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Surface Reactivity of Carbon Nanoporous Materials Studied with Chemical Bromination

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Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications (NANO 2020)

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Abstract

An electrophilic bromination is used as a probe reaction to assess the reactivity of a carbon surface, as well as to prepare versatile precursors for multifunctional modifications. In this chapter, we consider the bromination of nanoporous carbon materials with liquid bromine and KBr3. This bromination was performed under different reaction protocols. Here, we report the parallel oxidation and hydrolysis during bromination and show their effect on surface chemistry. Also, the pros and cons of the usage of the proposed reaction  are considered.  The surface oxidation and modification rules are discussed, and the amount of introduced bromine that can be substituted by a nucleophile is presented. In general, the potential for obtaining chemically uniform surfaces covered with amino groups by amination of the surface of brominated carbon materials has been shown.

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Acknowledgements

This work was funded by grants from the Ministry of Education and Science of Ukraine ([0111U006260], [0114U003554], and [0116U002558]).

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Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, Kyiv, 01601, Ukraine

    V. E. Diyuk, A. N. Zaderko, L. M. Grishchenko, A. V. Vakaliuk & V. V. Lisnyak

  2. Faculty of Humanities and Natural Sciences, University of Prešov, Prešov, Slovakia

    R. Mariychuk & V. V. Lisnyak

Authors
  1. V. E. Diyuk
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  2. A. N. Zaderko
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  3. L. M. Grishchenko
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  4. A. V. Vakaliuk
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  5. R. Mariychuk
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  6. V. V. Lisnyak
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Correspondence to V. V. Lisnyak .

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Editors and Affiliations

  1. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Olena Fesenko

  2. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid Yatsenko

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Diyuk, V.E., Zaderko, A.N., Grishchenko, L.M., Vakaliuk, A.V., Mariychuk, R., Lisnyak, V.V. (2021). Surface Reactivity of Carbon Nanoporous Materials Studied with Chemical Bromination. In: Fesenko, O., Yatsenko, L. (eds) Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications . NANO 2020. Springer Proceedings in Physics, vol 264. Springer, Cham. https://doi.org/10.1007/978-3-030-74800-5_12

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