patent 7,220,703, 22 May 2007
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© 2018 The Minerals, Metals & Materials Society
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Hammen, R. (2018). Production of Purified Lithium Salts with a One-Stage Solid Phase Extraction. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_216
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DOI: https://doi.org/10.1007/978-3-319-95022-8_216
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Publisher Name: Springer, Cham
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Online ISBN: 978-3-319-95022-8
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