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Organic Molecule, 1,4-Dihydroxy-9, 10-Anthraquinone, Doped Amorphous Silica Prepared by Sol-Gel Method and its Structures Studied by Photochemical Hole Burning

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Abstract

Ever since the anomalous contribution to the specific heat of silica glass below 1 K[1] was reported, extensive experimental efforts have been devoted to understand the dynamical properties of disordered solids. Although the observed phenomena seem to be consistent with the theoretical model based on the existence of two-level system’s(TLS’s)[2], the microscopic nature of TLS’s is not yet understood. In our attempt to gain further insight into the structures and dynamical properties of amorphous solids at low temperatures, we tried to introduce photosensitive functional “organic dye molecules” into the “inorganic silica glass matrix” and to probe the amorphous structure by the photochemical hole burning(PHB)[3] spectroscopy.

on leave from Mitsui Petrochemical Industries, Ltd. 2–5, Kasumigaseki 3, Chiyoda-ku Tokyo 100, Japan.

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References

  1. R. C. Zeller and R. O. Pohl, Thermal conductivity and specific heat of noncrystalline solids, Phys. Rev. B4: 2029 (1971).

    Article  Google Scholar 

  2. P. W. Anderson, B. I. Halperin and C M. Varma, Anomalous low-temperature thermal properties of glasses and spin glasses, Philos. Mag. 25: 1 (1972)

    Article  CAS  Google Scholar 

  3. W. A. Phillips, Tunnelling states in amorphous solids, J. Low Temp. Phys. 7: 351 (1972).

    Article  CAS  Google Scholar 

  4. J. Friedrich, H. Wolfrum and D. Haarer, Photochemical holes: A spectral probe of the amorphous state in the optical domain, J. Chem. Phys. 77: 2309 (1982).

    Article  CAS  Google Scholar 

  5. T. Tani, H. Namikawa K. Arai and A. Makishima, Photochemical hole-burning study of 1,4-dihydroxyanthraquinone doped in amorphous silica prepared by alcoholate method, J. Appl. Phys. 58: 3559 (1985).

    Article  CAS  Google Scholar 

  6. A. Makishima and T. Tani, Preparation of amorphous silicas doped with organic molecules by the sol-gel process, J. Amer. Cer. Soc. to be published.

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  7. D. Avnir, D. Levy and R. Reisfeld, The nature of the silica cage as reflected by spectral changes and enhanced photostability of trapped rhodamine 6G, J. Phys. Chem. 88: 5956 (1984).

    Article  CAS  Google Scholar 

  8. S. K. Lyo and R. Orbach, Homogeneous fluorescence linewidths for amorphous hosts, Phys. Rev. B22: 4223 (1980).

    Article  CAS  Google Scholar 

  9. T. Tani, Matrix effects and structures of organic glasses made of small poler molecules studied by photochemical hole burning, under preparation.

    Google Scholar 

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© 1988 Plenum Press, New York

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Tani, T., Makishima, A., Itani, A., Itoh, U. (1988). Organic Molecule, 1,4-Dihydroxy-9, 10-Anthraquinone, Doped Amorphous Silica Prepared by Sol-Gel Method and its Structures Studied by Photochemical Hole Burning. In: Scher, H. (eds) Unconventional Photoactive Solids. Institute for Amorphous Studies Series. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0727-3_19

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  • DOI: https://doi.org/10.1007/978-1-4613-0727-3_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8052-1

  • Online ISBN: 978-1-4613-0727-3

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