Definition
A silicate mineral is a salt of silicate anions and cations formed by geological processes. Silica minerals [SiO2], such as quartz, cristobalite, and tridymite, and the hydrous phases [SiO2•nH2O], opal and mogánite, are often classified into the silicate minerals. A silicate anion is an oxo acid of silicon, and commonly consists of one centered Si and four O atoms forming a SiO4 tetrahedron, or rarely of one centered Si with six O atoms forming a SiO6 octahedron.
Classification
Tetrahedral (SiO4)4− anions are isolated in the crystal structures of nesosilicates . Forsterite [Mg2SiO4] of the olivine group and almandine [Fe2+ 3Al2(SiO4)3] of the garnet super group are typical examples of nesosilicate. In the other silicates, tetrahedral (SiO4)4− anions are polymerized by means of sharing the apical oxygen atom(s) to form dimers, trimers, or polymers. Solosilicates consist of the dimer (Si2O7)6− and/or trimer (Si3O10)8−, e. g., epidote [Ca2Fe3+Al2(Si2O7)(SiO4)O(OH)] of the...
References
American Mineralogist Crystal Structure Database (AMCSD). http://rruff.geo.arizona.edu/AMS/amcsd.php
Commission on New Minerals Nomenclature and Classification, International Mineralogical Association (CNMNC-IMA). http://www.ima-mineralogy.org/CNMNC_Strategy.htm
Visualization for Electronic and Structural Analysis (VESTA). http://jp-minerals.org/vesta/en/
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Miyawaki, R. (2017). Silicate Minerals. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_319-1
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DOI: https://doi.org/10.1007/978-3-319-39193-9_319-1
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