Skip to main content

Starch and Nanoparticle

  • Reference work entry
  • First Online:
Polysaccharides

Abstract

Nanotechnology and renewable bio-based materials are driving forces for the development of new materials that combine innovative properties and sustainability. Starch is an abundant, natural, renewable, and biodegradable polymer produced by many plants as a source of stored energy. Because of the multiscale structure of starch granules consisting of alternating crystalline and amorphous concentric layers, the controlled acid hydrolysis treatment of native starch disrupts this organization and releases crystalline platelet-like particles with nanoscale dimensions. This chapter intends to provide a comprehensive overview of their preparation, characterization, properties, and applications. The preparation and morphology of starch nanocrystals are exposed as well as strategies intended to improve the existing current methods. The properties of ensuing aqueous suspensions and reported surface chemical modifications are also presented. The preparation of polymer nanocomposites reinforced with starch nanocrystals and their properties is then reviewed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 999.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 549.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Alila S, Aloulou F, Thielemans W, Boufi S (2011) Sorption potential of modified nanocrystals for the removal of aromatic organic pollutant from aqueous solution. Ind Crop Prod 33:350–357

    Article  CAS  Google Scholar 

  • Angellier H, Choisnard L, Molina-Boisseau S, Ozil P, Dufresne A (2004) Optimization of the preparation of aqueous suspensions of waxy maize starch nanocrystals using a response surface methodology. Biomacromolecules 5:1545–1551

    Article  CAS  Google Scholar 

  • Angellier H, Putaux JL, Molina-Boisseau S, Dupeyre D, Dufresne A (2005a) Starch nanocrystals fillers in an acrylic polymer matrix. Macromol Symp 221:95–104

    Article  CAS  Google Scholar 

  • Angellier H, Molina-Boisseau S, Lebrun L, Dufresne A (2005b) Processing and structural properties of waxy maize starch nanocrystals reinforced natural rubber. Macromolecules 38:3783–3792

    Article  CAS  Google Scholar 

  • Angellier H, Molina-Boisseau S, Belgacem MN, Dufresne A (2005c) Surface chemical modification of waxy maize starch nanocrystals. Langmuir 21:2425–2433

    Article  CAS  Google Scholar 

  • Angellier H, Molina-Boisseau S, Dufresne A (2005d) Mechanical properties of waxy maize starch nanocrystals reinforced natural rubber. Macromolecules 38:9161–9170

    Article  CAS  Google Scholar 

  • Angellier H, Molina-Boisseau S, Dufresne A (2006a) Waxy maize starch nanocrystals as filler in natural rubber. Macromol Symp 233:132–136

    Article  CAS  Google Scholar 

  • Angellier H, Molina-Boisseau S, Dole P, Dufresne A (2006b) Thermoplastic starch-waxy maize starch nanocrystals nanocomposites. Biomacromolecules 7:531–539

    Article  CAS  Google Scholar 

  • Angellier-Coussy H, Putaux JL, Molina-Boisseau S, Dufresne A, Bertoft E, Perez S (2009) The molecular structure of waxy maize starch nanocrystals. Carbohydr Res 344:1558–1566

    Article  CAS  Google Scholar 

  • Battista OA (1975) Microcrystal polymer science. McGraw-Hill, New York

    Google Scholar 

  • BelHaaj S, Ben Mabrouk A, Thielemans W, Boufi S (2013) A one-step miniemulsion polymerization route towards the synthesis of nanocrystal reinforced acrylic nanocomposites. Soft Matter 9:1975–1984

    Article  CAS  Google Scholar 

  • Bouthegourd E, Rajisha KR, Kalarical N, Saiter JM, Thomas S (2011) Natural rubber latex/potato starch nanocrystal nanocomposites: correlation morphology/electrical properties. Mater Lett 65:3615–3617

    Article  CAS  Google Scholar 

  • Bruntland G (1987) Our common future. The world commission on environment and development. Oxford University Press, Oxford

    Google Scholar 

  • Buléon A, Colonna P, Planchot V, Ball S (1998) Starch granules: structure and biosynthesis. Int J Biol Macromol 23:85–112

    Article  Google Scholar 

  • Chang PR, Ai F, Chen Y, Dufresne A, Huang J (2009) Effects of starch nanocrystal-graft-polycaprolactone on mechanical properties of waterborne polyurethane-based nanocomposites. J Appl Polym Sci 111:619–627

    Article  CAS  Google Scholar 

  • Chen Y, Cao X, Chang PR, Huneault MA (2008a) Comparative study on the films of poly(vinyl alcohol)/pea starch nanocrystals and poly(vinyl alcohol)/native pea starch. Carbohydr Polym 73:8–17

    Article  CAS  Google Scholar 

  • Chen G, Wei M, Chen J, Huang J, Dufresne A, Chang PR (2008b) Simultaneous reinforcing and toughening: new nanocomposites of waterborne polyurethane filled with low loading level of starch nanocrystals. Polymer 49:1860–1870

    Article  CAS  Google Scholar 

  • Duan B, Sun P, Wang X, Yang C (2011) Preparation and properties of starch nanocrystals/carboxymethyl chitosan nanocomposite films. Starch-Starke 63:528–535

    Article  CAS  Google Scholar 

  • Dubief D, Samain E, Dufresne A (1999) Polysaccharide microcrystals reinforced amorphous poly(β-hydroxyoctanoate) nanocomposite materials. Macromolecules 32:5765–5771

    Article  CAS  Google Scholar 

  • Dufresne A, Cavaillé JY (1998) Clustering and percolation effect in microcrystalline starch reinforced thermoplastic. J Polym Sci B 36:2211–2224

    Article  CAS  Google Scholar 

  • Dufresne A, Cavaillé JY, Helbert W (1996) New nanocomposite materials: microcrystalline starch reinforced thermoplastic. Macromolecules 29:7624–7626

    Article  CAS  Google Scholar 

  • Gallant DJ, Bouchet B, Baldwin PM (1997) Microscopy of starch: evidence of a new level of granule organization. Carbohydr Polym 32:177–191

    Article  CAS  Google Scholar 

  • Garcia NL, Ribba L, Dufresne A, Aranguren MI, Goyanes S (2009) Physico-mechanical properties of biodegradable starch nanocomposites. Macromol Mater Eng 294:169–177

    Article  CAS  Google Scholar 

  • Garcia NL, Ribba L, Dufresne A, Aranguren MI, Goyanes S (2011) Effect of glycerol on the morphology of nanocomposites made from thermoplastic starch and starch nanocrystals. Carbohydr Polym 84:203–210

    Article  CAS  Google Scholar 

  • Habibi Y, Dufresne A (2008) Highly filled bionanocomposites from functionalized polysaccharide nanocrystals. Biomacromolecules 9:1975–1980

    Article  Google Scholar 

  • http://ec.europa.eu/agriculture/eval/reports/amidon/chap1.pdf. Accessed 10 May 2014

  • Jayakody L, Hoover R (2002) The effect of lintnerization on cereal starch granules. Food Res Int 35:665–680

    Article  CAS  Google Scholar 

  • Jivan MJ, Madadlou A, Yarmand M (2013) An attempt to cast light into starch nanocrystals preparation. Food Chem 141:1661–1666

    Article  CAS  Google Scholar 

  • Katz JR (1930) Abhandlungen zur physikalischen Chemie der Stärke und der Brotbereitung. Z Phys Chem 150:37–59

    CAS  Google Scholar 

  • Kim JY, Lim ST (2009) Preparation of nano-sized starch particles by complex formation with n-butanol. Carbohydr Polym 76:110–116

    Article  CAS  Google Scholar 

  • Kristo E, Biliaderis CG (2007) Physical properties of starch nanocrystal-reinforced pullulan films. Carbohydr Polym 68:146–158

    Article  CAS  Google Scholar 

  • Labet M, Thielemans W, Dufresne A (2007) Polymer grafting onto starch nanocrystals. Biomacromolecules 8:2916–2927

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2010) Starch nanoparticles: a review. Biomacromolecules 11:1139–1153

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2011a) Influence of botanic origin and amylose content on the morphology of starch nanocrystals. J Nanopart Res 86:1565–1572

    CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2011b) Evidence of micro and nano-scaled particles during starch nanocrystals preparation and their isolation. Biomacromolecules 12:3039–3046

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2011c) Ceramic membrane filtration for isolating starch nanocrystals. Carbohydr Polym 86:1565–1572

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Choisnard L, Dufresne A (2012a) Optimization of the batch preparation of starch nanocrystals to reach daily time-scale. Starch-Starke 64:489–496

    Article  CAS  Google Scholar 

  • LeCorre D, Vahanian E, Dufresne A, Bras J (2012b) Enzymatic pretreatment for preparing starch nanocrystals. Biomacromolecules 13:132–137

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2012c) Influence of native starch’s properties on starch nanocrystals thermal properties. Carbohydr Polym 87:658–666

    Article  CAS  Google Scholar 

  • LeCorre D, Bras J, Dufresne A (2012d) Influence of starch nanocrystals’ botanic origin on morphological and mechanical properties of natural rubber nanocomposites. Macromol Mater Eng 297:969–978

    Article  CAS  Google Scholar 

  • LeCorre D, Hohenthal C, Dufresne A, Bras J (2013) Comparative sustainability assessment of starch nanocrystals. J Polym Environ 21:71–80

    Article  CAS  Google Scholar 

  • LeCorre D, Dufresne A, Rueff M, Khelifi B, Bras J (2014) All starch nanocomposite coating for barrier material. J Appl Polym Sci 131:39826, 7 pp

    Article  Google Scholar 

  • Li C, Sun P, Yang C (2012) Emulsion stabilized by starch nanocrystals. Starch-Starke 64:497–502

    Article  CAS  Google Scholar 

  • Lin N, Huang J, Chang PR, Feng L, Yu J (2011) Effect of polysaccharide nanocrystals on structure, properties, and drug release kinetics of alginate-based microspheres. Colloids Surf B 85:270–279

    Article  CAS  Google Scholar 

  • Lin N, Huang J, Dufresne A (2012) Preparation, properties and applications of polysaccharide nanocrystals in advanced functional nanomaterials: a review. Nanoscale 4:3274–3294

    Article  CAS  Google Scholar 

  • Lintner CJ (1886) Studien über die diastase. J Prakt Chem 34:378–386

    Article  Google Scholar 

  • Liu D, Wu Q, Chen H, Chang PR (2009) Transitional properties of micro- to nano-sized starch particles manufactured via a green process. J Colloid Interface Sci 339:117–124

    Article  CAS  Google Scholar 

  • Ma X, Jian R, Chang PR, Yu J (2008) Fabrication and characterization of citric acid-modified starch nanoparticles/plasticized-starch composites. Biomacromolecules 9:3314–3320

    Article  CAS  Google Scholar 

  • Mélé P, Angellier-Coussy H, Molina-Boisseau S, Dufresne A (2011) Reinforcing mechanisms of starch nanocrystals in a nonvulcanized natural rubber matrix. Biomacromolecules 12:1487–1493

    Article  Google Scholar 

  • Muhr AH, Blanshard JMV, Bates DR (1984) The effect of lintnerisation on wheat and potato starch granules. Carbohydr Polym 4:399–425

    Article  CAS  Google Scholar 

  • Nägeli CW (1874) Beitage zur näheren Kenntniss des starke grupe. Annalen der Chemie 173:218–227

    Article  Google Scholar 

  • Namazi H, Dadkhah A (2008) Surface modification of starch nanocrystals through ring-opening polymerization of ε-caprolactone and investigation of their microstructures. J Appl Polym Sci 110:2405–2412

    Article  CAS  Google Scholar 

  • Namazi H, Dadkhah A (2010) Convenient method for preparation of hydrophobically modified starch nanocrystals with using fatty acids. Carbohydr Polym 79:731–737

    Article  CAS  Google Scholar 

  • Putaux JL (2005) Morphology and structure of crystalline polysaccharides: some recent studies. Macromol Symp 229:66–71

    Article  CAS  Google Scholar 

  • Putaux JL, Molina-Boisseau S, Momaur T, Dufresne A (2003) Platelet nanocrystals resulting from the disruption of waxy maize starch granules by acid hydrolysis. Biomacromolecules 4:1198–1202

    Article  CAS  Google Scholar 

  • Ren L, Jiang M, Wang L, Zhou J, Tong J (2012) A method for improving dispersion of starch nanocrystals in water through crosslinking modification with sodium hexametaphosphate. Carbohydr Polym 87:1874–1876

    Article  CAS  Google Scholar 

  • Robin JP (1976) Comportement du grain d’amidon à l’hydrolyse acide ménagée. Etude physico-chimique et enzymatique de la fraction insoluble. Contribution à la connaissance de la structure de l’amylopectine. PhD thesis, Université Pierre et Marie Curie, Paris

    Google Scholar 

  • Robin JP, Mercier C, Duprat RF, Charbonniere R, Guibot A (1975) Amidons lintnérisés. Etudes chromatographique et enzymatique des résidus insolubles provenant de l’hydrolyse chlorhydrique d’amidons de céréales, en particulier de maïs cireux. Die Stärke 27:36–45

    Article  CAS  Google Scholar 

  • Singh V, Ali SZ (2000) Acid degradation of starch. The effect of acid and starch type. Carbohydr Polym 41:191–195

    Article  CAS  Google Scholar 

  • Song S, Wang C, Pan Z, Wang X (2008) Preparation and characterization of amphiphilic starch nanocrystals. J Appl Polym Sci 107:418–422

    Article  CAS  Google Scholar 

  • Thielemans W, Belgacem MN, Dufresne A (2006) Starch nanocrystals with large chain surface modifications. Langmuir 22:4804–4810

    Article  CAS  Google Scholar 

  • Viguié J, Molina-Boisseau S, Dufresne A (2007) Processing and characterization of waxy maize starch films plasticized by sorbitol and reinforced with starch nanocrystals. Macromol Biosci 7:1206–1216

    Article  Google Scholar 

  • Wang Y, Tian H, Zhang L (2010) Role of starch nanocrystals and cellulose whiskers in synergistic reinforcement of waterborne polyurethane. Carbohydr Polym 80:665–671

    Article  CAS  Google Scholar 

  • Wei B, Hu X, Li H, Wu C, Xu X, Jin Z, Tian Y (2014) Effect of pHs on dispersivity of maize starch nanocrystals in aqueous medium. Food Hydrocoll 36:369–373

    Article  CAS  Google Scholar 

  • Xu Y, Ding W, Liu J, Li Y, Kennedy JF, Gu Q, Shao S (2010) Preparation and characterization of organic-soluble acetylated starch nanocrystals. Carbohydr Polym 80:1078–1084

    Article  CAS  Google Scholar 

  • Yu J, Ai F, Dufresne A, Gao S, Huang J, Chang PR (2008) Structure and mechanical properties of poly(lactic acid) filled with (starch nanocrystal)-graft-poly(ε-caprolactone). Macromol Mater Eng 293:763–770

    Article  CAS  Google Scholar 

  • Zheng H, Ai F, Chang PR, Huang J, Dufresne A (2009) Structure and properties of starch nanocrystal-reinforced soy protein plastics. Polym Compos 30:474–480

    Article  CAS  Google Scholar 

  • Zobel HF (1988) Starch crystal transformation and their industrial importance. Starch/Sträke 40:1–7

    Article  CAS  Google Scholar 

  • Zou J, Zhang F, Huang J, Chang PR, Su Z, Yu J (2011) Effects of starch nanocrystals on structure and properties of waterborne polyurethane-based composites. Carbohydr Polym 85:824–831

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Alain Dufresne .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this entry

Cite this entry

Dufresne, A. (2015). Starch and Nanoparticle. In: Ramawat, K., Mérillon, JM. (eds) Polysaccharides. Springer, Cham. https://doi.org/10.1007/978-3-319-16298-0_72

Download citation

Publish with us

Policies and ethics