Abstract
Surface modification is an effective way of improving the tribological properties of base materials and is now actively being used in the automotive industry. Surface wettability can affect the overall performance of automotive components, such as windshields and mirrors, and controlling the surface hydrophobicity or hydrophilicity has been a major focus of research work in this industry. Diamond-like carbon (DLC), which is an amorphous carbon compound with outstanding mechanical and tribological properties, has gained considerable attention as a superior functional coating material and has been successfully applied to a range of mechanical automotive components, leading to better performance and durability. Recently, DLC-based materials with special wettability have been successfully used for the development of superhydrophobic and superhydrophilic surfaces, and a variety of industrial as well as biomedical applications have been proposed. Undoubtedly, being able to control the surface wettability using such DLC-based materials with tunable wettability would expand the original capabilities of the materials used in the automotive industry today. In this chapter, after giving a brief introduction to the fundamentals of surface wettability in relation to DLC coatings, we review recent studies on the control of surface wettability using DLC-based materials and then discuss future outlook.
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References
J. R. Sayer, M. L. Mefford, M. J. Flannagan, M. Sivak, S. Kojima (1997). The influence of hydrophobic windshield coating on driver visual performance. UMTRI-97-31.
J. R. Sayer, M. L. Mefford, M. J. Flannagan, M. Sivak (1999). The effects of hydrophobic treatment of the driver-side window and rearview mirror on distance judgement. UMTRI-99-22.
J. R. Sayer, M. L. Mefford (2001). The effect of hydrophilic and hydrophobic rear window treatments on visual performance, The University of Michigan Transportation Research Institute. UMTRI-2001-21.
R. Wang, K. Hashimoto, A. Fujishima, M. Chikuni, E. Kojima, A. Kitamura, M. Shimohigoshi, T. Watanabe, Light-induced amphiphilic surfaces. Nature 388 (1997) 431.
A. R. Parker, C. R. Lawrence, Water capture by a desert beetle. Nature 414 (2001) 33.
I. P. Parkin, R. G. Palgrave, Self-cleaning coatings. Journal of Materials Chemistry 15 (2005) 1689.
A. H. Yan, X. C. Xiao, I. Kulaots, B. W. Sheldon, R. H. Hurt, Controlling water contact angle on carbon surfaces from 5 degrees to 167 degrees. Carbon 44 (2006) 3116.
R. N. Wenzel, Resistance of solid surfaces to wetting by water. Industrial and Engineering Chemistry 28 (1936) 988.
A. B. D. Cassie, S. Baxter, Wettability of porous surfaces. Transactions of the Faraday Society 40 (1944) 546.
V. Zorba, E. Stratakis, M. Barberoglou, E. Spanakis, P. Tzanetakis, S. H. Anastasiadis, C. Fotakis, Biomimetic artificial surfaces quantitatively reproduce the water repellency of a lotus leaf. Advanced Materials 20 (2008) 4049.
K. Koch, W. Barthlott, Superhydrophobic and superhydrophilic plant surfaces: an inspiration for biomimetic materials. Philosophical Transactions of the Royal Society a-Mathematical Physical and Engineering Sciences 367 (2009) 1487.
W. Barthlott, C. Neinhuis, Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 202 (1997) 1.
Y. M. Zheng, D. Han, J. Zhai, L. Jiang, In situ investigation on dynamic suspending of microdroplet on lotus leaf and gradient of wettable micro- and nanostructure from water condensation. Applied Physics Letters 92 (2008) 084106.
H. F. Meng, S. T. Wang, J. M. Xi, Z. Y. Tang, L. Jiang, Facile means of preparing superamphiphobic surfaces on common engineering metals. Journal of Physical Chemistry C 112 (2008) 11454.
J. M. Xi, L. Feng, L. Jiang, A general approach for fabrication of superhydrophobic and superamphiphobic surfaces. Applied Physics Letters 92 (2008) 053102.
W. C. Wu, X. L. Wang, D. A. Wang, M. Chen, F. Zhou, W. M. Liu, Q. J. Xue, Alumina nanowire forests via unconventional anodization and super-repellency plus low adhesion to diverse liquids. Chemical Communications (2009) 1043.
T.-Y. Kim, B. Ingmar, K. Bewilogua, K. H. Oh, K.-R. Lee, Wetting behaviours of a-C:H:Si:O film coated nano-scale dual rough surface. Chemical Physics Letters 436 (2007) 199.
Y. Rahmawan, M.-W. Moon, K.-S. Kim, K.-R. Lee, K.-Y. Suh, Wrinkled, dual-scale structures of diamond-like carbon (DLC) for superhydrophobicity. Langmuir 26 (2010) 484.
T.-G. Cha, J. W. Yi, M.-W. Moon, K.-R. Lee, H.-Y. Kim, Nanoscale patterning of microtextured surfaces to control superhydrophobic robustness. Langmuir 26 (2010) 8319.
Aisenber S., Chabot R. (1971) Ion-beam deposition of thin films of diamondlike carbon. Journal of Applied Physics. 42: 2953.
C. Donnet, J. Fontaine, F. Lefebvre, A. Grill, V. Patel, C. Jahnes, Solid state C-13 and H-1 nuclear magnetic resonance investigations of hydrogenated amorphous carbon. Journal of Applied Physics 85 (1999) 3264.
D. R. McKenzie, Tetrahedral bonding in amorphous carbon. Reports on Progress in Physics 59 (1996) 1611.
J. Robertson, Properties of diamond-like carbon. Surface & Coatings Technology 50 (1992) 185.
A. Erdemir, C. Donnet, Tribology of diamond-like carbon films: recent progress and future prospects. Journal of Physics D-Applied Physics 39 (2006) R311.
K.-R. Lee, Y.-J. Baik, K. Y. Eun, S. Han, Precursor gas effect on the structure and properties of diamond-like carbon-films. Diamond and Related Materials 3 (1994) 1230.
P. A. Dearnley, A. Neville, S. Turner, H. J. Scheibe, R. Tietema, R. Tap, M. Stuber, P. Hovsepian, A. Layyous, B. Stenbom, Coatings tribology drivers for high density plasma technologies. Surface Engineering 26 (2010) 80.
K.-R. Lee, M.-G. Kim, S.-J. Cho, K. Y. Eun, T.-Y. Seong, Structural dependence of mechanical properties of Si incorporated diamond-like carbon films deposited by RF plasma-assisted chemical vapour deposition. Thin Solid Films 308 (1997) 263.
P. Papakonstantinou, J. F. Zhao, P. Lemoine, E. T. McAdams, J. A. McLaughlin, The effects of Si incorporation on the electrochemical and nanomechanical properties of DLC thin films. Diamond and Related Materials 11 (2002) 1074.
T. I. T. Okpalugo, A. A. Ogwu, P. D. Maguire, J. A. D. McLaughlin, Platelet adhesion on silicon modified hydrogenated amorphous carbon films. Biomaterials 25 (2004) 239.
H.-G. Kim, S.-H. Ahn, J.-G. Kim, S. J. Park, K.-R. Lee, Effect of Si-incorporation on wear-corrosion properties of diamond-like carbon films. Thin Solid Films 482 (2005) 299.
P. D. Maguire, J. A. McLaughlin, T. I. T. Okpalugo, P. Lemoine, P. Papakonstantinou, E. T. McAdams, M. Needham, A. A. Ogwu, M. Ball, G. A. Abbas, Mechanical stability, corrosion performance and bioresponse of amorphous diamond-like carbon for medical stents and guidewires. Diamond and Related Materials 14 (2005) 1277.
A. A. Ogwu, T. I. T. Okpalugo, N. Ali, R. D. Maguire, J. A. D. McLaughlin, Endothelial cell growth on silicon modified hydrogenated amorphous carbon thin films. Journal of Biomedical Materials Research Part B-Applied Biomaterials 85B (2008) 105.
B. J. Jones, A. Mahendran, A. W. Anson, A. J. Reynolds, R. Bulpett, J. Franks, Diamond-like carbon coating of alternative metal alloys for medical and surgical applications. Diamond and Related Materials 19 (2010) 685.
T. Saito, T. Hasebe, S. Yohena, Y. Matsuoka, A. Kamijo, K. Takahashi, T. Suzuki, Antithrombogenicity of fluorinated diamond-like carbon films. Diamond and Related Materials 14 (2005) 1116.
T. Hasebe, A. Shimada, T. Suzuki, Y. Matsuoka, T. Saito, S. Yohena, A. Kamijo, N. Shiraga, M. Higuchi, K. Kimura, H. Yoshimura, S. Kuribayashi, Fluorinated diamond-like carbon as antithrombogenic coating for blood-contacting devices. Journal of Biomedical Materials Research Part A 76A (2006) 86.
T. Hasebe, S. Yohena, A. Kamijo, Y. Okazaki, A. Hotta, K. Takahashi, T. Suzuki, Fluorine doping into diamond-like carbon coatings inhibits protein adsorption and platelet activation. Journal of Biomedical Materials Research Part A 83A (2007) 1192.
H. W. Choi, J.-H. Choi, K.-R. Lee, J.-P. Ahn, K. H. Oh, Structure and mechanical properties of Ag-incorporated DLC films prepared by a hybrid ion beam deposition system. Thin Solid Films 516 (2007) 248.
C. S. Lee, K.-R. Lee, K. Y. Eun, K. H. Yoon, J. H. Han, Structure and properties of Si incorporated tetrahedral amorphous carbon films prepared by hybrid filtered vacuum arc process. Diamond and Related Materials 11 (2002) 198.
S. Okuda, T. Dewa, T. Sagawa (2007). Development of 5W-30 GF-4 fuel-saving engine oil for DLC-coated valve lifters. SAE Technical Paper 2007-01-1979.
R. Gahlin, M. Larsson, P. Hedenqvist, Me-C:H coatings in motor vehicles. Wear 249 (2001) 302.
M. Kalin, J. Vizintin, The tribological performance of DLC-coated gears lubricated with biodegradable oil in various pinion/gear material combinations. Wear 259 (2005) 1270.
A. Gangopadhyay, D. G. McWatt, R. J. Zdrodowski, S. J. Simko, S. Matera, K. Sheffer, R. S. Furby, Valvetrain friction reduction through thin film coatings and polishing. Tribology Transactions 55 (2012) 99.
M. Grischke, A. Hieke, F. Morgenweck, H. Dimigen, Variation of the wettability of DLC-coatings by network modification using silicon and oxygen. Diamond and Related Materials 7 (1998) 454.
E. K. Her, T.-J. Ko, K.-R. Lee, K. H. Oh, M.-W. Moon, Bioinspired steel surfaces with extreme wettability contrast. Nanoscale 4 (2012) 2900.
T.-J. Ko, E. K. Her, B. Shin, H.-Y. Kim, K.-R. Lee, B. K. Hong, S. H. Kim, K. H. Oh, M.-W. Moon, Water condensation behavior on the surface of a network of superhydrophobic carbon fibers with high-aspect-ratio nanostructures. Carbon 50 (2012) 5085.
E. K. Her, T.-J. Ko, B. Shin, H. Roh, W. Dai, W. K. Seong, H.-Y. Kim, K.-R. Lee, K. H. Oh, M.-W. Moon, Superhydrophobic transparent surface of nanostructured poly(methyl methacrylate) enhanced by a hydrolysis reaction. Plasma Processes and Polymers 10 (2013) 481.
E. Yu, H. J. Lee, T.-J. Ko, S. J. Kim, K.-R. Lee, K. H. Oh, M.-W. Moon, Hierarchical structures of AlOOH nanoflakes nested on Si nanopillars with anti-reflectance and superhydrophobicity. Nanoscale 5 (2013) 10014.
S.-C. Cha, E. K. Her, T.-J. Ko, S. J. Kim, H. Roh, K.-R. Lee, K. H. Oh, M.-W. Moon, Thermal stability of superhydrophobic, nanostructured surfaces. Journal of Colloid and Interface Science 391 (2013) 152.
R. S. Butter, D. R. Waterman, A. H. Lettington, R. T. Ramos, E. J. Fordham, Production and wetting properties of fluorinated diamond-like carbon coatings. Thin Solid Films 311 (1997) 107.
G. Q. Yu, B. K. Tay, Z. Sun, Fluorinated amorphous diamond-like carbon films deposited by plasma-enhanced chemical vapor deposition. Surface & Coatings Technology 191 (2005) 236.
R. K. Roy, H. W. Choi, J. W. Yi, M.-W. Moon, K.-R. Lee, D. K. Han, J. H. Shin, A. Kamijo, T. Hasebe, Hemocompatibility of surface-modified, silicon-incorporated, diamond-like carbon films. Acta Biomaterialia 5 (2009) 249.
T. Hasebe, S. Nagashima, A. Kamijo, M.-W. Moon, Y. Kashiwagi, A. Hotta, K.-R. Lee, K. Takahashi, T. Yamagami, T. Suzuki, Hydrophobicity and non-thrombogenicity of nanoscale dual rough surface coated with fluorine-incorporated diamond-like carbon films: Biomimetic surface for blood-contacting medical devices. Diamond and Related Materials 38 (2013) 14.
S. Nagashima, T. Hasebe, A. Kamijo, Y. Yoshimoto, A. Hotta, H. Morita, H. Terada, M. Tanaka, K. Takahashi, T. Suzuki, Effect of oxygen plasma treatment on non-thrombogenicity of diamond-like carbon films. Diamond and Related Materials 19 (2010) 861.
J. W. Yi, M.-W. Moon, S. F. Ahmed, H. Kim, T.-G. Cha, H.-Y. Kim, S.-S. Kim, K.-R. Lee, Long-lasting hydrophilicity on nanostructured Si-incorporated diamond-like carbon films. Langmuir 26 (2010) 17203.
S. J. Kim, M.-W. Moon, K.-R. Lee, D.-Y. Lee, Y. S. Chang, H.-Y. Kim, Liquid spreading on superhydrophilic micropillar arrays. Journal of Fluid Mechanics 680 (2011) 477.
S. J. Kim, J. Kim, M.-W. Moon, K.-R. Lee, H.-Y. Kim, Experimental study of drop spreading on textured superhydrophilic surfaces. Physics of Fluids 25 (2013) 092110.
K. Bewilogua, G. Brauer, A. Dietz, J. Gabler, G. Goch, B. Karpuschewski, B. Szyszka, Surface technology for automotive engineering. CIRP Annals-Manufacturing Technology 58 (2009) 608.
J. L. Parker, P. M. Claesson, J. H. Wang, H. K. Yasuda, Surface forces between plasma polymer-films. Langmuir 10 (1994) 2766.
D. R. Tallant, J. E. Parmeter, M. P. Siegal, R. L. Simpson, The thermal-stability of diamond-like carbon. Diamond and Related Materials 4 (1995) 191.
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Nagashima, S., Moon, MW. (2015). Diamond-Like Carbon Coatings with Special Wettability for Automotive Applications. In: Cha, S., Erdemir, A. (eds) Coating Technology for Vehicle Applications. Springer, Cham. https://doi.org/10.1007/978-3-319-14771-0_11
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DOI: https://doi.org/10.1007/978-3-319-14771-0_11
Publisher Name: Springer, Cham
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