Abstract
This book chapter addresses the recent advances in the supramolecular electrochemistry approach concerning investigation of electrochemical phenomena on nanoscale of self-assembled nanomaterials formed from individual components known as molecular building blocks, such as, semiconductive oxides, coordination compounds, metallic nanoparticles, biomolecules, and carbon-based materials. These individual lower-level components carry in their structures information that can be combined through self-assembly, self-recognition, dynamic nature, and self-organization processes in order to design new functional hybrid nanoarchitectures, nanocomposites, self-assembled monolayers, and 2-D multilayer assemblies. Generally, the self-assembled nanostructures exhibit high stability, chemical reactivity, and desirable targeting properties. We highlight the successful use of supramolecular electrochemistry strategy to understand the thermodynamics and kinetics proprieties developed by smart self-assembled nanomaterials used for construction of sensor, biosensor, electronic device, energy storage, and electrochemical device.
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The financial support from CAPES and CNPq (436086/2018-2 and 314456/2020-1 projects) is gratefully acknowledged.
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Soares, A.M.B.F., Carvalho, C.L.C., de Andrade Rodrigues, G., Luz, R.A.S., Gerôncio, E.T.S., Cantanhêde, W. (2022). Supramolecular Electrochemistry: Recent Trends and Perspectives. In: Crespilho, F.N. (eds) Advances in Bioelectrochemistry Volume 1. Springer, Cham. https://doi.org/10.1007/978-3-030-94988-4_6
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