Abstract
Today, technetium is continuously released into the natural environment as a result of human activity in the fields of the nuclear industry and the nuclear medicine.
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References
Abuzwida MA (1996) Anodic stripping voltammetry of technetium alkaline media. In: Third Arab conference on the peaceful uses of atomic energy. Damascus 9–13 Dec 1996, AAEA. https://inis.iaea.org/collection/NCLCollectionStore/_Public/31/065/31065341.pdf. Accessed 15 May 2019
Astheimer L, Schwochau K (1967) Zur invers-polarographie des technetiums. J Electroanal Chem 14:240–241
Chatterjee S, Del Negro A, Edwards MK et al (2011) Luminescence-based spectroelectrochemical sensor for [Tc(dmpe)3]2+/+ (dmpe = 1,2-bis(dimethylphosphino)ethane) within a charge-selective polymer film. Anal Chem 83:1766–1772
Chotkowski M, Wrzosek B, Grden M (2018) Intermediate oxidation states of technetium in concentrated sulfuric acid solutions. J Electroanal Chem 814:83–90
Desmet K, Myttenaere K (1986) Technetium in the environment. Elsevier
El-Reefy SA, Ruf H, Schrob K (1990) Catodic stripping voltammetry in the tethaphenylarsonium chloride/chloroform extract at a hanging mercury drop electrode. J Radioanal Nucl Chem 141(1):179–183
Friedrich M, Ruf H (1986) Assay of extremely low technetium concentration by adsorption strpping voltammetry at the HMDE after reaction with thiocyanate. J Electroanal Chem 198:261–268
German KE, Dorokhov AV, Kopytin AV et al (2005) Quaternary alkylammonium and alkylphosphonium pertechnetates: application to pertechnetate ion-selective electrodes. J Nucl Radiochem Sci 6(3):217–219
Guminski C, Galus Z (1986) Radioactive elements. In: Hirayama C, Galus Z, Guminski C (eds) Metals in mercury, IUPAC solubility data series, vol 25. Pergamon Press, p 421
Herlem G, Angoue O, Gharbi T et al (2015) Electrochemistry of pertechnetate on ultramicroelectrode: a new quality control for radiopharmaceuticals manufactured at hospitals in nuclear medicine. Electrochem Comm 51:76–80
Jasim F, Magee RJ, Wilson CL (1960) Chemical analysis on the microgram scale VI. The ultramicrogravimetric determination of technetium and rhenium. Microchim Acta 5–6:721–728
Lewis JY, Zodda JP, Deutsch E et al (1983) Determination of pertechnetate by liquid chromatography with reductive electrochemical detection. Anal Chem 55:708–713
Lewis JY, Pinkerton TC, Deutsch E et al (1985) Stripping chronocoulometry for the determination of pertechnetate. Anal Chim Acta 167:335–342
Rimke H, Herrmann G, Mang M et al (1990) Principle and analytical applications of resonance ionization mass spectrometry. Microchim Acta III:223–230
Ruf H (1988) Quantitative analytical assay of small amounts of technetium by stripping chronopotentiometry at a glassy carbon electrode. J Electroanal Chem 241:125–131
Shi K, Hou X, Roos P et al (2012) Determination of technetium-99 in environmental samples: a review. Anal Chim Acta 709:1–20
Takahashi Y (2017) Technetium. In: White WM (ed) Encyclopedia of geochemistry. Springer, p 1422
Torres Llosa JM, Ruf H, Schorb K et al (1988a) Stripping voltammetric determination of traces of technetium with glassy carbon electrode coated with tri-n-octylphosphine oxide. Anal Chim Acta 211:317–323
Torres Llosa JM, Ruf H, Schorb K et al (1988b) Stripping voltammetry assay of trace technetium with a TOPO coated glassy carbon electrode. J Res Nation Bureau Stand 93(3):493–495
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Chotkowski, M., Czerwiński, A. (2021). Determination of Trace Amounts of Tc by Electrochemical Methods. In: Electrochemistry of Technetium. Monographs in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-030-62863-5_6
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