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Ultrasonic Synthesis and Characterization of Zinc Pyrovanadate Nanostructures

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Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 279))

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Abstract

The unique low temperature synthesis of zinc pyrovanadate from oxides was proposed. Zn3V2O7(OH)2·2(H2O) was synthesized by ultrasonic (US) method using ZnO and V2O5 as raw materials. It was established using SEM and TEM methods that Zn3V2O7(OH)2·2(H2O) has the structure of nanosheets. The DTA method and XRD analysis showed the formation of the Zn3V2O8 phase after the removal of crystallization water from Zn3V2O7(OH)2·2(H2O). Ultrasonic treatment of oxides as initial reagents allows obtaining Zn3V2O8 with the specific surface area of 14 m2/g. For comparison, Zn3V2O8 was synthesized by solid-state (SS) synthesis from oxides. The properties of zinc pyrovanadate obtained by US synthesis and conventional SS synthesis were compared. The advantages of US method over conventional SS synthesis were noted.

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Acknowledgements

This work was financially supported by NASU Program “New functional substances and materials of chemical production” (project 13-21).

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, General Naumov Street, 13, Kyiv, 03164, Ukraine

    O. A. Diyuk, Valery Zazhigalov, L. S. Kuznetsova & M. M. Tsyba

  2. L.V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Pr. Nauky, Kyiv, 03028, Ukraine

    N. D. Shcherban

  3. Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, Kyiv, 01033, Ukraine

    N. V. Diyuk

  4. Institute of Geological Sciences, National Academy of Sciences of Ukraine, 55-B O.Gonchar Str., Kyiv, 01054, Ukraine

    V. V. Permyakov

  5. M.G. Kholodny Institute of Botany, National Academy of Sciences of Ukraine, Tereshchenkivska Str., 2, Kyiv, 01004, Ukraine

    S. M. Shcherbakov

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  1. O. A. Diyuk
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  2. Valery Zazhigalov
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  4. N. V. Diyuk
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  6. S. M. Shcherbakov
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  7. L. S. Kuznetsova
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Correspondence to O. A. Diyuk .

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Editors and Affiliations

  1. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Olena Fesenko

  2. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid Yatsenko

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Diyuk, O.A. et al. (2023). Ultrasonic Synthesis and Characterization of Zinc Pyrovanadate Nanostructures. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 279. Springer, Cham. https://doi.org/10.1007/978-3-031-18096-5_16

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