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Influence of Lanthanum concentration on the Corrosion Behaviour of Binary Mg-La Alloys

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Magnesium Technology 2011

Abstract

Different contents of Lanthanum have been added to Magnesium and have been investigated on their influence on the microstructure and the corrosion properties. The microstructure was studied by optical microscopy. Corrosion performance was evaluated using potentiodynamic polarization measurements. Immersion tests were carried out using distilled water and 0.1 M sodium chloride solution. The corrosion products were investigated by X-ray induced photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and X-ray diffraction (XRD) which lead to detailed information on phase formation. The oxide and hydroxide formation have been correlated to the chemical states and formed intermetallics, i.e by taking into account the XPS peak shift and peak splitting of the the Mg-2p state. Additionally, the results have been verified by means of AES on the Mg-KLL, O-KLL and La-MNN excitation and by XRD. Latter suggests the supplemental formation of a nanocrystalline phase.

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References

  1. G. Makar, J. Kruger and A. Joshl, The effect of alloying elements on the corrosion resistance of rapidly solidified magnesium alloys, International Magnesium Association and the Non-ferrous Metals Committee, The Minerals, Metals and Materials Society, Phoenix, 1988.

    Google Scholar 

  2. G. L. Makar and J. Kruger, “Corrosion studies of rapidly solidified magnesium alloys,” J Electrochem Soc, 137 (2) (1990), 414–421.

    Article  Google Scholar 

  3. E. Emley, Principles of magnesium technology, London, Pergamon Press, New York, 1966.

    Google Scholar 

  4. G. Makar and J. Kruger, Corrosion of magnesium, vol. 38, Maney Publishing, 1993.

    Google Scholar 

  5. I. Polmear, Magnesium alloys, Sevenoaks, UK 1989.

    Google Scholar 

  6. T. Takenaka et al., “Improvement of corrosion resistance of magnesium metal by rare earth elements,” Electrochimica Acta, 53(1) (2007), 117–121.

    Article  Google Scholar 

  7. J. H. Nordlien et al., “Morphology and structure of water-formed oxides on ternary mgal alloys,” J Electrochem Soc, 144 (2) (1997), 461–466.

    Article  Google Scholar 

  8. F. Rosalbino et al., “Effect of erbium addition on the corrosion behaviour of mg-al alloys,” Intermetallics, 13 (1) (2005), 55–60.

    Article  Google Scholar 

  9. G. Song and D. St. John, “The effect of zirconium grain refinement on the corrosion behaviour of magnesium-rare earth alloy mez,” Journal of Light Metals, 2 (1) (2002), 1–16.

    Article  Google Scholar 

  10. Y. Fan, G. Wu and C. Zhai, “Influence of cerium on the microstructure, mechanical properties and corrosion resistance of magnesium alloy,” Materials Science and Engineering: A, 433 (1–2) (2006), 208–215.

    Article  Google Scholar 

  11. Q. Peng et al., “The effect of La or Ce on ageing response and mechanical properties of cast mg-gd-zr alloys,” Materials Characterization, 59 (4) (2008), 435–439.

    Article  Google Scholar 

  12. S. Ardizzone et al., “Magnesium salts and oxide: An xps overview,” Appl Surf Sci, 119 (3–4) (1997), 253–259.

    Article  Google Scholar 

  13. A. Ivanova, “Structure, texture, and acid-base properties of alkaline earth oxides, rare earth oxides, and binary oxide systems,” Kinetics and Catalysis, 46 (5) (2005), 620–633.

    Article  Google Scholar 

  14. J. M. Fraile et al., “The basicity of mixed oxides and the influence of alkaline metals: The case of transesterification reactions,” Applied Catalysis A: General, In Press, Corrected Proof (-) (2010).

    Google Scholar 

  15. C. D. Wagner and P. Biloen, “X-ray excited auger and photoelectron spectra of partially oxidized magnesium surfaces: The observation of abnormal chemical shifts,” Surface Science, 35 ((1973), 82–95.

    Article  Google Scholar 

  16. J. C. Fuggle et al., “High-resolution auger spectra of adsorbates,” Journal of Electron Spectroscopy and Related Phenomena, 26 (2) (1982), 111–132.

    Article  Google Scholar 

  17. W. H. Hocking et al., “Scanning auger microscopy study of lanthanum partitioning in sphene-based glass-ceramics,” Philosophical Magazine A, 49 (5) (1984), 637–656.

    Article  Google Scholar 

  18. L. Davis et al., Handbook of auger electron spectroscopy, Physical Electronics Industries Eden Prairie, MN, 1976.

    Google Scholar 

  19. “Powder diffraction file,” ICDD, International Centre for Diffraction Data, Newtown, PA, 2008.

    Google Scholar 

  20. T. Ungár, “Microstructural parameters from x-ray diffraction peak broadening,” Scripta Materialia, 51 (8) (2004), 777–781.

    Article  Google Scholar 

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Campos, R.S., Höche, D., Blawert, C., Kainer, K.U. (2011). Influence of Lanthanum concentration on the Corrosion Behaviour of Binary Mg-La Alloys. In: Sillekens, W.H., Agnew, S.R., Neelameggham, N.R., Mathaudhu, S.N. (eds) Magnesium Technology 2011. Springer, Cham. https://doi.org/10.1007/978-3-319-48223-1_94

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