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The Mössbauer Parameters in Tin(IV) and Europium(III) Compounds

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Mössbauer Effect Methodology

Abstract

There is a considerable interest in the interpretation of the Mössbauer parameters of Sn(IV) and organotin (IV) compounds. A compilation of the isomer shift, δ, and the quadrupole splitting, AEq, data on organotin compounds (1) and reviews on this topic have appeared (2–4). Tin-119 isomer shifts reflect changes in 5 s electron density at the nucleus. It has been shown that the contribution of inner shells remains virtually constant for both emitters and absorbers in Sn(IV) compounds (3). The δ value is known to be dependent on populations of Sn(IV) ion valence states i.e. s, p and d orbitals relative to those of the emitter (5). Expressions relating isomer shifts with the electronic structure of tin in its compounds have been obtained by Goldanskii et al (6) by following Fermi-Segré formulae for the electron density of 5 s electrons. Ruby et al obtained almost linear relationships of 6 with the electron populations of valence states in tin for different numbers of s and p electrons using Hartree-Fock self consistent-field atomic wave functions (7).

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Authors and Affiliations

  1. Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada

    A. J. Carty & H. D. Sharma

Authors
  1. A. J. Carty
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  2. H. D. Sharma
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Editors and Affiliations

  1. Nuclides and Sources Division, New England Nuclear Corporation, Billerica, Massachusetts, USA

    Irwin J. Gruverman (Manager) (Manager)

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Carty, A.J., Sharma, H.D. (1971). The Mössbauer Parameters in Tin(IV) and Europium(III) Compounds. In: Gruverman, I.J. (eds) Mössbauer Effect Methodology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9002-6_9

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  • DOI: https://doi.org/10.1007/978-1-4615-9002-6_9

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9004-0

  • Online ISBN: 978-1-4615-9002-6

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