Skip to main content

Mesoporous Carbon for Energy

  • Chapter
  • First Online:
Anisotropic Nanomaterials

Part of the book series: NanoScience and Technology ((NANO))

  • 2178 Accesses

Abstract

Ordered mesoporous carbons (OMCs) are of great interest in energy-related research and applications, partly due to their high surface areas, uniform pore channels, and narrow pore size distributions. During the past decades, a number of breakthroughs for the synthesis of OMCs, including hard templating methods and soft templating strategies, have been made by carbon chemists. Thanks to unique properties, OMCs-based supercapacitors are attracting more and more attention around the world in recent years in view of their ultrafast charge-discharge rate, high power capability, low maintenance, and long cycle life. In this chapter, we wish to overview those representative pathways for OMC materials and their performance in supercapacitor application.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Antonietti, K. Müllen, Carbon: the sixth element. Adv. Mater. 22, 787 (2010)

    Article  Google Scholar 

  2. H. Liang, Q. Guan, L. Chen, Z. Zhu, W. Zhang, S.-H. Yu, Macroscopic-scale template synthesis of robust carbonaceous nanofiber hydrogels and aerogels and their applications. Angew. Chem. Int. Ed. 51, 5101–5105 (2012)

    Article  Google Scholar 

  3. J. Wei, D. Zhou, Z. Sun, Y. Deng, Y. Xia, D.Y. Zhao, A controllable synthesis of rich nitrogen-doped ordered mesoporous carbon for CO2 capture and supercapacitors. Adv. Funct. Mater. 23, 2322–2328 (2013)

    Article  Google Scholar 

  4. P.F. Zhang, J. Yuan, T. Fellinger, M. Antonietti, H.R. Li, Y. Wang, Improving hydrothermal carbonization by using poly(ionic liquid)s. Angew. Chem. Int. Ed. 52, 6028–6032 (2013)

    Article  Google Scholar 

  5. M. Titirici, M. Antonietti, Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization. Chem. Soc. Rev. 39, 103–116 (2010)

    Article  Google Scholar 

  6. N. Baccile, M. Antonietti, M.-M. Titirici, One-step hydrothermal synthesis of nitrogen-doped nanocarbons: albumine directing the carbonization of glucose. Chem. Sus. Chem. 3, 246–253 (2010)

    Article  Google Scholar 

  7. Q. Wang, H. Li, L.Q. Chen, X.J. Huang, Monodispersed hard carbon spherules with uniform nanopores. Carbon 39, 2211–2214 (2001)

    Article  Google Scholar 

  8. S. Joo, S. Choi, I. Oh, J. Kwak, Z. Liu, O. Terasaki, R. Ryoo, Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature 412, 169 (2001)

    Article  ADS  Google Scholar 

  9. A.H. Lu, J. Nitz, M. Comotti, C. Weidenthaler, K. Schlichte, C. Lehmann, O. Terasaki, F. Schüth, Spatially and size selective synthesis of Fe-based nanoparticles on ordered mesoporous supports as highly active and stable catalysts for ammonia decomposition. J. Am. Chem. Soc. 132, 14152–14162 (2010)

    Article  Google Scholar 

  10. J. Liang, Y. Zheng, J. Chen, J. Liu, D. Hulicova-Jurcakova, M. Jaroniec, S.Z. Qiao, Facile oxygen reduction on a three-dimensionally ordered macroporous graphitic C3N4/Carbon composite electrocatalyst. Angew. Chem. Int. Ed. 51, 3892–3896 (2012)

    Article  Google Scholar 

  11. Y. Zhai, Y. Dou, D.Y. Zhao, P.F. Fulvio, R.T. Mayes, S. Dai, Carbon materials for chemical capacitive energy storage. Adv. Mater. 23, 4828–4850 (2011)

    Article  Google Scholar 

  12. A.B. Fuertes, G. Lota, T.A. Centeno, E. Frackowiak, Templated mesoporous carbons for supercapacitor application. Electrochim. Acta 50, 2799–2805 (2005)

    Article  Google Scholar 

  13. H. Liu, X. Wang, W. Cui, Y. Dou, D. Zhao, Y.Y. Xia, Highly ordered mesoporous carbon nanofiber arrays from a crab shell biological template and its application in supercapacitors and fuel cells. J. Mater. Chem. 20, 4223–4230 (2010)

    Article  Google Scholar 

  14. Z. Qiao, B. Guo, A.J. Binder, J. Chen, G.M. Veith, S. Dai, Controlled synthesis of mesoporous carbon nanostructures via a “silica-assisted” strategy. Nano Lett. 13, 207–212 (2013)

    Article  ADS  Google Scholar 

  15. R. Ryoo, S. Joo, S. Jun, Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. J. Phys. Chem. B 103, 7743–7746 (1999)

    Article  Google Scholar 

  16. J. Lee, S. Yoon, T. Hyeon, S.M. Oh, K.B. Kim, Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors, Chem. Commun. 21, 2177–2178 (1999)

    Google Scholar 

  17. Z.J. Li, W.F. Yan, S. Dai, Surface functionalization of ordered mesoporous carbons–a comparative study. Langmuir 21, 11999–12006 (2005)

    Article  Google Scholar 

  18. Z.J. Li, S. Dai, Surface functionalization and pore size manipulation for carbons of ordered structure. Chem. Mater. 17, 1717–1721 (2005)

    Article  Google Scholar 

  19. S. Jun, S.H. Joo, R. Ryoo, M. Kruk, M. Jaroniec, Z. Liu, T. Ohsuna, O. Terasaki, Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J. Am. Chem. Soc. 122, 10712–10713 (2000)

    Article  Google Scholar 

  20. H. Darmstadt, C. Roy, S. Kaliaguine, S. Choi, R. Ryoo, Surface chemistry of ordered mesoporous carbons. Carbon 40, 2673–2683 (2002)

    Article  Google Scholar 

  21. A.H. Lu, A. Kiefer, W. Schmidt, F. Schüth, Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures. Chem. Mater. 16, 100–103 (2004)

    Article  Google Scholar 

  22. Y. Wan, Y. Shi, D.Y. Zhao. Designed synthesis of mesoporous solids via nonionic-surfactant-templating approach. Chem. Commun. (9)897–926 (2007)

    Google Scholar 

  23. Y. Ren, Z. Ma, P.G. Bruce, Ordered mesoporous metal oxides: synthesis and applications. Chem. Soc. Rev. 41, 4909–4927 (2012)

    Article  Google Scholar 

  24. C. Liang, K. Hong, G.A. Guiochon, J.W. Mays, S. Dai, Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers. Angew. Chem. Int. Ed. 43, 5785–5789 (2004)

    Article  Google Scholar 

  25. S. Tanaka, N. Nishiyama, Y. Egashira, K. Ueyama. Synthesis of ordered mesoporous carbons with channel structure from an organic–organic nanocomposite, Chem. Commun. 2125–2127 (2005)

    Google Scholar 

  26. Y. Wan, Y. Shi, D.Y. Zhao, Supramolecular aggregates as templates: ordered mesoporous polymers and carbons. Chem. Mater. 20, 932–945 (2008)

    Article  Google Scholar 

  27. Y. Meng, D. Gu, F. Zhang, Y. Shi, H. Yang, Z. Li, C. Yu, B. Tu, D.Y. Zhao, Ordered mesoporous polymers and homologous carbon frameworks: amphiphilic surfactant templating and direct transformation. Angew. Chem. Int. Ed. 44, 7053–7059 (2005)

    Article  Google Scholar 

  28. Y. Deng, T. Yu, Y. Wan, Y. Shi, Y. Meng, D. Gu, L. Zhang, Y. Huang, C. Liu, X. Wu, D.Y. Zhao, Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene. J. Am. Chem. Soc. 129, 1690–1697 (2007)

    Article  Google Scholar 

  29. K.M. Nelson, Z. Qiao, S.M. Mahurin, R.T. Mayes, C.A. Bridges, S. Dai, A non-micellar synthesis of mesoporous carbon via spinodal decomposition. RSC Adv. 4, 23703–23706 (2014)

    Article  Google Scholar 

  30. C. Liang, S. Dai, Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction. J. Am. Chem. Soc. 128, 5316–5317 (2006)

    Article  Google Scholar 

  31. S. Kubo, R.J. White, N. Yoshizawa, M. Antonietti, M.-M. Titirici, Ordered carbohydrate-derived porous carbons. Chem. Mater. 23, 4882–4885 (2011)

    Article  Google Scholar 

  32. S. Schlienger, A. Graff, A. Celzard, J. Parmentier, Direct synthesis of ordered mesoporous polymer and carbon materials by a biosourced precursor. Green Chem. 14, 313–316 (2012)

    Article  Google Scholar 

  33. S. Wang, C. Han, J. Wang, J. Deng, M. Zhu, J. Yao, H. Li, Y. Wang, Controlled synthesis of ordered mesoporous carbohydrate-derived carbons with flower-like structure and N-doping by self-transformation. Chem. Mater. 26, 6872–6877 (2014)

    Article  Google Scholar 

  34. X. Wang, J. Lee, C. Tsouris, D.W. DePaoli, S. Dai, Preparation of activated mesoporous carbons for electrosorption of ions from aqueous solutions. J. Mater. Chem. 20, 4602–4608 (2010)

    Article  Google Scholar 

  35. R. Liu, Y. Shi, Y. Wan, Y. Meng, F. Zhang, D. Gu, Z. Chen, B. Tu, D.Y. Zhao, Triconstituent co-assembly to ordered mesostructured polymer–silica and carbon–silica nanocomposites and large-pore mesoporous carbons with high surface areas. J. Am. Chem. Soc. 128, 11652–11662 (2006)

    Article  Google Scholar 

  36. H. Li, R. Liu, D.Y. Zhao, Y.-Y. Xia, Electrochemical properties of an ordered mesoporous carbon prepared by direct tri-constituent co-assembly. Carbon 45, 2628–2635 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

P.F.Z. and S.D. were supported as part of the Fluid Interface Reactions, Structures, and Transport (FIRST) Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sheng Dai .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Zhang, P., Dai, S. (2015). Mesoporous Carbon for Energy. In: Li, Q. (eds) Anisotropic Nanomaterials. NanoScience and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-18293-3_11

Download citation

Publish with us

Policies and ethics