Abstract
Acid-catalyzed rearrangement of tertiary α-acetylenic (terminal) alcohols, leading to the formation of α,β-unsaturated ketones rather than the corresponding α,β- unsaturated aldehydes. Cf. Meyer–Schuster rearrangement.
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Li, J.J. (2014). Rupe rearrangement. In: Name Reactions. Springer, Cham. https://doi.org/10.1007/978-3-319-03979-4_239
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DOI: https://doi.org/10.1007/978-3-319-03979-4_239
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