Abstract
The availability of clean water is of pressing concern in developing countries and has been a key area of focus for research and development worldwide. The sixth Sustainable Development Goal of the United Nations emphasizes the need for clean water. Aromatic hydrocarbons are emerging organic contaminants that are being found frequently in drinking water, municipal wastewater, and surface water. Conventional wastewater treatment plants have been shown to have limited efficiency in removing these trace pollutants from water. Due to advantages including cost, effectiveness, simplicity of use, and reusability, the adsorption process is recognized as a promising water remediation technology for aromatic compound removal. Advanced carbon-based materials discussed in this chapter are two-dimensional materials, such as graphene and carbon nanotubes, and their composites. Their performance towards remediating monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) was explored using recent published results between 2007 and 2022 from reputable sources. The concluding section of the chapter presents recommendations for bridging knowledge gaps, as well as suggestions for future research direction.
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References
Honda, M., Suzuki, N.: Toxicities of polycyclic aromatic hydrocarbons for aquatic animals. Int. J. Environ. Res. Public Health 17(4), 1363 (2020)
Furukawa, S., et al.: Double aromaticity arising from σ- and π-rings. Commun. Chem. 1(1), 60 (2018)
Ololade, I.A., et al.: Bioavailability of polycyclic aromatic hydrocarbons (PAHs) and Environmental Risk (ER) Assessment: the case of the Ogbese river, Nigeria. Reg. Stud. Mar. Sci. 9, 9–16 (2017)
Adeola, A.O., Forbes, P.B.C.: Antiretroviral drugs in african surface waters: prevalence, analysis, and potential remediation. Environ. Toxicol. Chem. 42(2), 247–262 (2021)
Adeola, A.O., et al.: Facile synthesis of graphene wool doped with oleylamine-capped silver nanoparticles (GW-αAgNPs) for water treatment applications. Appl. Water Sci. 11(11), 172 (2021)
Adeola, A.O., Forbes, P.B.C.: Advances in water treatment technologies for removal of polycyclic aromatic hydrocarbons: existing concepts, emerging trends, and future prospects. Water Environ. Res. 93(3), 343–395 (2021)
Adeola, A.O., de Lange, J., Forbes, P.B.C.: Adsorption of antiretroviral drugs, efavirenz and nevirapine from aqueous solution by graphene wool: kinetic, equilibrium, thermodynamic and computational studies. Appl. Surf. Sci. Adv. 6, 100157 (2021)
Adeola, A.O., Forbes, P.B.C.: Assessment of reusable graphene wool adsorbent for the simultaneous removal of selected 2–6 ringed polycyclic aromatic hydrocarbons from aqueous solution. Environ. Technol. 43(8), 1255–1268 (2022)
Pathak, S., et al.: A state-of-the-art review of various adsorption media employed for the removal of toxic Polycyclic aromatic hydrocarbons (PAHs): An approach towards a cleaner environment. J. Water Proc. Eng. 47, 102674 (2022)
Ilyas, M., Ahmad, W., Khan, H.: Utilization of activated carbon derived from waste plastic for decontamination of polycyclic aromatic hydrocarbons laden wastewater. Water Sci. Technol. 84(3), 609–631 (2021)
Sabzehmeidani, M.M., et al.: Carbon based materials: a review of adsorbents for inorganic and organic compounds. Mater. Adv. 2(2), 598–627 (2021)
Rehman, A., et al.: Current progress on the surface chemical modification of carbonaceous materials. Coatings 9, 103 (2019)
Adeola, A.O., Forbes, P.B.C.: Influence of natural organic matter fractions on PAH sorption by stream sediments and a synthetic graphene wool adsorbent. Environ. Technol. Innov. 21, 101202 (2021)
Ololade, I.A., et al.: In-situ modification of soil organic matter towards adsorption and desorption of phenol and its chlorinated derivatives. J. Environ. Chem. Eng. 6(2), 3485–3494 (2018)
Adeola, A.O., Forbes, P.B.C.: Optimization of the sorption of selected polycyclic aromatic hydrocarbons by regenerable graphene wool. Water Sci. Technol. 80(10), 1931–1943 (2018)
Astrahan, P.: Monocyclic aromatic hydrocarbons (phthalates and BTEX) and aliphatic components in the SE Mediterranean costal Sea-surface microlayer (SML): Origins and phase distribution analysis. Mar. Chem. 205, 56–69 (2018)
USEPA.: U.S. Environmental Protection Agency Office of the Science Advisor Risk Assessment Forum. Framework for Human Health Risk Assessment to Inform Decision Making, April 5, 2012 (2014)
Abdel-Shafy, H.I., Mansour, M.S.M.: A review on polycyclic aromatic hydrocarbons: source, environmental impact, effect on human health and remediation. Egypt. J. Pet. 25(1), 107–123 (2016)
Maletic, S.P., et al.: State of the art and future challenges for polycyclic aromatic hydrocarbons is sediments: sources, fate, bioavailability and remediation techniques. J. Hazard. Mater. 365, 67–482 (2019)
Ali, I., et al.: Graphene based adsorbents for remediation of noxious pollutants from wastewater. Environ. Int. 127, 160–180 (2019)
Schoonraad, G., et al.: Synthesis and optimisation of a novel graphene wool material by atmospheric pressure chemical vapour deposition. J. Mater. Sci. 55, 545–564 (2020)
Kubheka, G., Adeola, A.O., Forbes, P.B.C.: Hexadecylamine functionalised graphene quantum dots as suitable nano-adsorbents for phenanthrene removal from aqueous solution. RSC Adv. 12(37), 23922–23936 (2022)
Song, T., Tian, W., Qiao, K., Zhao, J., Chu, M., Du, Z., et al.: Adsorption behaviors of polycyclic aromatic hydrocarbons and oxygen derivatives in wastewater on N-doped reduced graphene oxide. Sep. Purif. Technol. 254, 117565 (2021)
Rowley-Neale, S.J., et al.: An overview of recent applications of reduced graphene oxide as a basis of electroanalytical sensing platforms. Appl. Mater. Today 10, 218–226 (2018)
Lamichhane, S., Bal Krishna, K.C., Sarukkalige, R.: Polycyclic aromatic hydrocarbons (PAHs) removal by sorption: a review. Chemosphere 148, 336–353 (2016)
Wu, T., et al.: Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions. Chem. Eng. J. 173(1), 144–149 (2011)
Zhou, P.P., Zhang, R.Q.: Physisorption of benzene derivatives on graphene: critical roles of steric and stereoelectronic effects of the substituent. Phys. Chem. Chem. Phys. 17(18), 12185–12193 (2015)
Pourmand, S., Abdouss, M., Rashidi, A.M.: Preparation of nanoporous graphene via nanoporous zinc oxide and its application as a nanoadsorbent for benzene, toluene and xylenes removal. Int. J. Environ. Res. 9(4), 1269–1276 (2015)
Azizi, A., et al.: Adsorption performance of modified graphene oxide nanoparticles for the removal of toluene, ethylbenzene, and xylenes from aqueous solution. Desalin. Water Treat. 57(59), 28806–28821 (2016)
Ji, L., et al.: Graphene nanosheets and graphite oxide as promising adsorbents for removal of organic contaminants from aqueous solution. J. Environ. Qual. 42(1), 191–198 (2013)
Apul, O.G., et al.: Adsorption of aromatic organic contaminants by graphene nanosheets: comparison with carbon nanotubes and activated carbon. Water Res. 47(4), 1648–1654 (2013)
Sun, Y., et al.: Adsorption of polycyclic aromatic hydrocarbons on graphene oxides and reduced graphene oxides. Chem. Asian J. 8(11), 2755–2761 (2013)
Yang, X., Li, J., et al.: Adsorption of naphthalene and its derivatives on magnetic graphene composites and the mechanism investigation. Colloids Surf. A Physicochem. Eng. Asp. 422, 118–125 (2013)
Zhang, C., et al.: Adsorption of polycyclic aromatic hydrocarbons (Fluoranthene and Anthracenemethanol) by functional graphene oxide and removal by pH and temperature-sensitive coagulation. ACS Appl. Mater. Interf. 5(11), 4783–4790 (2013)
Wang, J., Chen, Z., Chen, B.: Adsorption of polycyclic aromatic hydrocarbons by graphene and graphene oxide nanosheets. Environ. Sci. Technol. 48(9), 4817–4825 (2014)
Zhao, J., et al.: Adsorption of phenanthrene on multilayer graphene as affected by surfactant and exfoliation. Environ. Sci. Technol. 48(1), 331–339 (2014)
Yang, K., Chen, B., Zhu, L.: Graphene-coated materials using silica particles as a framework for highly efficient removal of aromatic pollutants in water. Sci. Rep. 5, 11641 (2015)
Yang, X., et al.: Graphene oxide-iron oxide and reduced graphene oxide-iron oxide hybrid materials for the removal of organic and inorganic pollutants. RSC Adv. 2(23), 8821–8826 (2012)
Xu, L., et al.: Efficient synthesis of high quality double walled carbon nanotubes and their cost-effective properties. New J. Chem. 46(39), 18724–18731 (2022)
Tilmaciu, C.M., Morris, M.C.: Carbon nanotube biosensors. Front. Chem. 3, 59 (2015)
Golnabi, H.: Carbon nanotube research developments in terms of published papers and patents, synthesis and production. Sci. Iran. 19(6), 2012–2022 (2012)
Poudel, Y.R., Li, W.: Synthesis, properties, and applications of carbon nanotubes filled with foreign materials: a review. Mater. Today Phys. 7, 7–34 (2018)
Lu, C., Su, F., Hu, S.: Surface modification of carbon nanotubes for enhancing BTEX adsorption from aqueous solutions. Appl. Surf. Sci. 254(21), 7035–7041 (2008)
Abedi, Z., et al.: The effect of natural organic compounds on the adsorption of toluene and ethylene benzene on MWCNT. J. Environ. Health Sci. Eng. 17(2), 1055–1065 (2019)
Chen, W., Duan, L., Zhu, D.: Adsorption of polar and nonpolar organic chemicals to carbon nanotubes. Environ. Sci. Technol. 41(24), 8295–8300 (2007)
Wibowo, N., et al.: Adsorption of benzene and toluene from aqueous solutions onto activated carbon and its acid and heat treated forms: Influence of surface chemistry on adsorption. J. Hazard. Mater. 146(1), 237–242 (2007)
Chin, C.J.M., et al.: Adsorption of o-xylene and p-xylene from water by SWCNTs. Carbon 45(6), 1254–1260 (2007)
Yu, F., et al.: Magnetic iron oxide nanoparticles functionalized multi-walled carbon nanotubes for toluene, ethylbenzene and xylene removal from aqueous solution. Chemosphere 146, 162–172 (2016)
Anjum, H., et al.: Investigation of green functionalization of multiwall carbon nanotubes and its application in adsorption of benzene, toluene & p-xylene from aqueous solution. J. Clean. Prod. 221, 323–338 (2019)
Alves, D.C.D.S., et al.: Chapter 18—carbon nanotube-based materials for environmental remediation processes. In: Giannakoudakis, D., Meili, L., Anastopoulos, I. (eds.) Advanced Materials for Sustainable Environmental Remediation. Elsevier, pp. 475–513 (2022)
Agasti, N., et al.: Carbon nanotube based magnetic composites for decontamination of organic chemical pollutants in water: a review. Appl. Surf. Sci. Adv. 10, 100270 (2022)
Yahyazadeh, A., Khoshandam, B.: Carbon nanotube synthesis via the catalytic chemical vapor deposition of methane in the presence of iron, molybdenum, and iron–molybdenum alloy thin layer catalysts. Results Phys. 7, 3826–3837 (2017)
Mahgoub, H.A.: Nanoparticles used for extraction of polycyclic aromatic hydrocarbons. J. Chem. 2019(4), 816–849 (2019)
Menezes, H.C., et al.: Magnetic N-doped carbon nanotubes: a versatile and efficient material for the determination of polycyclic aromatic hydrocarbons in environmental water samples. Anal. Chim. Acta 873, 51–56 (2015)
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Adeola, A.O., Forbes, P.B.C. (2024). Two-Dimensional Carbon-Based Materials for Sorption of Selected Aromatic Compounds in Water. In: Tharini, J., Thomas, S. (eds) Carbon Nanomaterials and their Composites as Adsorbents. Carbon Nanostructures. Springer, Cham. https://doi.org/10.1007/978-3-031-48719-4_14
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DOI: https://doi.org/10.1007/978-3-031-48719-4_14
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