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Ring-closing metathesis (RCM)

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Name Reactions

Abstract

All three catalysts are illustrated as “LnM=CHR” in the mechanism below. Generation of the real catalyst from the precatalysts

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References

  1. Schrock, R. R.; Murdzek, J. S.; Bazan, G. C.; Robbins, J.; DiMare, M.; O’Regan, M. J. Am. Chem. Soc. 1990, 112, 3875–3886. Richard Schrock is a professor at MIT. He shared the 2005 Nobel Prize in Chemistry with Robert Grubbs of Caltech and Yves Chauvin of Institut Français du Pétrole in France for their contributions to metathesis.

    Google Scholar 

  2. Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446–452. (Review).

    Google Scholar 

  3. Scholl, M.; Tunka, T. M.; Morgan, J. P.; Grubbs, R. H. Tetrahedron Lett. 1999, 40, 2247–2250.

    Article  CAS  Google Scholar 

  4. Fellows, I. M.; Kaelin, D. E., Jr.; Martin, S. F. J. Am. Chem. Soc. 2000, 122, 10781–10787.

    Article  CAS  Google Scholar 

  5. Timmer, M. S. M.; Ovaa, H.; Filippov, D. V.; van der Marel, G. A.; van Boom, J. H. Tetrahedron Lett. 2000, 41, 8635–8638.

    Article  CAS  Google Scholar 

  6. Thiel, O. R. Alkene and alkyne metathesis in organic synthesis. In Transition Metals for Organic Synthesis (2nd Edn.), 2004, 1, pp 321–333. (Review).

    Google Scholar 

  7. Smith, A. B., III; Basu, K.; Bosanac, T. J. Am. Chem. Soc. 2007, 129, 14872–14874.

    Article  CAS  Google Scholar 

  8. Hoveyda, A.H.; Zhugralin, A. R. Nature 2007, 450, 243–251. (Review).

    Google Scholar 

  9. Marvin, C. C.; Clemens, A. J. L.; Burke, S. D. Org. Lett. 2007, 9, 5353–5356.

    Article  CAS  Google Scholar 

  10. Keck, G. E.; Giles, R. L.; Cee, V. J.; Wager, C. A.; Yu, T.; Kraft, M. B. J. Org. Chem. 2008, 73, 9675–9691.

    Article  CAS  Google Scholar 

  11. Donohoe, T. J.; Fishlock, L. P.; Procopiou, P. A. Chem. Eur. J. 2008, 14, 5716–5726. (Review).

    Google Scholar 

  12. Sattely, E. S.; Meek, S. J.; Malcolmson, S. J.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 943–953.

    Article  CAS  Google Scholar 

  13. Moss, T. A. Tetrahedron Lett. 2013, 54, 993–997.

    Article  CAS  Google Scholar 

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Li, J.J. (2014). Ring-closing metathesis (RCM). In: Name Reactions. Springer, Cham. https://doi.org/10.1007/978-3-319-03979-4_232

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