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Effect of Solutes Additions on the Microstructure and Mechanical Properties of Cast Mg–Al Based Alloys

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Magnesium Technology 2017

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

Aluminium is an essential alloying element in most commercially used Mg alloys and particularly AZ series. That is due to its outstanding ability to increasing castability, formability and mechanical properties of Mg. However, seeking higher mechanical properties alloys has always been a hot topic in this research area. Grain refinement, solid solution strengthening and precipitation hardening are all mechanisms to increasing the as-cast mechanical properties of the alloys. In the current work, the effects of 6 different solutes addition, namely titanium, silicon, manganese, copper, calcium and tin, on the microstructure and mechanical properties of Mg–Al based alloys have been studied. In terms of microstructure, results showed that even though higher Q-values can be obtained through increasing the solutes addition, grain refinement is not always associated with the Q-values. In addition, intermetallic compounds played a major role in enhancing the hardness of the alloys.

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Abbreviations

HPDC:

High pressure die casting

E2EM:

Edge-to-Edge Matching Model

Q-value:

Growth restriction factor

Sol. treatment:

Solution treatment

Temp.:

Temperature

TEM:

Transmission electron microscope

References

  1. H.E. Friedrich, B.L. Mordike, Magnesium Technology (Springer, Berlin, 2006)

    Google Scholar 

  2. G.L. Song, A. Atrens, Corrosion mechanisms of magnesium alloys. Adv. Eng. Mater. 1(1), 11–33 (1999)

    Article  Google Scholar 

  3. E. Aghion, B. Bronfin, Magnesium alloys development towards the 21st century, in Materials Science Forum (Trans Tech Publication, Switzerland, 2000)

    Google Scholar 

  4. D.H. St John et al., Grain refinement of magnesium alloys. Metall. Mater. Trans. A 36A, 1671–1679 (2005)

    Google Scholar 

  5. M. Gupta, N.M.L. Sharon, Magnesium, Magnesium Alloys, and Magnesium Composites (Wiley, New York, 2011)

    Google Scholar 

  6. B. Mordike, Creep-resistant magnesium alloys. Mater. Sci. Eng., A 324(1), 103–112 (2002)

    Article  Google Scholar 

  7. M.O. Pekguleryuz, Development of creep resistant magnesium diecasting alloys, in Materials Science Forum (Trans Tech Publication, Switzerland, 2000)

    Google Scholar 

  8. Y. Ali et al., Current research progress in grain refinement of cast magnesium alloys: a review article. J. Alloy. Compd. 619, 639–651 (2015)

    Article  Google Scholar 

  9. R. Schmid-Fetzer, A. Kozlov, Thermodynamic aspects of grain growth restriction in multicomponent alloy solidification. Acta Materialia 59, 6133–6144 (2011)

    Google Scholar 

  10. M.-X. Zhang et al., Crystallographic study of grain refinement in aluminum alloys using the edge-to-edge matching model. Acta Mater. 53, 1427–1438 (2005)

    Google Scholar 

  11. P.M. Kelly, M.-X. Zhang, Edge-to-edge matching—a new approach ti the norphology and crystallography of precipitates. Mater. Forum 23, 41–62 (1999)

    Google Scholar 

  12. D. Qiu, M.-X. Zhang, P.M. Kelly, Crystallography of heterogeneous nucleation of Mg grains on Al2Y nucleation particles in an Mg–10wt.% Y alloy. Scripta Mater. 61(3), 312–315 (2009)

    Article  Google Scholar 

  13. Y. Ali et al., The influence of CaO addition on grain refinement of cast magnesium alloys. Scripta Mater. 114, 103–107 (2016)

    Article  Google Scholar 

  14. H.M. Fu et al., The development of a new grain refiner for magnesium alloys using the edge-to-edge model. J. Alloy. Compd. 456(1–2), 390–394 (2008)

    Google Scholar 

  15. S. Abaspour, C.H. Cáceres, Thermodynamics-based selection and design of creep-resistant cast Mg alloys. Metall. Mater. Trans. A 46(12), 5972–5988 (2015)

    Article  Google Scholar 

  16. E-112, A., Standard Test Methods for Determining Average Grain Size (ASTM International, USA, 2010)

    Google Scholar 

  17. D.H. StJohn et al., Grain refinement of magnesium alloys: a review of recent research, theoretical developments, and their application. Metall. Mater. Trans. A 44(7), 2935–2949 (2012)

    Article  Google Scholar 

  18. D.H. StJohn et al., the interdependence theory: the relationship between grain formation and nucleant selection. Acta Mater. 59(12), 4907–4921 (2011)

    Article  Google Scholar 

  19. W. Kurz, D.J. Fisher, Fundamentals of Solidification (Trans Tech Publications, Switzerland, 1986)

    Google Scholar 

  20. P. Villars, A. Prince, H. Okamoto, Handbook of Ternary Alloy Phase Diagrams (ASM International, 1995)

    Google Scholar 

  21. Y. Guangyin et al., Microstructure and mechanical properties of Mg/Zn/Si-based alloys. Mater. Sci. Eng. A 357, 314–320 (2003)

    Google Scholar 

  22. J.J. Kim et al., Modification of Mg2Si morphology in squeeze cast Mg-Al-Zn-Si alloys by Ca or P addition. Scripta Mater. 41(3), 333–340 (1999)

    Article  Google Scholar 

  23. T. Rzychon, B. Chmiela, The influence of tin on the microstructure and creep properties of a Mg-5Al-3Ca-0.7Sr-0.2Mn magnesium alloy. Solid State Phenomena 191, 151–158 (2012)

    Google Scholar 

  24. S.F. Hassan, M. Gupta, Development of a novel magnesium-copper based composite with improved mechanical properties. Mater. Res. Bull. 37, 13 (2002)

    Google Scholar 

  25. S.F. Hassan, M. Gupta, Development of high strength magnesium—copper based hybrid composites with enhanced tensile properties. Mater. Sci. Technol. 19, 7 (2003)

    Article  Google Scholar 

  26. W.D. Callister, D.G. Rethwisch, Materials Science and Engineering: An Introduction, vol 7 (Wiley, New York, 2007)

    Google Scholar 

  27. M. Pekguleryuz, M. Celikin, Creep resistance in magnesium alloys. Int. Mater. Rev. 55(4), 197–217 (2010)

    Article  Google Scholar 

  28. A. Srinivasan et al., Observations of microstructural refinement in Mg–Al–Si alloys containing strontium. J. Mater. Sci. 41, 6087–6089 (2006)

    Article  Google Scholar 

  29. C. Blawert et al., Influence of the copper content on microstructure and corrosion resistance of AZ91 based secondary magnesium alloys. SAE Technical Paper 2006-01-0254 (2006)

    Google Scholar 

  30. J.-O. Andersson et al., Thermo-Calc & DICTRA, computational tools for materials science. Calphad 26(2), 273–312 (2002)

    Article  Google Scholar 

  31. A. Srinivasan, U.T.S. Pillai, B.C. Pai, Microstructure and mechanical properties of Si and Sb Added AZ91 magnesium alloy. Metall. Mater. Trans. A 36A, 2235–2243 (2005)

    Google Scholar 

  32. S.-S. Li, B. Tang, D.-B. Zengb, Effects and mechanism of Ca on refinement of AZ91D alloy. J. Alloys Compd. 437, 5 (2007)

    Google Scholar 

  33. J. Jayaraj et al., Enhanced precipitation hardening of Mg–Ca alloy by Al addition. Scripta Mater. 63(8), 831–834 (2010)

    Article  Google Scholar 

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Correspondence to Yahia Ali .

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Ali, Y., Zhang, MX. (2017). Effect of Solutes Additions on the Microstructure and Mechanical Properties of Cast Mg–Al Based Alloys. In: Solanki, K., Orlov, D., Singh, A., Neelameggham, N. (eds) Magnesium Technology 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52392-7_38

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