CAS Registry Number: 77355-61-4
Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Eudesmanes (Selinanes) Eudesmanes – Monoesters
Biological sources: Verbesina glabrata Hook. et Arn., V. luetzelburgii Mattf. [1]; Solidago nemoralis Aiton [2]; Verbesina sordescens DC. [3]
C24H32O3: 368.2351
Mp: colorless gum [1]
Isolated as its 1-OAc [2]
Mp (its 1-OAc): colorless oil [2]
[α]24 (λ, nm): +56.5° (589), +59.4° (578), +69.0° (546), +135.6° (436) (c 3.3, CHCl3) [1]
MS: 368.235 (C24H32O3) (8), 220 [M − PhCH = CHCOOH] (17), 202 [220 − H2O] (37), 131 [C6H4CH = CHCO]+ (100) [1]
MS (its 1-OAc): 410.246 [M]+ (1) (C26H34O4), 350 (12), 262 (5), 202 (55), 159 (81), 131 (100), 43 (48) [2]
1 H NMR (270 MHz, CDCl3, TMS): 0.88 (3H, d, J = 7, H-13), 1.05 (3H, d, J = 7, H-12), 1.10 (3H, s, H-14), 1.19 (1H, m, H-9b), 1.19 (3H, br s, H-15), 1.47 (1H, dqq, J = 7;...
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References
F. Bohlmann, M. Grenz, R.K. Gupta, A.K. Dhar, M. Ahmed, R.M. King, H. Robinson, Phytochemistry 19(11), 2391 (1980)
F. Bohlmann, U. Fritz, R.M. King, H. Robinson, Phytochemistry 19(12), 2655 (1980)
F. Bohlmann, C. Zdero, H. Robinson, R.M. King, Phytochemistry 21(7), 1663 (1982)
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(2013). 6β-Cinnamoyloxy-5α,6α,7α(H)-eudesm-3-en-1β-ol (6β-Cinnamoyloxy-1β-hydroxy-Eudesm-3-ene; 6β-Cinnamoyloxy-3,4-dehydroeudesmane). In: Azimova, S.S., Saidkhodzhaev, A.I. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0539-9_1724
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