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Preparation of Polymeric Phosphate Ferric Sulfate Flocculant and Application on Coking Wastewater Treatment

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Characterization of Minerals, Metals, and Materials 2016
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Abstract

Na2HPO4 and Polymeric ferric sulfate (PFS) were used as raw materials to synthesize the polymeric phosphorus ferric sulfate (PPFS) in the laboratory, which was used for the treatment of coking wastewater. Effects of nPO43-/ nFe3+, preparation temperature, preparation time, and dosage on flocculation influence were discussed by single factor experiment. The results indicated that PPFS had superior flocculation effect for coking wastewater. Total organic carbon (TOC) minimum concentration can be reduced to 23.88mg/L, and the removal rate of TOC was above 60% when nP043-/ nFe3+ is 0.3, preparation temperature 80°C, preparation time 60min, and the dosage 0.8ml/L. In addition, the structure of PPFS was characterized by SEM. and mechanism of flocculation was discussed.

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References

  1. Du X. et al., “Denitrification dynamics of treating analog coking wastewater in upflow blanket filter,” Journal of Chemical Engineering, 64(7)(2013), 2650–2655.(in Chinese)

    Google Scholar 

  2. Hu X. et al., “Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes”. Water research, 43(17) (2009), 4347–4355.

    Article  Google Scholar 

  3. Ren Y. et al., “Environmental and biological characteristics of coking wastewater”. Acta Scientiae Circumstantiae. 27(7)(2007), 1094–1100. (in Chinese)

    Google Scholar 

  4. Tian B.Z. et al., “The hydrolyzed and other chemical characters of ferric chloride solution containing phosphate”. Environmental Chemistry. 14(4)(1995), 329–336. (in Chinese)

    Google Scholar 

  5. Zheng Y.J. et al., “Treating municipal living sewage with new type coagulant PPFS”. Journal of Central South University of Technology. 33(2)(2002), 141–144. (in Chinese)

    Google Scholar 

  6. Zheng H.L. et al., “Coagulation removal of phthalic acid esters environmental hormones by polymeric phosphate ferric sulfate”. Journal of civil, Architectural & Environmental Engineering. 34(3)(2012), 129–132. (in Chinese)

    Google Scholar 

  7. Bao X.J., et al., “Application of UV254 in coking wastewater treatment”. Fuel & Chemical Process. 42 (6)(2011), 42–44. (in Chinese)

    Google Scholar 

  8. Han X.Y., et al., “Preparation and application of a novel flocculent polyferric phosphate sulfate”. Petrochemical Technology & application. 27(4)(2009), 322–324. (in Chinese)

    Google Scholar 

  9. Shi T.H., et al., “Studies on new production method and flocculation properties of PPFS flocculants”. China Environmental Science. 21(2)(2001), 161–164. (in Chinese)

    Google Scholar 

  10. Zhang Z, et al., “Experimental study on advanced treatment of coking wastewater by magnetic flocculation technology”. Industrial Water and Wastewater. 43(2)(2012), 25–29. (in Chinese)

    Google Scholar 

  11. Zheng H.L., et al., “ Topography structure and flocculation mechanism of polymeric phosphate ferric sulfate(PPFS)”. Spectroscopy and Spectral Analysis, 31(5) (2011), 1410–1413. (in Chinese)

    Google Scholar 

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© 2016 TMS (The Minerals, Metals & Materials Society)

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Wang, L., Hwang, J., Xue, G., Zhang, L. (2016). Preparation of Polymeric Phosphate Ferric Sulfate Flocculant and Application on Coking Wastewater Treatment. In: Ikhmayies, S.J., et al. Characterization of Minerals, Metals, and Materials 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48210-1_66

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