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Plasma Bonding of Plastic Films and Applications

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Abstract

This article reviews “plasma bonding” of plastic films. Polyethylene terephthalate (PET) films can be bonded directly by oxygen plasma irradiation and heat-press at low temperatures of 100–160 °C. Functional groups of COOH and OH are detected on the irradiated surface. The irradiated films are kept in the atmosphere for 6 years, yet they can be bonded tightly. The irradiated surface is extremely active just after the irradiation, and it is still considerably active after 5 years.

Dry- and wet-peel tests on the bonded films suggest that there are two elements, hydrogen bonding and chemical bonding. The films are bonded weakly by these two elements at lower press temperatures because of the major hydrogen bonding, while they are bonded strongly at higher press temperatures because of the major chemical bonding. The hydrogen bonding is broken by water penetration into the interface, causing smaller peel strength under the wet-peel test.

FTIR results on the non-irradiated, irradiated, and bonded samples indicate that the COOH and OH groups are created at the irradiated surface, and they are responsible for the both of hydrogen and chemical bondings. The OH is consumed during the heat-press bonding; then dehydrated condensation reaction can be proposed for the chemical bonding. Cross-linking layer may be the origin for the long lifetime of the irradiated active surface.

The irradiated films are soaked in various liquids, but they do not lose the plasma effects and bonding ability. Only the films soaked in AlCl3 and FeCl3 solutions lose the bonding ability. Then we can keep the irradiated films in the atmosphere without special cares.

It is mentioned on feasible applications of laminated plastic films for back-sheets in solar cell and insulator sheets in EV motor.

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References

  1. S. Adachi, Convertech 354, 40 (2002)

    Google Scholar 

  2. E. Sugimoto, Electron. Parts Mater. 47, 103 (2008)

    Google Scholar 

  3. K. Ino, E. Sugimoto, Convertech 355, 40 (2002)

    Google Scholar 

  4. M. DeBergalis, J. Fluor. Chem. 125, 1255 (2004)

    Article  Google Scholar 

  5. M. Yokura, T. Hayashi, T. Yoshii, Y. Maeda, T. Endo, Trans. Mat. Res. Soc. Japan 35(1), 191 (2010)

    Article  Google Scholar 

  6. N. Inagaki, K. Narushima, S. Ijima, Y. Ikeda, S. K. Lim, Y. W. Park, K. Miyazaki: J. Adhesion Sci.Technol. 17 (2003) 1457.

    Google Scholar 

  7. E. Occhiello, G. Morra, F. Garbassi, P. Humphrey, J. Appl. Polym. Sci. 42, 551 (1991)

    Article  Google Scholar 

  8. A.N. Banerjee, C.K. Ghosh, K.K. Chattopadhyay, H. Minoura, A.K. Sarkar, A. Akiba, A. Kamiya, T. Endo, Thin Solid Films 496, 112 (2005)

    Article  Google Scholar 

  9. Z. Hao, H. Chen, X. Zhu, J. Li, C. Liu, J. Chromatogr. A 1209, 246 (2008)

    Article  Google Scholar 

  10. M. Audronis, S.J. Hinder, P. Mack, V. Bellido-Gonzalez, D. Bussey, A. Matthews, M.A. Baker, Thin Solid Films 520, 1564 (2011)

    Article  Google Scholar 

  11. M.O.H. Cioffi, H.J.C. Voorwald, R.P. Mota, M. Charact. 50, 209 (2003)

    Article  Google Scholar 

  12. Y. Setsuhara, K. Cho, K. Takenaka, A. Ebe, M. Shiratani, M. Sekine, M. Hori, E. Ikenaga, H. Kondo, O. Nakatsuka, S. Zaima, Thin Solid Films 518, 1006 (2009)

    Article  Google Scholar 

  13. L. Yang, J. Chen, Y. Guo, Z. Zhang, Appl. Surface Sci. 255, 4446 (2009)

    Article  Google Scholar 

  14. Y. Setsuhara, K. Cho, K. Takenaka, M. Shiratani, M. Sekine, M. Hori, Surf. Coatings Tech. 205, S484 (2011)

    Article  Google Scholar 

  15. M. Katsikogianni, E. Amanatides, D. Mataras, Y.F. Missirlis, Colloids Surf. B: Biointerfaces 65, 257 (2008)

    Article  Google Scholar 

  16. A. Vesel, M. Mozetic, S. Strnad, Vacuum 85, 1083 (2011)

    Article  Google Scholar 

  17. K.N. Pandiyaraj, V. Selvarajan, R.R. Deshmukh, M. Bousmina, Surf. Coatings Tech. 202, 4218 (2008)

    Article  Google Scholar 

  18. K.N. Pandiyaraj, V. Selvarajan, R.R. Deshmukh, C. Gao, Vacuum 83, 332 (2009)

    Article  Google Scholar 

  19. C.-A. Dai, Y.-H. Lee, A.-C. Chiu, T.-A. Tsui, K.-J. Lin, K.-L. Chen, M.-W. Liu, Polymer 47, 8583 (2006)

    Article  Google Scholar 

  20. C. Scott, C. Macosko, J. Polym. Sci. B Polym. Phys. 32, 205 (1994)

    Article  Google Scholar 

  21. P. Marechal, G. Coppens, R. Legra, J.-M. Dekoninck, J. Polym. Sci. Part A, Polym. Chem. 33, 757 (1995)

    Article  Google Scholar 

  22. J. Friedrich, The Plasma Chemistry of Polymer Surface: Advanced Techniques for Surface Design (Wiley-VCH, Weinheim, 2012)

    Book  Google Scholar 

  23. T. Hayashi, M. Kato, M. Yokura, K. Uehara, X. Guo, Y. Nakamura, T. Endo, World J. Eng. 7(Suppl.2), 520 (2010)

    Google Scholar 

  24. M. Yokura, T. Hayashi, H. Katsumata, G. Xiang, T. Yoshii, M. Matsui, T. Endo, World J. Eng. 7(Suppl.2), 519 (2010)

    Google Scholar 

  25. M. Yokura, K. Uehara, G. Xiang, A. Okamoto, Y. Nakamura, L. Reddy, T. Endo, World J. Eng. 8(Suppl.3), 1275 (2011)

    Google Scholar 

  26. M. Yokura, K. Hanada, K. Uehara, M. Nagashima, H. Nishikawa, Y. Nakamura, H. Kezuka, K. Endo, T. Endo: Proc. Int. Conf. Composites/Nano Engineering (Beijing) (2012) CDROM

    Google Scholar 

  27. M. Yokura, K. Uehara, G. Xiang, K. Hanada, Y. Nakamura, L.S. Leddy, K. Endo, T. Endo, Mater. Res. Soc. Symp. Proc. 1454, 201 (2012)

    Article  Google Scholar 

  28. M. Yokura, K. Hanada, K. Uehara, Y. Nakamura, L.S. Reddy, H. Nishikawa, M. Nagashima, T. Endo, Jpn. J. Appl. Phys. 51, 11PG14 (2012)

    Article  Google Scholar 

  29. M. Yokura, K. Uehara, K. Hanada, Y. Nakamura, H. Nishikawa, T. Tsuchiya, S.L. Reddy, R. Philip, Y. Izumi, S. Tomita, T. Endo, Jpn. J. Appl. Phys. 53, 05FB21 (2014)

    Article  Google Scholar 

  30. K. Hanada, M. Yokura, M. Nagashima, Y. Nakamura, H. Nishikawa, Y. Strzhemechny, Z. Orel, S.L. Reddy, Y. Izumi, S. Tomita, T. Endo, Jpn. J. Appl. Phys. 53, 05FB23 (2014)

    Article  Google Scholar 

  31. T. Endo, L. Reddy, H. Nishikawa, S. Kaneko, Y. Nakamura, K. Endo, Procedia Eng. 171, 88 (2017)

    Article  Google Scholar 

  32. S. Teii, J. Inst. Electr. Eng. Japan 107, 1096 (1987)

    Google Scholar 

  33. H. Kobayashi, S. Hirose, Electron. Parts Mater. 20, 151 (1981)

    Google Scholar 

  34. H. Iriyama, Convertech 356, 46 (2002)

    Google Scholar 

  35. Y. Nakayama, T. Takahagi, F. Soeda, K. Hatada, S. Nagaoka, J. Suzuki, A. Ishitani, J. Polym. Sci. Polym. Chem. 26, 559 (1988)

    Article  Google Scholar 

  36. M. Mito: The Mechanism of Organic/Inorganic Interface, K. Fukushima (Sci. Technol., Tokyo, 2006) 3–9.

    Google Scholar 

  37. Y. Iriyama, J. Yasuda: Appl. Polym. Sci., Appl. Polym. Symp. 42 (1998) 97.

    Google Scholar 

  38. M. Hudis: Techniques and Applications of Polymer Chemistry, J. R. Hollahan, A. T. Bell (Wiley, New York, 1974) 113.

    Google Scholar 

Download references

Acknowledgment

In this article, the most of figures and tables are reproduced from ① Jpn. J. Appl. Phys. (JJAP) 51 (2012) 11PG14 [28], ② JJAP 53 (2014) 05FB21 [29], ③ JJAP 53 (2014) 05FB23 [30], and ④ Procedia Eng. 171 (2017) 88 [31]. These are noted in each figure and table caption. We obtained reproduction permissions from the Japan Society of Applied Physics for JJAP and from Elsevier for Procedia Eng. <Reproduction under the terms of the Creative Commons Attribution-Non Commercial-No Derivatives License (CC BY NC ND)>. We would appreciate these society and company for giving us their permissions.

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Correspondence to Tamio Endo .

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Uehara, K. et al. (2017). Plasma Bonding of Plastic Films and Applications. In: Kaneko, S., et al. Carbon-related Materials in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE. Springer, Cham. https://doi.org/10.1007/978-3-319-61651-3_16

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