Skip to main content

Comparative Study of Cellulose Extraction Processes from Palm Kernel Cake

  • Chapter
  • First Online:
Developments in Sustainable Chemical and Bioprocess Technology
  • 2429 Accesses

Abstract

Palm kernel cake (PKC) is one of palm oil industry by-products which are rich in edible cellulose, which can be used as potential source in food and pharmaceutical industry. The extraction of cellulose from PKC involved essentially delignification and hemicellulose removal processes. In this study, three delignification and two hemicellulose removal techniques were comparatively investigated. Response surface methodology (RSM) with D-optimal design was used for the analysis. In this analysis, delignification techniques, hemicellulose removal techniques, and hemicellulose removal time (HRT) were chosen as process factors, whereas quantity of hemicellulose removal, cellulose yield, and cellulose purity were chosen as process responses. The comparative result obtained in this study shows that the combination of liquid phase oxidation (LPO) of delignification technique and alkali treatment of hemicellulose removal was the best method of cellulose extraction from palm kernel. The result of FTIR spectrum analysis of the cellulose produced in this study was similar to those produced commercially validating the cellulose structure. The optimum cellulose extraction method in this study shows that hemicellulose can be removed up to 24 % with cellulose yield 70 % and purity 77 %.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 89.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Alimon, A. R. (2004). The nutritive value of palm kernel cake for animal feed, Department of Animal Science, Faculty of Agriculture UPM. http://www.chgs.com.my/chinese/download/Palm%20Oil.pdf.

  • Asim, K. R. C. (2006). Textile preparation and dyeing, chemistry of textile materials (p. 11). New Hampshire: Science Publishers, 03784, USA.

    Google Scholar 

  • Astimar, A. A., Husin, M., & Anis, M. (2002). Preparation of cellulose from oil palm empty fruit bunches via ethanol digestion: Effect of acid and alkali catalysts. Journal of Oil Palm Research, 14(1), 9–14.

    Google Scholar 

  • Biljana, M. P., Mirjana, M. K., Petar, D. S., & Jovana, Z. P. (2008). The effects of hemicelluloses and lignin removal on water uptake behavior of hemp fibers. Bioresource Technolnology 99(15), 7152–7159.

    Google Scholar 

  • Bono, A., Duduku K., Mariani R., & Nancy J. S. (2006). D-optimal analysis of formula variation effect on Melamine-Urea Formaldehyde. Studies in Surface Science and Catalysis (pp. 713–716). Elsevier BV. ISBN-10: 0-444-52751-6 159.

    Google Scholar 

  • Bono, A., Rosalam, S., Mariani, R., & Duduku, K. (2008a). Effect of mixture components on the properties of MUF resin. International Journal of Physical Sciences, 3, 45–49.

    Google Scholar 

  • Bono, A., Duduku, K., & Mariyani, R. (2008b). Product and process optimization using response surface methodology. Universiti Malaysia, Sabah. ISBN: 978-983-2369-80-6.

    Google Scholar 

  • Chu, Y. M. (2011). Overview of the Malaysian Oil Palm Industry 2010, Malaysian Palm Oil Board, Malaysia.

    Google Scholar 

  • Duduku, K., Rajesh, N., & Rosalam, S. (2011). Optimization of spray for drying Morinda citrifolia L. fruit extract. Journal of Applied Sciences, 11(13), 2276–2283.

    Article  Google Scholar 

  • Duduku, K., Anisuzzaman, S. M., Bono, A., & Rosalam S. (2012). Adsorption of 2, 4, 6-Trichlorophenol (TCP) onto activated carbon. Journal of King Saud University-Science (in press).

    Google Scholar 

  • Dusterhoft, E. M., Posthumus, M. A., & Voragen, A. G. J. (1992). Non-starch polysaccharides from sunflower (Helianthus annuus) meal and palm kernel (Elaeisguineensis) meal preparation of cell wall material and extraction of polysaccharide fractions. Journal of the Science of Food and Agriculture, 59, 151–160.

    Article  CAS  Google Scholar 

  • Farm, Y., Duduku, K., Bono, A., & Mariani, R. (2009). Cellulose extraction from Palm kernel cake using Liquid phase oxidation. Journal of Engineering Science and Technology, 4(1), 57–68.

    Google Scholar 

  • Feng, X., Jin-Xia, S., Runcang, S., Paul, F., & Mark, S. B. (2006). Comparative study of organosolv lignins from wheat straw. Industrial Crops and Products, 23, 180–193.

    Article  Google Scholar 

  • Hoenich, N. (2006). Cellulose for medical applications: past, present and future. BioResources, 1(2), 270–280.

    Google Scholar 

  • Isogai, A. (2001). In D. N. S. Hon & N. Shiraishi (Eds.) Chemical modification of cellulose in wood and cellulosic chemistry: Second Edition, revised and expanded (pp. 599–625). New York: Mercel Dekker.

    Google Scholar 

  • Kammes, K. L., Bals, B. D., Dale, B. E., & Allen, M. S. (2011). Grass leaf protein, a coproduct of cellulosic ethanol production, as a source of protein for livestock. Animal Feed Science and Technology, 164(1–2), 79–88.

    Article  CAS  Google Scholar 

  • Kim, J., Yun, S., & Ounaies, Z. (2006). Discovery of cellulose as a smart material. Macromolecus, 39, 4202–4206.

    Article  CAS  Google Scholar 

  • Liu, C. F., Fu, X., Sun, J. X., Ren, J. L., Curling, S. R., Sun, C., et al. (2006). Physicochemical characterization of cellulose from perennial ryegrass leaves (Lolium perenne). Carbohydrate Research, 341, 2677–2687.

    Article  PubMed  CAS  Google Scholar 

  • Mae, K., Isao H., Noriaki S., & Kouichi M. (2000). A new conversion method for recovering valuable chemicals from oil palm shell wastes utilizing liquid phase oxidation with H2O2 under mild condition. Energy & Fuels, 14, 1212–1218.

    Google Scholar 

  • Sarwar, J. M., Chowdhury, D. A. N., Khalidul, I. M., & Iqbal M. S. M. (2007). Characterization of Lignin Isolated from Some Nonwood Available in Bangladesh. Bioresource Technology, 98, 465–469.

    Google Scholar 

  • Sun, J. X., Sun, X. F., Zhao, H., & Sun, R. C. (2004a). Isolation and characterization of cellulose from sugarcane bagasse. Polymer Degradation and Stability, 84, 331–339.

    Google Scholar 

  • Sun, X. F., Sun, R. C., Fowler, P., & Baird, M. S. (2004b). Isolation and characterisation of cellulose obtained by a two-stage treatment with organosolv and cyanamide activated hydrogen peroxide from wheat straw. Carbohydrate Polymers, 55, 379–391.

    Article  CAS  Google Scholar 

  • Sundu, B., Kumar, A., & Dingle, J. (2006). Palm kernel cake in broiler diets: effect on chicken performance and health. Worlds Poultry Science Journal, 62, 316–325.

    Article  Google Scholar 

  • TAPPI T 15 os-58, Technical Association for the Pulp and Paper Industries. (1978). Ash in wood and pulp.TAPPI Test Method T 15 os-58. TAPPI PRESS, Atlanta.

    Google Scholar 

  • TAPPI standard T 222 OS-74, TAPPI Standard Methods. (2009). Fibrous Materials and Pulp Testing. Technical Association of Pulp and Paper Industry, Atlanta.

    Google Scholar 

  • TAPPI Test Method T 12 OS-75. (1978). Technical Association for the Pulp and Paper Industries Preparation of extractive free-wood. TAPPI PRESS, Atlanta.

    Google Scholar 

  • Wise, L. E., Maxine, M., & D’Addieco, A. A. (1946). Chlorite holoeellulose, its fractionation and bearing on summative wood analysis and on studies on the hemicelluloses. Paper Trade Journal, 122, 35–43.

    CAS  Google Scholar 

  • Wu, J., & Yuan, Q. (2002). Gas permeability of a novel cellulose membrane. Journal of Membrane Science, 204(1–2), 185–194.

    Article  CAS  Google Scholar 

  • Xu, F., Sun, J. X., Geng, Z. C., Liu, C. F., Ren, J. L., Sun, R. C., et al. (2007). Comparative study of water-soluble and alkali-soluble hemicelluloses from perennial ryegrass leaves (Loliumperee). Carbohydrate Polymers, 67(1), 56–65.

    Article  CAS  Google Scholar 

  • Xua, Y., Kecheng, L., & Meiyun, Z. (2007). Lignin precipitation on the pulp fibers in the ethanol-based organosolv pulping. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 301, 255–263.

    Article  Google Scholar 

  • Zhang, Y. H. P., Ding, S. Y., Mielenz, J. R., Cui, J. B., Elander, R. T., Laser, M., et al. (2007). Fractionating recalcitrant lignocellulose at modest reaction conditions. Biotechnology and Bioengineering, 97(2), 214–223.

    Article  PubMed  CAS  Google Scholar 

  • Zhang, S. P., Jin, F. M., Hu, J. J., Huo, Z. B. (2011). Improvement of lactic acid production from cellulose with the addition of Zn/Ni/C under alkaline hydrothermal conditions. Bioresource Technology, 102(2), 1998–2003.

    Google Scholar 

Download references

Acknowledgments

Financial support for this study was provided by Penyelidikan Siswazah Universiti (PGD) 2006, MOSTI, Malaysia.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Bono .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media New York

About this chapter

Cite this chapter

Farm, Y.Y., Anisuzzaman, S.M., Krishnaiah, D., Bono, A. (2013). Comparative Study of Cellulose Extraction Processes from Palm Kernel Cake. In: Pogaku, R., Bono, A., Chu, C. (eds) Developments in Sustainable Chemical and Bioprocess Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4614-6208-8_33

Download citation

Publish with us

Policies and ethics