Abstract
The properties of metals and alloys are dependent on their atomic structure. Metals are an aggregation of atoms that, apart from mercury, are solid at room temperature. These atoms are held together by “metallic bonds” that result from sharing available electrons. A negative electron bond pervades the structure, and heat and electricity can be conducted through the metal by the free movement of electrons. The atoms are regularly arranged, forming a symmetrical three-dimensional group, which repeats itself periodically and which is called a unit cell. Unit cells of identical characteristics form a crystal with regular spatial distribution of atoms, which can be defined by a space lattice. Atoms can be stacked in different ways to create a variety of simple lattice types. There are three common types of lattice structure that most metals belong to (Fig. 4.1): face-centred cubic (fcc), body-centred cubic (bcc) and close-packed hexagonal (cph).
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References
Bachmann, H.-G.: The Identification of Slags from Archaeological Sites Institute of Archaeology Occasional Publication No. 6. Institute of Archaeology, London (1982)
Bhadeshia, H.K.D.H.: Bainite in Steels, 2nd edn. IOM Communications Ltd, London (2001)
Bhadeshia: Physical metallurgy of steels. In: Laughlin, D., Hono, K. (eds.) Physical Metallurgy III, 5th edn, pp. 2157–2214. Elsevier, Amsterdam et al. (2014)
Barrena, M.I., Gómez de Salazar, J.M., Soria, S.A.: Corrosion of brass archaeological blinker: characterisation of natural degradation process. Mater. Lett. 62(24), 3944–3946 (2008)
Barrett, C.S., Massalski, T.B.: Structure of Metals: Crystallographic Methods, Principles and Data, International Series on Materials Science and Technology 35, 3rd rev edn. Pergamon, Oxford/New York/Seoul/Tokyo (1993)
Biborski, M., Kaczanowski, P., Kedzierski, Z., Stepinski, J.: Ergebnisse der metallographischen Untersuchungen römischen Schwertern aus dem Vindonissa-Museum Brugg und dem Römermuseum Augst, Jahresbericht 1985 der Gesellschaft Pro Vindonissa, pp. 45–80 (1985)
Breeks, J.W.: An Account of the Primitive Tribes and Monuments of the Nilagiris. Allen, London (1873)
Brüggler, M., Dirsch, C., Drechsler, M., Schwab, R., Willer, F.: Ein römischer Schienenarmschutz aus dem Auxiliarlager Till-Steincheshof und die Messingherstellung in der römischen Kaiserzeit. Bonner Jahrbücher. 212, 121–152 (2012)
Buchwald, V.F.: Handbook of Iron Meteorites 1–3. University of California Press, Berkeley (1975)
Buchwald, V.F.: Ancient Iron and Slags in Greenland. Meddelelser om Grønland, Man & Society 26. Danish Polar Center, Copenhagen (2001)
Buchwald, V.F.: Iron and Steel in Ancient Times. Historisk-filosofiske Skrifter 29. Det Kongelige Danske Videnskabernes Selskab, Copenhagen (2005)
Buchwald, V.F.: Iron, Steel and Cast Iron before Bessemer. Historisk-filosofiske Skrifter 32. Det Kongelige Danske Videnskabernes Selskab, Copenhagen (2008)
Buchwald, V.F., Wivel, H.: Slag analysis as a method for characterization and provenancing of iron objects. Mater. Charact. 40, 73–96 (1998)
Budd, P.: Alloying and metalworking in the Copper Age of Central Europe. Bull. Met. Mus. 17, 3–14 (1992)
Cellini, B.: The Treatises of Benvenuto Cellini on Goldsmithing and Sculpture. Trans. C.R. Ashbee, Dover, New York (1967)
Chadwick, R.: The effect of composition and constitution on the working and some physical properties of the tin bronzes. J. Inst. Met. 64, 331–346 (1939)
Chang, Y.A., Neumann, J.P., Mikula, A., Goldberg, D.: Phase Diagrams and Thermodynamic Properties of Ternary Copper-Metal Systems. International Copper Research Association Series on the Metallurgy of Copper 6. NSRD, Washington, DC (1979)
Cope, L.H.: The metallurgical analysis of Roman Imperial silver and aes coinage. In: Hall, E.T., Metcalf, D.M. (eds.) Methods of Chemical and Metallurgical Investigation of Ancient Coinage Royal Numismatic Society Special Publication 8, pp. 3–47. Royal Numismatic Society, London (1972)
Coustures, M.P., Béziat, D., Tollon, F., Domergue, C., Long, L., Rebiscoul, A.: The use of trace element analysis of entrapped slag inclusions to establish ore – bar iron links: examples from two Gallo-Roman iron-making sites in France (Les Martys, Montagne noire, and les Ferrys, Loiret). Archaeometry. 45, 599–613 (2003)
Cowley, J.M.: X-ray measurement of order in single crystals of Cu3Au. J. Appl. Phys. 21(1), 24–30 (1950)
Craddock, P.T.: Early metal mining and production. Edinburgh University Press, Edinburgh (1995)
Craddock, P.T., Meeks, N.D.: Iron in ancient copper. Archaeometry. 29(2), 187–204 (1987)
Davenport, E.S., Bain, E.C.: Transformation of austenite at constant subcritical temperatures. Trans. Am. Inst. Min. Metall. Eng. 90, 117–144 (1930)
Davis, J.R. (ed.): ASM Specialty Handbook: Copper and Copper Alloys. ASM International, Materials Park (2008)
Dieudonné-Glad, N., Parisot, J.: Etude métallographique d‘épées celtiques et romaines du musée Denon à Châlon-sur-Saône. In: Nicolini, G., Dieudonne-Glad, N. (eds.) Les métaux antiques: travail et restauration. Monographies Instrumentum 6, pp. 153–163. Monique Mergoil, Montagnac (1998)
Dillmann, P., L’Héritier, M.: Slag inclusion analyses for studying ferrous alloys employed in French medieval buildings: supply of materials and diffusion of smelting processes. J. Archaeol. Sci. 34, 1810–1823 (2007)
Dillmann, P., Schwab, R., Bauvais, S., Brauns, M., Disser, A., Leroy, S., Gassmann, G., Fluzin, P.: Circulation of iron products in the North-Alpine area during the end of the First Iron Age (6th–5th c. BC): a combination of chemical and isotopic approaches. J. Archaeol. Sci. 87, 108–124 (2017)
Dövener, F., Schwab, R., Willer, F.: Kleine Zeugnisse einstiger Größe – Vier Bronzestatuen-Fragmente aus Luxemburg. Archaeologia Luxemburgensis. 4, 141–160 (2018)
Dungworth, D.: Serendipity in the foundry? Tin oxide inclusions in copper and copper alloys as an indicator of production process. Bull. Met. Mus. 32, 1–5 (2000)
English, A.T., Chin, G.Y., Wonsiewicz, B.C.: Structures resulting from plastic deformation. In: Lyman, T. (ed.) Metallography, Structures and Phase Diagrams ASM Handbook 8, pp. 211–216. American Society for Metals, Metals Park (1973)
Glover, I., Bennett, A.: The high-tin bronzes of Thailand. In: Jett, P. (ed.) Scientific Research on Ancient Asian Metallurgy: Proceedings of the Fifth Forbes Symposium at the Freer Gallery of Art, pp. 101–114. Archetype, London (2012)
Goodway, M., Conklin, H.C.: Quenched high-tin bronzes from the Philippines. Archeomaterials. 2, 1–27 (1987)
Graf, L.: The causes and mechanism of stress-corrosion cracking of homogeneous non-supersaturated alloys as derived from experimental work with alloys containing noble metal components. In: Scully, J.C. (ed.) The Theory of Stress-Corrosion Cracking in Alloys: Research Evaluation Conference Held at Ericeira, Portugal over the Period 29 March to 2 April 1971, pp. 399–341. NATO Scientific Affairs Division, Brussels (1971)
Hanson, D., Pell-Walpole, W.T.: Chill-Cast Tin Bronzes. Edward Arnold, London (1951)
Hansen, M., Anderko, K.: Constitution of Binary Alloys. McGraw-Hill, New York/Toronto/London (1958)
Hansen, N., Barlow, C.Y.: Plastic deformation of metals and alloys. In: Laughlin, D.E., Hono, K. (eds.) Physical Metallurgy II, 5th edn, pp. 1681–1764. Elsevier, Amsterdam et al. (2014)
Hauptmann, A., Maddin, R., Prange, M.: On the structure and composition of copper and tin ingots excavated from the shipwreck of Uluburun. Bull. Am. Sch. Orient. Res. 328, 1–30 (2002)
Horstmann, D.: Metallkundliche Untersuchungen an Klingen von zwei römischen Dolchen Ausgrabungen und Funde in Westfalen-Lippe 9/B, pp. 111–135 (1995)
Hillert, M. (ed.): Viewpoint set No. 25 “bainite”. Scr. Mater. 47, 137–212 (2002)
Hultgren, R., Tarnapol, L.: The effect of silver on the gold-copper superlattice Au-Cu. Trans. Am. Inst. Min. Metall. Eng. 33, 228–237 (1939)
Hume-Rothery, W., Raynor, G.V.: The Structure of Metals and Alloys. Institute of Metals Monograph and Report Series 1. The Institute of Metals, London (1956)
Illescas, F.J., Asensio, J., Guilemany, J.M.: TEM study of bainitic low-carbon HSLA steel: the orientation relationships of cementite. Pract. Metall. 44(6), 334–346 (2007)
Ingo, G.M., de Caro, T., Bultrini, G.: Microchemical investigation of archaeological copper based artefacts disclosing an ancient witness of the transition from the value of the substance to the value of the appearance. Microchim. Acta. 144(1), 87–95 (2004)
Johansson, C.H., Linde, J.O.: J.O.: Röntgenographische und elektrische Untersuchungen des CuAu-Systems. Ann. Phys. 417(1), 1–48 (1936)
Juleff, J.: X-ray diffraction studies of gold. Unpublished BSc thesis, Institute of Archaeology, London (1981)
Kallfass, M., Paul, J., Jehn, H.: Investigations on the embrittlement of an antique Roman silver bowl. Practical Metallogr. 2, 317–323 (1985)
Karakaya, I., Thompson, W.T.: The Ag-Sn (silver-tin) system. Bull. Alloy Phase Diagr. 8(4), 340–347 (1987)
Kastowsky, K., Mehofer, M.: Metallographische Analysen an den kaiserzeitlichen Depots aus Mannersdorf am Leithagebirge. In: Pollak, M. (ed.) Stellmacherei und Landwirtschaft: zwei römische Materialhorte aus Mannersdorf am Leithagebirge, Niederösterreich. Fundberichte aus Österreich Materialhefte A 16, pp. 55–65. Berger, Wien (2006)
Kienlin, T.L.: Traditions and transformations: approaches to eneolithic (Copper Age) and Bronze Age metalworking and society in Eastern Central Europe and the Carpathian Basin. British Archaeological Reports International Series 2184. Archaeopress, Oxford (2010)
Kiessling, R.: Non-metallic Inclusions in Steel III: The Origin and Behaviour of Inclusions and their Influence on the Properties of Steels. Percy Lund, London (1968)
Krauss, G.: Steels: Heat Treatment and Processing Principles. ASM International, Materials Park (2000)
Kuczynski, G.C., Hochman, R.F., Doyama, M.: Isothermal transformations in CuAu. J. Appl. Phys. 26, 871–874 (1955)
Lang, J., Williams, A.R.: The hardening of iron swords. J. Archaeol. Sci. 2, 199–207 (1975)
La Niece, S.: Metallography in numismatics. In: Oddy, A., Cowell, M. (eds.) Metallurgy in Numismatics 4, Royal Numismatic Society Special Publication 30, pp. 114–133. Royal Numismatic Society, London (1998)
Lechtman, H.: Traditions and styles in central Andean metalwork. In: Maddin, R. (ed.) The Beginning of the Use of Metals and Alloys (BUMA I), pp. 344–378. MIT Press, Cambridge, MA (1988)
Lehner, J.W., Schwab, R., Pernicka, E., Schachner, A.: Cupronickel and the rise of the Hittite State: metallurgical investigations of Late Bronze Age copper alloys at Boğazköy-Hattuša (forthcoming)
Liu, K.H., Chan, H., Notis, M.R., Pigott, V.S.: Analytical electron microscopy of early steel from the Bacqah Valley, Jordan. In: Romig Jr., A.D., Goldstein, J.I. (eds.) Microbeam Analysis-1984, pp. 261–263. San Francisco Press, San Francisco (1984)
Lutz, J., Schwab, R.: The Early Iron Age hoard from Fliess in Tyrol and ore resources in the Eastern Alps. In: Pernicka, E., Schwab, R. (eds.) Under the Volcano. Forschungen zur Archäometrie und Altertumswissenschaft 5, pp. 25–34. M. Leidorf, Rahden/Westf (2014)
Lychatz, B.: Die Metallurgie des Rennverfahrens. Freiberger Forschungshefte D 245. Technische Universität Bergakademie Freiberg, Freiberg (2013)
Maddin, R.: A history of martensite: some thoughts on the early hardening of iron. In: Olson, G.B., Owen, W.S. (eds.) Martensite: A Tribute to Morris Cohen, pp. 11–19. ASM International, Materials Park (1992)
Maddin, R., Hauptmann, A., Baatz, D.: A metallographic examination of some iron tools from the Saalburgmuseum. Saalburg Jahrbuch. 46, 5–23 (1991)
Marshall, J.: Taxila: An Illustrated Account of Archaeological Excavations Carried Out at Taxila Under the Orders of the Government of India Between the Years 1913 and 1934, vol. 1–3. Cambridge University Press, Cambridge (1951)
Massalski, T.B. (ed.): Binary alloy phase diagrams 1–2, Ohio. American Society of Metals, Materials Park (1986)
Matteoli, L., Storti, C.: Metallographic research on four pure copper axes and one related metallic block from Eneolithic Italian cave. J. Hist. Metall. Soc. 16(2), 65–69 (1982)
Meeks, N.D., Tite, M.S.: The analysis of platinum-group element inclusions in gold antiquities. J. Archaeol. Sci. 7(3), 267–275 (1980)
McDonald, A.S., Sistare, G.H.: The metallurgy of some carat gold jewellery alloys. Part I – coloured gold alloys. Gold Bull. 11, 66–73 (1978)
McMullin, J.F., Norton, J.T.: On the structure of gold-silver-copper alloys. Trans. Am. Inst. Min. Metall. Eng. 33, 228–237 (1949)
Marshall, J.: Taxila, 3 vols. Cambridge University Press, Cambridge (1951)
Masing, G., Kloiber, K.: Ausscheidungsvorgänge im System Kupfer-Silber-Gold. Z. Met. 32, 125–132 (1940)
Melikian-Chirvani, A.S.: The white bronzes of early Islamic Iran. Metrop. Mus. J. 9, 123–151 (1974)
Michalak, J.T.: Plastic deformation structures in iron and steel. In: Lyman, T. (ed.) Metallography, Structures and Phase Diagrams ASM Handbook 8, pp. 218–220. American Society for Metals, Metals Park (1973)
Mizutani, U., et al.: Electron theory of complex metallic alloys. In: Laughlin, D.E., Hono, K. (eds.) Physical Metallurgy I, 5th edn, pp. 103–202. Elsevier, Amsterdam et al (2014)
Northover, J.P.: The exploration of long-distance movement of bronze in Bronze and early Iron Age Europe. Bull. Inst. Archaeol. Univ. Lond. 19, 45–72 (1982)
Northover, J.P.: Exotic alloys in antiquity. In: Rehren, T., Hauptmann, A., Muhly, J.D. (eds.) Metallurgica Antiqua. In Honour of Hans-Gert Bachmann and Robert Maddin. Der Anschnitt Beiheft 8, pp. 113–121. Deutsches Bergbau-Museum, Bochum (1998)
Northover, P.: Copper in the Industrial Age. In: Degrigny, C., van Langh, R., Joosten, I., Ankersmit, B. (eds.) METAL 07, vol. 1, pp. 83–90. Elsevier, Amsterdam (2007)
Notis, M.R., Shugar, A.N.: Roman shears: metallography, composition and historical approach to investigation. In: Archaeometallurgy in Europe 1, pp. 109–118. AIM, Milan (2003)
Odgen, J.: The technology of Medieval jewellery. In: Scott, D.A., Podany, J., Considine, B.B. (eds.) Ancient & Historic Metals – Conservation and Scientific Research, pp. 153–182. National Museum of Singapore, Singapore (1994)
Park, J.S., Park, C.W., Lee, K.J.: Implication of peritectic composition in historical high-tin bronze metallurgy. Mater. Charact. 60(11), 1268–1275 (2009)
Pleiner, R.: Zur Schmiedetechnik im römerzeitlichen Bayern. Bayerische Vorgeschichtsblätter. 35, 113–140 (1970)
Pleiner, R.: The Celtic Sword. Clarendon Press, Oxford (1993)
Pleiner, R.: Iron in Archaeology: The European Bloomery Smelters. Archeologicky Ústav Avcr, Praha (2000)
Pleiner, R.: Iron in Archaeology: Early European Blacksmiths. Archeologicky Ústav Avcr, Praha (2006)
Pliny the Elder: Natural History, 10 vols, trans. H. Rackham. Harvard University Press/William Heinemann, Cambridge/Harvard/London (1979)
Pryce, O., Murillo-Barroso, M., Bellina, B., Martinón-Torres, M.: Khao Sam Kaeo – an archaeometallurgical crossroads for trans-Asiatic technological traditions. In: Srinivasan, S., Ranganathan, S., Giumlia-Mair, A. (eds.) Metals and Civilizations, Proceedings of the International Conference, Beginning of the Use of Metals and Alloys, BUMA VII, Bangalore September 2009, Bangalore, pp. 33–46 (2015)
Rajpitak, W., Seeley, N.: The bronze bowls from Ban Don Ta Phet: an enigma of prehistoric metallurgy. World Archaeol. 11(1), 26–31 (1979)
Rapson, W.S., Groenewald, T.: Gold Usage. Academic, London (1978)
Ravich, I.G.: Study of the composition of Scythian and Sarmatian bronze mirrors and technologies of their manufacture. Bull. Met. Mus. 16, 20–31 (1991)
Ravich, I.G., Ryndina, N.V.: Early copper-arsenic alloys and the problems of their use in the Bronze Age of the North Caucasus. Bull. Met. Mus. 23, 1–18 (1995)
Reeve, M.R., Bowden, J.S., Cuthbertson, J.W.: A report on the microstructure of tin bronzes containing 15–28% tin. Part One. Met. Ind. 78, 23–25 (1953)
Reeve, M.R., Bowden, J.S., Cuthbertson, J.W.: A report on the microstructure of tin bronzes containing 15-28% tin. Part Two. Met. Ind. 78, 49–52 (1953)
Rehren, T., Northover, J.P.: Selenium and tellurium in ancient copper ingots. In: Pernicka, E., Wagner, G.A. (eds.) Archaeometry ‘90, pp. 221–228. Birkhäuser, Basel/Boston/Berlin (1991)
Rhines, F.N., Bond, W.E., Rummel, R.A.: Constitution of ordering alloys of the system gold-copper. Trans. Am. Soc. Met. 47, 578–597 (1955)
Roberts-Austen, W.C., Rose, K.T.: On certain properties of the alloys of the gold-copper series. Proc. R. Soc. Lond. 67(435–441), 105–112 (1901)
Rodney, D., Bonneville, J.: Dislocations. In: Laughlin, D.E., Hono, K. (eds.) Physical Metallurgy II, 5th edn, pp. 1591–1680. Elsevier, Amsterdam et al (2014)
Root, W.C.: Gold-copper alloys in ancient America. J. Chem. Educ. 28(2), 76–78 (1951)
Rostoker, W., Bronson, B.: Pre-industrial Iron. Archeomaterials Monograph 1. Archeomaterials, Philadelphia (1990)
Samuels, L.E.: Optical Microscopy of Carbon Steels. American Society for Metals, Metals Park (1980)
Saunders, N., Miodownik, A.P.: The Cu-Sn (copper-tin) system. Bull. Alloy Phase Diagr. 11(3), 278–287 (1990)
Schaaber, O.: Beiträge zur Frage des Norischen Eisens. Metallkundliche Grundlagen und Untersuchungen an Funden vom Magdalensberg. Carinthia I, 153, pp. 129–279 (1963)
Schwab, R.: Untersuchungen zur Technologie und Herkunft eiserner Werkzeuge und Waffen. In: Sievers, S., Leicht, M., Ziegaus, B. (eds.) Ergebnisse der Ausgrabungen 1996–1999 in Manching-Altenfeld Die Ausgrabungen in Manching 18, pp. 251–293. Reichert Verlag, Wiesbaden (2013)
Scott, R.E.: New complex phase in the copper-gold system. J. Appl. Phys. 31(12), 2112–2117 (1960)
Scott, D.A.: Pre-Hispanic Colombian metallurgy: studies of some gold and platinum alloys. PhD thesis, Institute of Archaeology, University of London (1982)
Scott, D.A.: Metallography and microstructure of ancient and historic metals, Getty conservation institute, J. Paul Getty Museum, Malibu (1991)
Scott, D.A.: Ancient Metals: Microstructure and Metallurgy 1. Conservation Science Press, Los Angeles (2011)
Senn Bischofberger, M.: Das Schmiedehandwerk im nordalpinen Raum von der Eisenzeit bis ins frühe Mittelalter. Internationale Archäologie – Naturwissenschaft und Technologie 5. Verlag Marie Leidorf, Rahden (2005)
Shalev, S., Northover, J.P.: The metallurgy of the Nahal Mishmar hoard reconsidered. Archaeometry. 35(1), 35–47 (1993)
Shim, J.H., Oh, C.S., Lee, B.J., Lee, D.N.: Thermodynamic assessment of the Cu-Sn system. Z. Met. 87, 205–212 (1996)
Smith, C.S.: A History of Metallography. The University of Chicago Press, Chicago (1960)
Smith, C.S.: Bronze technology in the east: a metallurgical study of early Thai bronzes. In: Teich, M., Young, R. (eds.) Changing Perspectives in the History of Science: Essays in Honour of Joseph Needham, pp. 21–32. Heinemann, London (1973)
Smith, R., Bowles, J.S.: The crystallography of the cubic to orthorhombic transformation in the alloy AuCu. Acta Metall. 8(7), 405–415 (1960)
Srinivasan, S.: The use of tin and bronze in prehistoric southern Indian metallurgy. J. Met. 50(7), 44–48 (1998)
Srinivasan, S., Glover, I.: Wrought and quenched, and cast high-tin bronzes in Kerala State, India. Hist. Metall. 29(2), 69–88 (1995)
Srinivasan, S., Glover, I.: Skilled mirror craft of intermetallic delta high-tin bronze (Cu31Sn8, 32.6% tin) from Aranmula, Kerala. Curr. Sci. 93(1), 35–40 (2007)
Sterner-Rainer, L.: Die Verbindung Au-Cu in Goldlegierungen. Z. Met. 17, 162–165 (1925)
Sterner-Rainer, L.: Die Edelmetall-Legierungen in Industrie und Gewerbe. Verlag Wihelm Diebener, Leipzig (1930)
Steurer, W.: Crystal structures of metallic elements and compounds. In: Laughlin, D.E., Hono, K. (eds.) Physical Metallurgy I, 5th edn, pp. 1–101. Elsevier, Amsterdam et al (2014)
Stöllner, T., Oeggl, K. (eds.): Bergauf Bergab – 10.000 Jahre Bergbau in den Ostalpen. Veröffentlichung aus dem Deutschen Bergbau-Museum Bochum 207. Verlag Marie Leidorf, Bochum (2015)
Stöllner, T., Schwab, R.: Hart oder weich? Worauf es ankommt! Pickel aus dem prähistorischen Bergbau in den Ostalpen. Festschrift Fritz Eckart Barth, Mitteilungen der Anthropologischen Gesellschaft in Wien. 139, 149–166 (2009)
Tadmor, M., Kedem, D., Begemann, F., Hauptmann, A., Pernicka, E., Schmitt-Strecker, S.: The Naḥal Mishmar hoard from the Judean Desert: technology, composition, and provenance. Atiqot. 27, 95–148 (1995)
Tamalameque. Averiguaciones en Tamalameque sobre los manyllas que Mando Hazer Juan de Azpeleta a los Yndios de su Encomienda de Anpihuegas. Justicia, Legajo 610–612, folios 2520–25 (manuscript) Archivo General de Indias, Seville. Trans in Museo del Oro Archives, Bogota, Colombia (1555)
Uran, L.: Observations métallographiques sur les épées celtiques en fer. Revue Aquitania Supplément. 1, 299–308 (1986)
Vander Voort, G.F.: Metallography, Principles and Practice. McGraw-Hill, New York (1984)
Voce, E.: Examination of specimens from the Pitt Rivers Museum. In: Coghlan, H.H. (ed.) Notes on the Prehistoric Metallurgy of Copper and Bronze in the Old World. Pitt Rivers Museum Occasional Papers on Technology 4, pp. 110–111. University Press, Oxford (1951)
Wanhill, R.J.H., Steijaart, J.P.H.M., Leenheer, R., Koens, J.F.W.: Damage assessment and preservation of an Egyptian silver vase (300–200 BC). Archaeometry. 40(1), 123–137 (1998)
Wayman, M.L., Duke, M.J.M.: The effects of melting on native copper. In: Hauptmann, A., Pernicka, E., Rehren, T., Yalçın, Ü. (eds.) The Beginnings of Metallurgy. Der Anschnitt Beiheft 9, pp. 55–63. Deutsches Bergbau-Museum, Bochum (1999)
Weast, R.C. (ed.): The CRC Handbook of Chemistry and Physics, 59th edn. CRC Press, Boca Raton (1978)
Weins, W.N., Bleed, P.: Why is the Japanese sword curved? MRS Proc. 185(p), 691–698 (1990)
Wheeler, T.S., Maddin, R.: The techniques of the early Thai metalsmith. Expedition. 18(4), 38–47 (1976)
Willer, F., Schwab, R., Mirschenz, M.: Römische Bronzestatuen am Limes: Archäometrische Untersuchungen zur Herstellungstechnik. Bonner Jahrbücher. 216, 57–207 (2017)
Wise, E.M.: Gold: Recovery, Properties, and Applications. Van Nostrand Company, Toronto/New York/London (1964)
Zhang, Y.M., Yang, S., Evans, J.R.G.: Revisiting Hume-Rothery’s rules with artificial neural networks. Acta Mater. 56(5), 1094–1105 (2008)
Zwicker, U.: Archaeometallurgical investigation on the copper – and copper-alloy-production in the area of the Mediterranean Sea (7000–1000 B.C.). Bull. Met. Mus. 15, 3–32 (1990)
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Scott, D.A., Schwab, R. (2019). The Structure of Metals and Alloys. In: Metallography in Archaeology and Art. Cultural Heritage Science. Springer, Cham. https://doi.org/10.1007/978-3-030-11265-3_4
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