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Design of Functionalized Polysiloxane Adsorbents and Their Environmental Applications

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Sol-Gel Methods for Materials Processing

Abstract

Here we consider the routes of synthesis (which is performed by use of sol-gel method) of a new class of sorbents, namely: polysiloxane xerogels functionalized with nitrogen-, oxygen-, phosphorus- and sulfur chapter ligand groups. Applying a number of physical methods (SEM, TEM, AFM, IR and Raman spectroscopy, 1H, 13C, 29Si and 31P CP/MAS NMR, EPR spectroscopy, ERS, thermal analysis) we established the structure of both: the xerogels and their surface. An influence of some factors on the structural-adsorption characteristics of such xerogels and their sorption properties is analyzed.

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Authors and Affiliations

  1. O. O. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17 General Naumov Str., Kyiv, 03164, Ukraine

    Yuriy L. Zub (Head of Surface Chemistry of Hybrid Materials Department)

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  1. Yuriy L. Zub
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  1. University of Sassari, Italy

    Plinio Innocenzi

  2. Ukraine Academy of Sciences, Kiev, Ukraine

    Yuriy L. Zub

  3. Swedish Life Science University (SLU), Uppsala, Sweden

    Vadim G. Kessler

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Zub, Y.L. (2008). Design of Functionalized Polysiloxane Adsorbents and Their Environmental Applications. In: Innocenzi, P., Zub, Y.L., Kessler, V.G. (eds) Sol-Gel Methods for Materials Processing. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8514-7_1

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