Abstract
In this chapter we explain the fundamentals of electrodeposition starting with the principles of electrolysis, and electrodeposition cells. The electrochemical fundamentals play a vital role in electrodeposition, then these will be discussed in details and modern approaches for the investigation of thermodynamics and kinetics aspects are reviewed. Nucleation and growth of electrodeposition and their modes including overpotential (OPD) and underpotential (UPD) deposition control the microstructure and consequent properties, as will be introduced. Characterisation methods of initial stages of electrodeposition and other stages will be explained using conventional electrochemical techniques and modern microscopical and nanoscopical techniques. The enhancement of electrodeposition process by application of external forces such as magnetic and ultrasound will be explained.
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References
P.W. Atkins, Physical Chemistry, 5th edn. (Oxford University Press, Oxford, 1994)
Y.D. Gamburg, G. Zangari, Theory and Practice of Metal Electrodeposition (Springer, New York, 2011)
N. Kanani, Electroplating- Basic Principles (Processes and Practice, Elsevier, Oxford, 2004)
M. Schlesinger, M. Paunovic (eds.), Modern Electroplating, 5th edn (John Wiley & Sons, New Jersey, 2010)
F. Endres, D. MacFarlane, A. Abbott (eds.), Electrodeposition from Ionic Liquids (Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim, 2008)
H. Nattar, M. Bukowski, Hempelmann et al., Z. Phys. Chem. 220, 1275–1291 (2006)
F. Endres, S., Zein El Abedin, Z., Phys. Chem. 221, 1407–1427
F. Endres, S, Z. Phys. Chem. 218, 255–283 (2004)
A. Brenner, Electrodeposition of Alloys (Principles and Practice, Volumes I, II, III, Elsevier, 1963)
S.S. Djokic, Modern Aspects of Electrochemistry, Electrodeposition Theory and Practice, No. 48 (Springer, New York, 2010)
D.R. Crow, Principles and Applications of Electrochemistry (Springer-Science + Business Media, B.V., 1974)
J.O’.M. Bockris, A.K.N. Reddy, Modern Electrochemistry, 2nd edn. (Kluwer Academic Publishers, New York, 2002)
E. Budevski, G. Staikov, W.J. Lorenz, Electrochemical Phase Formation and Growth (VCH Verlagsgesellschaft mbH, Weinheim, Germany, 1996)
A. Milchev, Electrocrystallization: Fundamentals of Nucleation and Growth (Kluwer Academic Publishers, Dordrecht, 2002)
F.C. Walsh, M.R. Herron, J. Phys. D Appl. Phys. 24, 217 (1991)
M. Fleischmann (ed.), Electrocrystallisation, Nucleation and Phase Formation (Faraday Symposia of the Chemical Society 12) (The Chemical Society, London, 1977)
M. Fleischmann, H.R. Thirsk, Electrochim. Acta 2, 22 (1960)
M. Fleischmann, H.R. Thirsk, Ado. Electrochem. Elecfrochem. Eng. 3, 123 (1963)
A. Bewick, M. Fleischmann, H.R. Thirsk, Trans. Faraday Soc. 58, 2200 (1962)
M. Paunovic, M. Schlesinger, Fundamentals of Electrochemical Deposition, 2nd edn. (John Wiley & Sons, Hoboken, New Jersey, 2006)
P. Delahay, T. Berzins, J. Am. Chem. Soc. 75(10), 2486–2493 (1953)
T. Berzins, P. Delahay, J. Am. Chem. Soc. 75(17), 4205–4213 (1953)
B.R. Scharifker, G.J. Hills, J. Electroanal. Chem. 130, 9 (1981)
C.A. Gunawardena, G.J. Hills, I. Montenegro, Electrochim. Acta 23, 693 (1978)
G.J. Hills, I. Montenegro, B.R. Scharifker, J. Appl. Elecrtrochem. 10, 807 (1980)
G.J. Hills, A. Kaveh Pour, B.R. Scharifker, Electrochim. Acta 28, 891 (1982)
D.J. Astley, J.A. Harrison, H.R. Thirsk, Trans. Faraday Soc. 64, 172 (1968)
G.J. Hills, D.J. Schiffrin, J. Thompson, Electrochim. Acta 19, 657 (1974)
G.A. Gunawardena, G. Hills, I. Montenegro, B. Scharifker, J. Electroanal. Chem. 138, 225 (1982)
B. Scharifker, G. Hills, Electrochim. Acta 28, 879 (1983)
M. Avrami, J. Chem. Phys. 7, 1103 (1939)
M. Avrami, J. Chem. Phys. 8, 212 (1940)
E. Bosco, S.K. Rangarajan, J. Electroanal. Chem. 134, 213 (1982)
E. Bosco, S.K. Rangarajan, J. Electroanal. Chem. 134, 225 (1982)
Bard, A.J., Faulkner, L.R., Electrochemical methods Fundamentals and Applications. (John Wiley & Sons, 2001)
B. Scharifker, J. Mostany, J. Electroanal. Chem. 177, 13 (1984)
M.E. Hyde, R. Jacobs, R.G. Compton, J. Phys. Chem. Sect. B 106, 11075 (2002)
J. Yu, H. Cao, Y. Chen, L. Kang, H. Yang, J. Electroanal. Chem. 474, 69 (1999)
M.E. Hyde, O.V. Klymenko, R.G. Compton, J. Electroanal. Chem. 534, 13 (2002)
M. Sluyters-Rehbach, J.H.O.J. Wijenberg, E. Bosco, J.H. Sluyters, J. Electroanal. Chem. 236, 1 (1987)
L. Heerman, A. Tarallo, J. Electroanal. Chem. 470, 70 (1999)
L. Heerman, E. Matthijs, S. Langerock, Electrochim. Acta 47, 905 (2001)
M. Ghorbani, F. Nasirpouri, A. Irajizad, A. Saedi, Mater. Des. 27(10), 983–988 (2006)
S.M. Rossnagel, T.S. Kuan, J. Vac. Sci. Technol., B 22, 240 (2004)
F. Nasirpouri, A. Nogaret, D. Atkinson, M Ghorbani. J. Magn. Magn. Mater. 299(2), 356–361 (2006)
V. Ng, J.F. Hu, A.O. Adeyeye, J.P. Wang, T.C. Chong, J. Appl. Phys. 91, 7206 (2002)
J. Gong, S. Riemer, A. Morrone, V. Venkatasamy, M. Kautzky, I. Tabakovic, J. Electrochem. Soc. 159, D447–D454 (2012)
R. Rabady, I. Avrutsky, 2003. J. Opt. Soc. Am. B 20, 2174 (2003)
F. Nasirpouri, M.R. Sanaeian, A.S. Samardak, E.V. Sukovatitsina, A.V. Ognev, Appl. Surf. Sci. 292, 795–805 (2014)
Y.-P. Zhao, G.-C. Wang, T.-M. Lu, Characterization of Amorphous and Crystalline Rough Surface: Principles and Applications (Academic Press, New York, 2001)
P. Meakin, Fractals, Scaling and Growth far From Equilibrium (Cambridge University Press, Cambridge, 1998)
W.W. Mullins, R.F. Sekerka, J. Appl. Phys. 35, 444 (1964)
W. Schwarzacher, J. Phys. Cond. Matter. 16, R859–R880 (2004)
F.P. Nasirpourim, Ionics, 19(3), 535–542 (2013)
F. Family, J. Phys. A: Math. Gen. 19, L441 (1986)
F. Family, T. Vicsek, Dynamics of Fractal Surfaces (World Scientific Publishing, Co., New Jersey, 1991)
F. Family, T. Vicsek, J. Phys. A: Math. Gen. 18, L75 (1985)
M. Schroeder, M. Siegert, D.E. Wolf, J.D. Shore, M. Plischke, Europhys. Lett. 24, 563 (1993)
S. Das Sarma, S.V. Ghaisas, J.M. Kim, Phys. Rev. E 49, 122 (1994)
J.M. Lopez, Phys. Rev. Lett. 83, 4594 (1999)
G.L.M.K.S. Kahanda, X.-Q. Zou, R. Farrell, P.-Z. Wong, Phys. Rev. Lett. 68, 3741 (1992)
J.M. Pastor, M.A. Rubio, Physica D 96, 384 (1996)
A. Iwamoto, T. Yoshinobu, H. Iwasaki, Phys. Rev. Lett. 72, 4025 (1994)
S. Huo, W. Schwarzacher, Phys. Rev. Lett. 86, 256 (2001)
J. Morales, S.M. Krijer, P. Esparza, S. Gonzalez, L. Vazquez, R.C. Salvarezza, A.J. Arvia, Langmuir 12, 1068 (1996)
M. Saitou, A. Makabe, T. Tomoyose, Surf. Sci. 459, L462 (2000)
M. Saitou, W. Oshikawa, M. Mori, A. Makabe, J. Electrochem. Soc. 148, C780 (2001)
Y. Shapir, S. Raychaudhuri, D.G. Foster, J. Jorne, Phys. Rev. Lett. 84, 3029 (2000)
G. Nabiyouni, Jalali Farahani B. Appl. Surf. Sci. 256, 674–682 (2009)
W. Schwarzacher, S. Huo, Phys. Rev. Lett. 91, 119601 (2003)
L. Liu, W. Schwarzacher, Electrochem. Commun. 29, 52–54 (2013)
G. Binnig, H. Rohrer, Helv. Phys. Acta 55, 726 (1982)
R. Sonnenfeld, P.K. Hansma, Science 232, 211 (1986)
H.-Y. Liu, F.-R.F. Fan, C.W. Lin, A.J. Bard, J. Am. Chem. Soc. 108, 3838 (1986)
H. Siegenthaler, STM in electrochemistry, in Scanning Tunneling Microscopy II, ed. by R. Wiesendanger, H.J. Gunterodt (Springer, New York, 1992)
T.P. Moffat, Electroanalytic Chemistry: A Series of Advances, ed. by A.J. Bard, I. Rubinstein, vol. 1 (New York, M. Dekker, 1999)
C. Li, K.J. Kjoller, Veeco Instruments Inc., 2007. Scanning electrochemical potential microscope US Patent US7156965 B1
M. Herpich, J. Friedl, U. Stimming, Surface Science Tools for Nanomaterials Characterization, ed. by C.S.S.R. Kumar. (Springer, 2015), pp. 1–67, 2015
A. Bard, K.L. Fan, Anal. Chem. 61(2), 132–138
G. Binnig, C.F. Quate, C. Gerber, Phys. Rev. Lett. 56, 930 (1985)
G.A. Snook, A.M. Bond, S. Fletcher, J. Electroanal. Chem. 526, 1–9 (2002)
F. Nasirpouri, Ionics 17(4), 331–337 (2011)
F. Nasirpouri, Prot. Met. Phys. Chem. Surf. 47(4), 534–539 (2011)
A. Wong, X.D. Zhu, Appl. Phys. A 63, 1 (1996)
P. Thomas, E. Nabighian, M.C. Bartelt, C.Y. Fong, X.D. Zhu, Appl. Phys. A 79, 131 (2004)
G.Y. Wu, S.E. Bae, A.A. Gewirth et al., Surf. Sci. 60, 1886 (2007)
W. Schwarzacher, J. Gray, X.D. Zhu, Electrochem. Solid-State Lett. 6, C73 (2003)
J.M.D. Coey, G. Hinds, J. Alloy. Compd. 326, 238–245 (2001)
M. Uhlemann et al., Eur. Phys. J. Special Topics 220, 287–302 (2013)
O. Devos et al., J. Electrochem. Soc. 145, 401 (1998)
H. Matsushima et al., Electrochim. Acta 53, 161 (2007)
M. Uhlemann et al., J. Electrochem. Soc. 152, C817 (2005)
J. Koza et al., Electrochim. Acta 56, 2665 (2011)
A. Krause et al., Thin Solid Films 515, 1694 (2006)
L.M.A. Monzon, J.M.D. Coey, Electrochem. Commun. 42, 38–41 (2014)
A. Nogaret, F. Nasirpouri, J.C. Portal, H.E. Beere, D.A. Ritchie, A.T. Hindmarch, EPL (Europhys. Lett.) 94(2), 28001 (2011)
G. Mutschke et al., Phys. Rev. Lett. 109, 229401 (2012)
O. Gorobets et al., J. Phys. Chem. C 112, 3373 (2008)
P. Dunne et al., Phys. Rev. Lett. 107, 024501 (2011)
P. Dunne, J.M.D. Coey, Phys. Rev. B 85, 224411 (2012)
P. Dunne, R. Soucaille, K. Ackland, J.M.D. Coey, J. Appl. Phys. 111, 07B915 (2012)
J. Koza et al., Electrochem. Comm. 11, 425 (2009)
K. Tschulik et al., Electrochim. Acta 56, 5174 (2011)
R. O’Brien, K. Santhanam, Electrochim. Acta 32, 679 (1987)
K. Tschulik et al., Technisches Messen 78, 232, and 2012. Analyt. Chem. 84, 2328 (2012)
T.J. Mason, V.S. Bernal, B.G. Pollet (eds.), Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution (John Wiley & Sons, West Sussex, United Kingdom, 2012)
N. Moriguchi, The effect of supersonic waves on chemical phenomena (III). The effect on the concentration polarization. J. Chem. Soc. Jpn. 55, 749–750 (1934)
R. Walker, Ultrasound and electroplating. Chem. Br. 26, 251–254 (1990)
I. Tudela, Y. Zhang, M. Pal, I. Kerr, A. Cobley, Surf. Coat. Technol. 259, 363–373 (2014)
J.Y. Hihn, F. Touyeras, M.-L. Doche, C. Costa, B.G. Pollet, Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution, ed. by B.G. Pollet, John Wiley & Sons, West Sussex, United Kingdom
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Nasirpouri, F. (2017). Fundamentals and Principles of Electrode-Position. In: Electrodeposition of Nanostructured Materials. Springer Series in Surface Sciences, vol 62. Springer, Cham. https://doi.org/10.1007/978-3-319-44920-3_3
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