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Fractional Solidification for Purification of Recycled Aluminium Alloys

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Light Metals 2020

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

Recycling Al is an up-to-date topic nowadays due to the economic benefits and sustainability , in fact recycling Al employs only 5% of the energy necessary for its extraction from bauxite ore, saving 9 ton of CO2 per 1 tonne of Al recycled. In this research project the principles of fractional solidification have been applied to reduce the amount of impurities in model recycled Al alloys. A set-up based on isothermal squeezing of a semi-solid alloy has been developed and tested. The ultrasonic vibration applied to the semi-solid material has proven to enhance the purification achievable, up to 65% of reduction in the concentration. A number of potential impurities, such as Si, Ni, Cu, have been tested. The role of solute partitioning during the process has been evaluated and characterised by optical microscopy and modelling.

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References

  1. Green JAS, (2007) Aluminum recycling and processing for energy conservation and sustainability. Materials Park, OH: ASM International

    Google Scholar 

  2. Capuzzi S, Timelli G, (2018) Preparation and melting of scrap in Aluminium Recycling: A review. Metals, 8, 249:1–25

    Google Scholar 

  3. Calliauw G, Frederick E, Gibon V, Greyt VD, Wounters J, Foubert I, Dewettinck K, (2010) On the fractional crystallization of palm olein: solid solutions and eutectic solidification. Food Research International, 43:972–981

    Google Scholar 

  4. Garcia-Arias M, Stevensen G, (2017) Phase equilibrium modelling of granite magma petrogenesis: B. An evaluation of the magma compositions that result from fractional crystallization. Lithos, 277:109–130

    Google Scholar 

  5. Sillikens W.H et al., (1998) Refining Aluminium Scrap by means of Fractional Crystallization: Technical Feasibility. Paper presented at Fourth ASM international Conference and Exhibition on the Recycling of Metals, ASM Vienna, Austria, 1998

    Google Scholar 

  6. Pattinson (1833) Separating silver from lead. British Patent 6497 23 November 1833

    Google Scholar 

  7. Pfann WG (1957) Zone Melting, Metallurgical Reviews, 2(1):29–76

    Google Scholar 

  8. Lux AL, Flemings MC, (1979) Refining by Fractional Melting. Metall. Trans. B 10B:79–83

    Google Scholar 

  9. Lux AL, Flemings MC, (1979) Refining by Fractional Solidification. Metall Trans. B 10B:71–78

    Google Scholar 

  10. Ali AT, Stubina NM, Toguri JM, (1989) Silicon Removal from Cast Aluminum Scrap Using an Isothermal Compression Technique Resources. Conservation and Recycling, 2:87–98

    Google Scholar 

  11. Sotome T, Ohtaki M (1998) Application of fractional crystallization for refining of molten aluminium scrap. Paper presented at International Conference Aluminium Alloys Aluminium alloys, Toyohashi, Japan, 1998

    Google Scholar 

  12. Ichikawa K, Katoh M, Asuke F, Nakazawa Y, (1997) High Efficient Recovery of Pure Aluminium from Al-Sn and Al-Ni Alloys by Rheorefining Process. Materials Transactions. 38(7):622–629

    Google Scholar 

  13. Eskin GI. (1998) Ultrasonic Treatment of Light Alloy Melts, Gordon and Breach Science Publishers, Amsterdam

    Google Scholar 

  14. Bernard D, Nielsen O, Salvo L, Cloetens P, (2005) Permeability assessment by 3D interdendritic flow simulations on microtomography mappings of Al–Cu alloys. Mater. Sci. Eng. A 32:112–120

    Google Scholar 

  15. Voller VR, Beckerman C, (1999) A unified model of microsegregation and coarsening. Metall. Mater. Trans. A 30A:2183–2189

    Google Scholar 

Download references

Acknowledgements

This work is part of an Industrial Case Ph.D. project jointly funded by Engineering and Physical Sciences Research Council of UK (voucher no 16000068) and Jaguar Land Rover.

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Correspondence to Susanna Venditti .

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Venditti, S., Eskin, D., Jacot, A. (2020). Fractional Solidification for Purification of Recycled Aluminium Alloys. In: Tomsett, A. (eds) Light Metals 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36408-3_150

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