Abstract
Raman scattering is an inelastic light-scattering technique that finds wide application in physics, chemistry, geology, engineering, and life sciences. It is a nondestructive evaluation method that gives information on vibrational modes in sample materials and can thus be used for characterization of structure and composition of materials. This includes phase identification (study of polytypes and phase transitions), characterization of residual stress and strain, studies of nanomaterials, radiation damage, catalysis processes, corrosion mechanisms, oxide formation, metabolic process in biological tissues, and many more. Information is obtained at the micron scale in materials, and Raman mapping can be used to determine composition and stress/strain in materials at similar spatial scales. Advances in instrumentation over the past decade or so have made the technique more widely accessible, and a brief overview of dispersive Raman instrumentation is given. The description of the basics of the method focuses on solid materials, and applications focus on phase identification and NDE of stress and strain. The examples covered in more detail include stress determination in diamond and polycrystalline diamond (PCD) tools and in situ characterization of corrosion processes on iron surfaces. The chapter concludes with a short overview of other NDE applications, with citations of relevant literature, and method developments such as tip-enhanced Raman spectroscopy (TERS).
References
Adar F, Mamedov S, Whitley A (2010) Microsc Microanal 16:360–361
Ager JW, Drory D (1993) Phys Rev B 48:2601–2607
Ager JW, Veirs DK, Rosenblatt GM (1991) Phys Rev B 43:6491–6499
Anastassakis E, Pinczuk A, Burstein E, Pollak FH, Cardona M (1970) Solid State Commun 8:133–138
Austin LA, Osseiran S, Evans CL (2016) Analyst 141:476–503
Balkanski M, Wallis RF, Haro E (1983) Phys Rev B 28:1928–1934
Beechem T, Graham S, Kearney SP, Phinney LM, Serrano JR (2007) Rev Sci Instrum 78:061301
Bergman L, Nemanich RJ (1995) J Appl Phys 78:6709–6719
Boppart H, van Straaton J, Silvera IF (1985) Phys Rev B Rapid Commun 32:1423–1425
Borer WJ, Mitra SS, Namjoshi DV (1971) Solid State Commun 9:1377–1381
Boteler JM, Gupta YM (1993) Phys Rev Lett 71:3497–3500
Brookes CA (1992) In: Field JE (ed) The properties of natural and synthetic diamond. Academic, London, p 515
Brookes CA, Brookes EJ, Howes VR, Roberts SG, Waddington CP (1990) J Hard Mater 1:3–24
Brüesch P (1982) Phonons: theory and experiments I. Springer, New York
Brüesch P (1986) Phonons: theory and experiments II. Springer, Berlin Heidelberg
Burke EAJ (2001) Lithos 55:139–158
Campbell IH, Fauchet PM (1986) Solid State Commun 58:739–741
Cardona M (1982) In: Cardona M, Güntherodt G (eds) Light scattering in solids II (topics in applied physics 50). Springer, Berlin
Catledge SA, Vohra YK (1995) J Appl Phys 78:7053–7058
Catledge SA, Vohra YK, Ladi R, Rai G (1996) Diam Relat Mater 5:1159–1165
Cohen M (1978) In: Frakenthal RP, Kruger J (eds) Passivity of metals. The Electrochemical Society Inc, New Jersey, pp 521–545
Colomban P (2002) Adv Eng Mater 4:535–542
Colomban P (2017) J Raman Spectrosc 2017:1–14
Colomban P, Gouadec G, Mathez J, Tschiember J, Pérès P (2006) Compos Part A-Appl S 37:646–651
Crawford FS Jr (1968) Waves:Berkeley physics course, vol 3. McGraw-Hill, New York, p 376
Cullity BD, Weymouth JW (1978) Elements of X-ray diffraction, 2nd edn. Addison-Wesley, New York
Datchi F, Canny B (2004) Phys Rev B 69:144106
de la Vega A, Kinloch IA, Young RJ, Bauhofer W, Schulte K (2011) Compos Sci Technol 71:160–166
De Wolf I (1996) Semicond Sci Tech 11:139–154
De Wolf I (2003) Spectrosc Eur 15/2:6–13
De Wolf I (2015) J Appl Phys 118:053101
De Wolf I, Anastassakis E (1999) J Appl Phys 85:7484–7485
De Wolf I, Maes HE, Jones SK (1996) J Appl Phys 79:7148–7156
Dooley KA, McCormack J, Fyhrie DP, Morris MD (2009) J Biomed Opt 14:044018
Edwards HGM, Vandenabeele P (2016) Philos T Roy Soc A 374:20160052
Erasmus RM, Comins JD, Fish ML (2000) Diam Relat Mater 9:600–604
Erasmus RM, Daniel RD, Comins JD (2011a) J Appl Phys 109:013527
Erasmus RM, Comins JD, Mofokeng V, Martin Z (2011b) Diam Relat Mater 20:907–911
Evans T, Davey ST, Robertson SH (1984) J Mater Sci 19:2405–2414
Everall N (2010) Analyst 135:2512–2522
Everall N (2014) J Raman Spectrosc 45:133–138
Ferreira NG, Abramof E, Corat EJ, Trava-Airoldi VJ (2003) Carbon 41:1301–1308
Field JE (1992) In: Field JE (ed) The properties of natural and synthetic diamond. Academic Press, London, p 667
Foucher F, Ammar M-R, Westall F (2015) J Raman Spectrosc 46:873–879
Frezzotti ML, Tecce F, Casagli A (2012) J Geochem Explor 112:1–20
Ganesan S, Maradudin AA, Oitmaa J (1970) Ann Phys-New York 56:556–594
Gries T, Vandenbulcke L, Simon P, Canizares A (2007) J Appl Phys 102:083519
Griffith WP (1975) In: Karr C (ed) Infrared and Raman spectroscopy of lunar and terrestrial minerals. Academic Press, New York
Grimsditch MH, Anastassakis E, Cardona M (1978) Phys Rev B 18:901–904
GuptaYM, Horn PD, Yoo CS (1989) Appl Phys Lett 55:33–35
Hanfland M, Syassen K, Fahy S, Louie SG, Cohen ML (1985) Phys Rev B 31:6896–6899 Rapid Comm
Harris TK, Brookes EJ, Daniel RD (2001) Diam Relat Mater 10:755–759
Hart TR, Aggarwal RL, Lax B (1970) Phys Rev B 1:638–642
Herchen H, Cappelli MA (1993) Phys Rev B 47:14193–14199
Hou PY, Ager J, Mougin J, Galerie A (2011) Oxid Met 75:229–245
Imanaka M, Ishikawa R, Sakurai Y, Ochi K (2009) J Mater Sci 44:976–984
Ishigaki M, Hashimoto K, Sato H, Ozaki Y (2017) Sci Rep-UK 7:43942
Jaumot J, Gargallo R, de Juan A, Tauler R (2005) Chemometr Intell Lab 76:101–110
Jothilakshmi R, Ramakrishnan V, Kumar J, Sarua A, Kuball M (2011) J Raman Spectrosc 42:422–428
Keresztury G (2002) In: Chalmers JM, Griffiths PR (eds) Handbook of vibrational spectroscopy, Theory and instrumentation, vol 1. Wiley, Chichester
Kim JG, Yu J (1998) J Mater Res 13:3027–3033
Klein MV (1990) In: Horton GK, Maradudin AA (eds) Dynamical properties of solids. North-Holland, Amsterdam
Korsakov AV, Toporski J, Dieing T, Yang J, Zelenovskiye PS (2015) J Raman Spectrosc 46:880–888
Lammer A (1988) Mater Sci Tech-Lond 4:949–955
Landsberg G, Mandelstam L (1928a) Naturwissenschaften 16:557–558
Landsberg G, Mandelstam L (1928b) Z Phys 50:769–780
Lee CJ, Pezzotti G, Okui Y, Nishino S (2004) Appl Surf Sci 228:10–16
Liu Z, Zhang J, Gao B (2009) Chem Commun 2009:6902–6918
Long DA (2002) The Raman effect: a unified treatment of the theory of Raman scattering by molecules. Wiley, New York
Loudon R (1964) Adv Phys 13:423–482
Marcuse D (1980) Principles of quantum electronics. Academic, New York
McNamara D, Alveen P, Damm S, Carolan D, Rice JH, Murphy N, Ivanković A (2015) Int J Refract Met H 52:114–122
Mermoux M, Marcus B, Crisci A, Tajani A, Gheeraert E, Bustarret E (2005) J Appl Phys 97:043530
Mitra SS, Brafman O, Daniels WB, Crawford RK (1969) Phys Rev 186:942–944
Mohiuddin TMG, Lombardo A, Nair RR, Bonetti A, Savini G, Jalil R, Bonini N, Basko DM, Galiotis C (2009) Phys Rev B 79:205433
Mohrbacher H, Van Acker K, Blanpain B, Van Houtte P, Celis J-P (1996) J Mater Res 11:1776–1782
Mossbrucker J, Grotjohn TA (1997) J Vac Sci Technol A 15:1206–1210
Muraki N, Katagiri G, Sergo V, Pezzotti G, Nishida T (1997) J Mater Sci 32:5419–5423
Nafie LA (2017) J Raman Spectrosc 48:1692–1717
Nemanich RJ, Solin SA, Martin RM (1981) Phys Rev B 23:6348–6356
Nieuwoudt MK, Comins JD, Cukrowski I (2011a) J Raman Spectrosc 42:1335–1339
Nieuwoudt MK, Comins JD, Cukrowski I (2011b) J Raman Spectrosc 42:1353–1365
Noguchi N, Abduriyim A, Shimizu I, Kamegata N, Odakea S, Kagia H (2013) J Raman Spectrosc 44:147–154
Nugent KW, Prawer S (1998) Diam Relat Mater 7:215–221
Odusote JK, Cornish LA, Chown LH, Erasmus RM (2013) Corros Sci 70:276–284
Panneerselvam R, Liu G-K, Wang Y-H, Liu J-Y, Ding S-Y, Li J-F, Wu D-Y, Tian Z-Q (2018) Chem Commun 54:10–25
Parsons BJ (1977) Proc R Soc Lon Ser-A 352:397–417
Pezzotti G (2007) Expert Rev Med Devic 4:165–189
Postmus C, Ferraro JR, Mitra SS (1968) Phys Rev 174:983–987
Rahaman M, Rodriguez RD, Plechinger G, Moras S, Schüller C, Korn T, Zahn DRT (2017) Nano Lett 17:6027–6033
Raman CV (1928) Indian J Phys 2:387–398
Raman CV, Krishnan KS (1928) Nature 121:501–502
Richter H, Wang ZP, Ley L (1981) Solid State Commun 39:625–629
Roberts SG (1988) Philos Mag A 58:347–364
Sato N (1989) Corros Sci 31:1–19
Sato N (1997) Corros Sci 27:421–433
Sharma SK, Mao HK, Bell PM, Xu JA (1985) J Raman Spectrosc 16:350–352
Sherif E-SM, Erasmus RM, Comins JD (2010) Electrochim Acta 55:3657–3663
Srikar VT, Swan AK, Ünlü MS, Goldberg BB, Spearing SM (2003) J Microelectromech S 12:779–787
Stansbury EE, Buchanan RA (2000) Fundamentals of electrochemical corrosion, 1st edn. ASM International (Publishers), Ohio
Starman LA Jr, Lott JA, Amer MS, Cowan WD, Busbee JD (2003) Sensors Actuat A-Phys 104:107–116
Tarun A, Hayazawa N, Kawata S (2009) Anal Bioanal Chem 394:1775–1785
Thorne AP (1988) Spectrophysics, 2nd edn. Chapman and Hall, London
Uehara K, Yamaya S (1988) Int J Refract Met H 7:219–223
Van Camp PE, Van Doren VE, Devreese JT (1992) Solid State Commun 84:731–733
Vhareta M, Erasmus RM, Comins JD (2014) Diam Relat Mater 45:34–42
Wei J, Wang A, Lambert JL, Wettergreen D, Cabrol N, Warren-Rhodes K, Zacny K (2015) J Raman Spectrosc 46:810–821
Whalley E, Lavergne A, Wong PTT (1976) Rev Sci Instrum 47:845–848
Yeo B-S, Stadler J, Schmid T, Zenobi R, Zhang W (2009) Chem Phys Lett 472:1–13
Zakroczymski T, Fan C-J, Szklarska-Smialowska Z (1985) J Electrochem Soc 132:2868–2871
Zhao Q, Wagner HD (2004) Philos T Roy Soc A 362:2407–2424
Acknowledgements
Financial support from the National Research Foundation (NRF) of South Africa under Grant No 2053306, the DST-NRF Centre of Excellence in Strong Materials hosted by the University of the Witwatersrand, the University of the Witwatersrand, Johannesburg, and the African Laser Centre (ALC) is gratefully acknowledged.
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Erasmus, R.M., Comins, J.D. (2018). Raman Scattering. In: Ida, N., Meyendorf, N. (eds) Handbook of Advanced Non-Destructive Evaluation. Springer, Cham. https://doi.org/10.1007/978-3-319-30050-4_29-1
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