Abstract
HeI photoelectron spectra of gas phase clusters of small molecules are presented for the first time. Using a pulsed jet preparation system the spectra of molecular beams of N2 and N2O respectively are analysed to give data on the percentage condensation. An extension of the dielectric polarization relaxation model which considers spherical clusters shows that shifts in vertical ionization energies are approximately linear with log N for clusters of N molecules. The model should be useful in the N = 102 – 104 size range.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
J. C. Phillips, Chem. Rev., 86, 619 (1986).
J. Kontecky and P. Fantucci, Chem. Rev., 86, 539 (1986).
F. G. Celii and K. C. Janda, Chem. Rev., 86, 507 (1986).
P. M. Dehmer and J. L. Dehmer, J. Chem. Phys. 69, 125 (1978).
S. Tomoda, Y. Achiba and K. Kimura, Chem. Phys. Lett., 87, 197 (1982).
F. Carnovale, M. K. Livett and J. B. Peel, J. Am. Chem. Soc, 105, 6788 (1983).
H. Siegbahn, S. Svensson and M. Lundholm, J. Electron Spectrosc, 24, 205 (1981).
M. J. Campbell, J. Liesegang, J. D. Riley and J. G. Jenkin, J. Phys. C., 15, 2549 (1982).
L. S. Bartell, Chem. Rev., 86, 491 (1986).
S. H. Linn, Y. Ono and C. Y. Ng, J. Chem. Phys., 74, 3342 (1981).
H. H. Teng and D. C. Conway, J. Chem. Phys., 59, 2316 (1973).
A. van der Avoird, P.E.S Wormer and A.P.J. Jansen, J. Chem. Phys., 84, 1629 (1986).
H. J. Boehm and R. Ahlrichs, Mol. Phys., 55, 1159 (1985).
S. C. de Castro, H.F. Schaefer and R. M. Pitzer, J. Chem. Phys., 74, 550 (1981).
F.-J. Himpsel, N. Schwentner and E. E. Koch, Phys. Stat. Solid. B, 71, 615 (1975).
W. Keller, H. Morgner and W. A. Muller, Mol. Phys., 57, 623 (1986).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Plenum Press, New York
About this chapter
Cite this chapter
Carnovale, F., Peel, J.B., Rothwell, R.G. (1987). Photoelectron Spectroscopy of Molecular Clusters: N2 and N2O. In: Jena, P., Rao, B.K., Khanna, S.N. (eds) Physics and Chemistry of Small Clusters. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0357-3_82
Download citation
DOI: https://doi.org/10.1007/978-1-4757-0357-3_82
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-0359-7
Online ISBN: 978-1-4757-0357-3
eBook Packages: Springer Book Archive